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Furfuryl alcohol

Basic information Description References Safety Related Supplier
Furfuryl alcohol Basic information
Furfuryl alcohol Chemical Properties
  • Melting point:-29 °C
  • Boiling point:170 °C(lit.)
  • Density 1.135 g/mL at 25 °C(lit.)
  • vapor density 3.4 (vs air)
  • vapor pressure 0.5 mm Hg ( 20 °C)
  • refractive index n20/D 1.486(lit.)
  • FEMA 2491 | FURFURYL ALCOHOL
  • Flash point:149 °F
  • storage temp. 2-8°C
  • solubility alcohol: soluble
  • pka14.02±0.10(Predicted)
  • form Liquid
  • color Clear yellow
  • PH6 (300g/l, H2O, 20℃)
  • OdorMildly irritating.
  • Odor Threshold8 ppm
  • explosive limit1.8-16.3%(V)
  • Water Solubility MISCIBLE
  • FreezingPoint -29℃
  • JECFA Number451
  • Merck 14,4305
  • BRN 106291
  • Exposure limitsNIOSH REL: TWA 10 ppm (40 mg/m3), STEL 15 ppm (60 mg/m3), IDLH 75 ppm; OSHA PEL: TWA 50 ppm; ACGIH TLV: TWA 10 ppm, STEL 15 ppm (adopted).
  • CAS DataBase Reference98-00-0(CAS DataBase Reference)
  • NIST Chemistry Reference2-Furanmethanol(98-00-0)
  • EPA Substance Registry System2-Furanmethanol (98-00-0)
Safety Information
MSDS
Furfuryl alcohol Usage And Synthesis
  • DescriptionFurfuryl alcohol is clear colorless organic liquid having a furan substituted with a hydroxymethyl group. It is primarily used for the synthesis of furans resins which are used in thermoset polymer matrix composites, cements, adhesive and coatings. It plays an essential role in the production of foundry sand binder and has long been used to produce cores and molds for metal casting. Other applications include as a fuel and wood treatment. In industry, it is manufactured through either direct reduction of furfural, or through the disproportionation via the Cannizaro reaction in NaOH solution. The basic raw materials for its manufacturing are waste vegetable materials such as rice hulls, sugar cane bagasse, oat hulls or corncobs.
  • Referenceshttps://en.wikipedia.org/wiki/Furfuryl_alcohol
    http://www.furan.com/furfuryl_alcohol_applications.html
  • Chemical Propertiesclear yellow liquid
  • Chemical PropertiesFurfural alcohol is a colorless to amber liquid that darkens on exposure to light. It has a faint, burning odor.
  • Chemical PropertiesFurfuryl alcohol has a very mild, warm, oily, “burnt” odor and a cooked sugar taste.
  • Physical propertiesClear, colorless to pale yellow liquid with an irritating odor. Darkens to yellowish-brown on exposure to air. A detection odor threshold concentration of 32 mg/m3 (8.0 ppmv) was determined by Jacobson et al. (1958).
  • OccurrenceReported found in roasted almonds, cooked apple, apple juice, roasted barley, beans, beef fat, canned beef stew, beer, brandy, white bread, cocoa, cocoa bean, roasted coffee, roasted flberts, honey, heated skim milk, dried mushrooms, roasted onion, yellow passion fruit, roasted peanuts, pineapple, popcorn, potato chips, roasted sesame seeds, cheeses, milk, meats, grape wines, cognac, whiskies, soybean products, coconut, corn oil, shrimps, clams and other sources
  • UsesFurfuryl Alcohol has been obtained by yeast reduction of furfural. Furfuryl Alcohol is used as solvent and in the manufacturing of wetting agents, resins.
  • UsesSolvent; manufacture of wetting agents, resins.
  • DefinitionChEBI: A member of the class of furans bearing a hydroxymethyl substituent at the 2-position.
  • PreparationUsually prepared from furfural that is obtained by the processing of corncobs; oil obtained by steam distillation of roasted coffee bean meal consists of 50% furfuryl alcohol; prepared industrially by the catalytic reduction of furfural using nickel and Cu-CrO catalysts.
  • Aroma threshold valuesDetection: 1 to 2 ppm.
  • Taste threshold valuesTaste characteristics at 50 ppm: burnt, sweet, caramellic and brown.
  • General DescriptionA clear colorless liquid. Flash point 167°F. Boiling point 171°F. Denser than water. Contact may irritate skin, eyes and mucous membranes. May be toxic by ingestion and skin contact and moderately toxic by inhalation.
  • Air & Water ReactionsSlightly soluble in water.
  • HazardMay react explosively with mineral acids and some organic acids. Toxic by inhalation and skin absorption. Approved for food products. Toxic by skin absorption.
  • Health HazardInhalation causes headache, nausea, and irritation of nose and throat. Vapor irritates eyes; liquid causes inflammation and corneal opacity. Contact of skin with liquid causes dryness and irritation. Ingestion causes headache, nausea, and irritation of mouth and stomach.
  • Fire HazardCombustible material: may burn but does not ignite readily. When heated, vapors may form explosive mixtures with air: indoors, outdoors and sewers explosion hazards. Contact with metals may evolve flammable hydrogen gas. Containers may explode when heated. Runoff may pollute waterways. Substance may be transported in a molten form.
  • Chemical ReactivityReactivity with Water No reaction; Reactivity with Common Materials: No reactions; Stability During Transport: The product darkens and forms water insoluble material on exposure to air or acids. This reaction is accelerated at elevated temperatures; Neutralizing Agents for Acids and Caustics: Not pertinent; Polymerization: Not pertinent; Inhibitor of Polymerization: Not pertinent.
  • Safety ProfilePoison by ingestion, skin contact, and subcutaneous routes.Moderately toxic by inhalation and intraperitoneal routes. Mutation data reported. An eye irritant. Flammable when exposed to heat or flame; can react with oxidtzing materials. Moderate explosion hazard when exposed to heat or flame. Reacts violently with acids (e.g., formic acid, cyanoacetic acid + heat). Ignites on contact with 85% hydrogen peroxide. To fight fire, use alcohol foam, CO2, dry chemical. When heated to decomposition it emits acrid smoke and fumes.
  • Potential ExposureUsed as a starting monomer in the production of furan resins and used to produce tetrahydro furfural alcohol (THFA).
  • CarcinogenicityThe NTP conducted a 2-year inhalation study on furfuryl alcohol. F344 rats and B6C3F1 mice were exposed to 0, 2, 8, or 32 ppm furfuryl alcohol for 6 h/day, 5 days/week. All rats exposed to 32 ppm died by week 99; survival of all other animals was similar to control animals. There were increased incidences of nasal tumors in the male rats and increased incidences of kidney tubule tumors in male mice. Increased incidences of nonneoplastic lesions of the nose and increased severities of nephropathy were observed in male and female rats and male mice. Nonneoplastic lesions of nose and corneal degeneration occurred in female mice.
  • SourceFurfuryl occurs naturally in yarrow, licorice, sesame seeds, clove flowers, and tea leaves (Duke, 1992). Also detected in barrel-aged red, white, and model wines. Concentrations ranged from 3.5 mg/L in white wine after 55 wk of aging to 9.6 mg/L after 11 wk of aging (Spillman et al., 1998). Identified as one of 140 volatile constituents in used soybean oils collected from a processing plant that fried various beef, chicken, and veal products (Takeoka et al., 1996).
  • Environmental FateBiological. In activated sludge inoculum, following a 20-d adaptation period, 97.3% COD removal was achieved. The average rate of biodegradation was 41.0 mg COD/g?h (Pitter, 1976).
    Chemical/Physical. Easily resinified by acids (Windholz et al., 1983). Furfuryl alcohol will not hydrolyze because it has no hydrolyzable functional group.
    In barrel-aged red, white, and model wines, naturally occurring furfuryl alcohol decreased in concentration with time. In red wine, furfuryl ethyl ether was identified as a degradation product after 55 wk of storage. The average percentage decrease of furfuryl alcohol was 73% (Spillman et al., 1998).
  • ShippingUN2874 Furfuryl alcohol, Hazard Class: 6.1; Labels: 6.1-Poisonous materials.
  • Purification MethodsDistil it under reduced pressure to remove tarry material, shake with aqueous NaHCO3, dry it with Na2SO4 and fractionally distil it under reduced pressure from Na2CO3. It can be further dried by shaking with Linde 5A molecular sieves. [Beilstein 17/3 V 338.]
  • IncompatibilitiesIncompatible with oxidizers (chlorates, nitrates, peroxides, permanganates, perchlorates, chlorine, bromine, fluorine, etc.); contact may cause fires or explo sions. Keep away from alkaline materials, strong bases, strong acids, oxoacids, epoxides. Contact with acids can cause polymerization. Strong reaction with oxidizers. Incompatible with alkaline earth and alkali metals; strong caustics; aliphatic amines; isocyanates, acetaldehyde, benzoyl peroxide; chromic acid, chromium trioxide; cyanoacetic acid; dialkylzincs, dichlorine oxide; ethylene oxide; hydrogen per oxide; isopropyl chlorocarbonate; lithium tetrahydroalumi nate; nitric acid; nitrogen dioxide; pentafluoroguanidine, phosphorus pentasulfide; tangerine oil; triethylaluminum, trii sobutylaluminum. Attacks some plastics, coatings and rubber.
  • Waste DisposalIncineration in admixture with a more flammable solvent.
Furfuryl alcohol Preparation Products And Raw materials
Furfuryl alcohol(98-00-0)Related Product Information
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