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1,1'-BIS(DI-TERT-BUTYLPHOSPHINO)FERROCENE

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1,1'-BIS(DI-TERT-BUTYLPHOSPHINO)FERROCENE Basic information
1,1'-BIS(DI-TERT-BUTYLPHOSPHINO)FERROCENE Chemical Properties
  • Melting point:181-182°C (dec.)
  • form crystal
  • color orange to red
  • Water Solubility Insoluble in water.
  • InChIKeyFPLSJBJGQLJLSV-UHFFFAOYSA-N
Safety Information
MSDS
  • Language:EnglishProvider:ALFA
1,1'-BIS(DI-TERT-BUTYLPHOSPHINO)FERROCENE Usage And Synthesis
  • Reaction
    1. Ligand for synthesis of polycyclic indoles via Pd-catalyzed intramolecular heteroannulation.
    2. Ligand for the palladium-catalyzed intramolecular arylation of aryl bromides under mild conditions.
    3. Ligand for cross-coupling reactions between bromoarenes and potassium allyltrifluoroborates promoted by a catalyst prepared from Pd(OAc)2 and DTBPF selectively providing γ-coupling products.
    4. Ligand for the copper-catalyzed system for the ß-boration of of a variety of α,ß-unsaturated amides.
    5. Ligand for the synthesis of Paucifloral F and related indanone analogues via palladium-catalyzed α-arylation.
    6. Ligand for the Pd-carbon monoxide complex catalyzed hydroxycarbonylation of aryl halides.
    7. Ligand for the palladium-catalyzed β-C-glycosylation by decarboxylative allylation to normal pyran systems,and cis-2,6-disubstituted tetrahydropyrans.
    8. Pd-catalyzed dearomative indole bisfunctionalization via a diastereoselective arylcyanation.
    9. Ligand for the copper- DTBPF catalyzed C–H activation and carboxylation of terminal alkynes.

1,1'-BIS(DI-TERT-BUTYLPHOSPHINO)FERROCENE Preparation Products And Raw materials
1,1'-BIS(DI-TERT-BUTYLPHOSPHINO)FERROCENE(84680-95-5)Related Product Information
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