ChemicalBook Product Catalog Inorganic chemistry Oxides and peroxides Metal oxide TIN(II) OXIDE

TIN(II) OXIDE

Product NameTIN(II) OXIDE
CAS21651-19-4
MFOSn
MW134.71
EINECS244-499-5
MOL File21651-19-4.mol

Chemical Properties

Melting point

1080 °C

Density

6,95 g/cm³

storage temp.

Store at RT.

solubility

insoluble in H2O, ethanol; soluble in acid solutions

form

powder

color

Blue-black

Specific Gravity

6.95

Water Solubility

Insoluble in water, and alcohol.

Hydrolytic Sensitivity

4: no reaction with water under neutral conditions

Crystal Structure

PbO type

crystal system

square

Merck

14,8787

Space group

P4/nmm

Lattice constant

a/nm	b/nm	c/nm	α/o	β/o	γ/o	V/nm3
0.38029	0.38029	0.48382	90	90	90	0.07

Exposure limits

ACGIH: TWA 2 mg/m3
NIOSH: IDLH 100 mg/m3; TWA 2 mg/m3

Stability

Stable. Incompatible with strong acids, strong bases.

InChI

1S/O.Sn

InChIKey

QHGNHLZPVBIIPX-UHFFFAOYSA-N

Safety Information

Safety Statements	24/25
OEB	B
OEL	TWA: 2 mg/m3
WGK Germany	3
RTECS	XQ3700000
TSCA	TSCA listed
HS Code	28259085
Storage Class	6.1C - Combustible acute toxic Cat.3 toxic compounds or compounds which causing chronic effects
Hazard Classifications	Acute Tox. 4 Oral Eye Irrit. 2 Skin Sens. 1 STOT RE 1

MSDS

Provider	Language
ACROS	English
SigmaAldrich	English
ALFA	English

Usage And Synthesis

Physical Properties

Bluish-black powder; tetragonal crystals; density 6.45 g/cm3; decomposes at 1,080°C; insoluble in water; dissolves in acids to form Sn2+ and in base to form stannite ion, Sn(OH)^3–.

Uses

Tin(II) oxide is a reducing agent; and is used in preparing other tin(II) salts. Also, it is used to make soft abrasive putty powder.

Preparation

Tin(II) oxide is prepared by heating tin(II) hydroxide. The latter is obtained as a white precipitate by reacting Sn2+ ions with hydroxide ions:
Sn2+(aq) + 2OH¯(aq) → Sn(OH)2 (s)

Chemical Properties

black crystals with a characteristic odour. Tin oxide is insoluble in water but soluble in acids and alkalis and slightly soluble in ammonium chloride. Tin oxide is incompatible with acids and/or alkalis.

Uses

Reducing agent; preparation of stannous salts.

Uses

Tin(II) oxide is used as reducing agent, soft abrasive, and in preparation of stannous salts. It is used in the manufacture of copper ruby glass, and for illumination with UV light.

General Description

Brownish-black powder or black to blue-black crystalline solid. Mp: 1080°C (decomposes); density: 6.45 g cm-3. Insoluble in water.

Reactivity Profile

TIN(II) OXIDE is a reducing agent. Unstable in air due to slow oxidation to tin(IV) oxide. At 300°C this oxidation proceeds incandescently. Incompatible with strong oxidizing agents. Reacts with acids and with strong bases.

TIN(II) OXIDE

Chemical Properties

Safety Information

MSDS

Usage And Synthesis

Preparation Products And Raw materials

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TIN(II) OXIDE manufacturers

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