Geranylacetat

Bezeichnung:Geranylacetat

CAS-Nr105-87-3

Englisch Name:Geranyl acetate

CBNumberCB5334054

SummenformelC12H20O2

Molgewicht196.29

MOL-Datei105-87-3.mol

Synonyma

Geranylacetat

Geranylacetat physikalisch-chemischer Eigenschaften

Schmelzpunkt	25°C
Siedepunkt	236-242 °C(lit.)
Dichte	0.916 g/mL at 25 °C
Dampfdichte	6.8 (vs air)
Dampfdruck	0.07 mm Hg ( 20 °C)
Brechungsindex	n20/D 1.462
FEMA	2509 \| GERANYL ACETATE
Flammpunkt	220 °F
storage temp.	2-8°C
Löslichkeit	Chloroform (Slightly), Ethyl Acetate (Slightly), Methanol (Slightly)
Aggregatzustand	Liquid
Farbe	Colourless
Wichte	0.916
Geruch (Odor)	at 100.00 %. floral rose lavender green waxy
Geruchsart	floral
Wasserlöslichkeit	<0.1 g/100 mL at 20 ºC
JECFA Number	58
LogP	4.04 at 20℃
CAS Datenbank	105-87-3(CAS DataBase Reference)
NIST chemische Informationen	2,6-Octadien-1-ol, 3,7-dimethyl-, acetate, (E)-(105-87-3)
EPA chemische Informationen	trans-Geraniol acetate (105-87-3)

Sicherheit

Kennzeichnung gefährlicher	Xi
R-Sätze:	36/37/38
S-Sätze:	26-36-24/25
RIDADR	UN1230 - class 3 - PG 2 - Methanol, solution
WGK Germany	3
RTECS-Nr.	RG5920000
F	10-23
Hazard Note	Irritant
TSCA	Yes
HS Code	29153900
Giftige Stoffe Daten	105-87-3(Hazardous Substances Data)
Toxizität	The acute oral UD 50 value in rats was reported as 6.33 g/kg (Jenner, Hagan, Taylor, Cook & Fitzhugh, 1964).

Gefahreninformationscode (GHS)

Geranyl acetate Chemische Eigenschaften,Einsatz,Produktion Methoden

R-Sätze Betriebsanweisung:
R36/37/38:Reizt die Augen, die Atmungsorgane und die Haut.
S-Sätze Betriebsanweisung:
S26:Bei Berührung mit den Augen sofort gründlich mit Wasser abspülen und Arzt konsultieren.
S36:DE: Bei der Arbeit geeignete Schutzkleidung tragen.
S24/25:Berührung mit den Augen und der Haut vermeiden.
Beschreibung
Geranyl acetate has a pleasant, flowery odor reminiscent of rose lavender. It has a burning taste, initially somewhat bitter and then sweet. It is produced from geraniol by acetylation or by fractional distillation of essential oils in which it is present.
Beschreibung
Geranyl acetate is a monoterpene that has been found in C. sativa with diverse biological activities. It reduces compound action potential (CAP) peak amplitude in isolated frog sciatic nerves (IC₅₀ = 0.51 mM). Geranyl acetate inhibits the radial growth of M. gypsum, T. vercossum, and C. tropicalis on solid media. It is sporicidal against B. subtilis when used at a concentration of 1% in an agar diffusion assay. Geranyl acetate inhibits growth of COLO 205 cells (IC₅₀ = 30 μM) via induction of DNA damage, cell cycle arrest at the G₂/M phase, and mitochondrial apoptosis.
Chemische Eigenschaften
Geranyl Acetate occurs in varying amounts in many essential oils: up to 60% in oils from Callitris and Eucalyptus species and up to 14% in palmarosa oil. A smaller amount occurs in, for example, geranium, citronella, petitgrain, and lavender oils. Geranyl acetate is a liquid with a fruity rose note, reminiscent of pear and slightly of lavender. It is used frequently in perfumery not only to create floral, fruity nuances (e.g., rose) but also for citrus and lavender notes. A small amount is added to fruit aromas for shading.
Chemische Eigenschaften
Clear, colorless liquid; odor of lavender. Soluble in alcohol and ether; insoluble in water and glycerol. Combustible.
Chemische Eigenschaften
Geranyl acetate has a pleasant, fowery odor reminiscent of rose lavender It has a burning taste, initially somewhat bitter and then sweet.
Occurrence
Reported found in a large number of essential oils; Ceylon citronella, palmarose, lemongrass, petitgrain, neroi bigarade, geranium, coriander, lavender, carrot, sassafras, in various Callitris species (C verrucosa, C robusta, and others) and Eucalyptus species (E acervula, E urnigera, etc ) A 60% level has been reported in the essential oil of Eucalyptus macar- thuri and up to 50% in the essential oil of Orthodon citraliferum; also identifed in bitter orange essential oil and Cymbopogon citratus oil Also reported found in citrus peel oils and juices, black currants, pineapple, celery seed, cinnamon, ginger, pepper- mint oil, corn mint oil, nutmeg, mace, thymus, hop oil, beer, rum, grape wines, coffee, tea, passion fruit, tomato, almond, muscal grape, cardamom, coriander leaf and seed, tarragon, lovage, Ocimum basilicum, laurel, myrtle leaf and berry, rosemary, clary sage and calabash nutmeg
Verwenden
Perfumery, flavoring
Verwenden
β-Geranyl Acetate is found in essential oils such as Moroccan commercial essential oils which has anti-oxidant, anti-inflammatory and anti-proliferative activities; and in Salvia scabiosifolia from Bulgaria.
synthetische
From geraniol by acetylation or by fractional distillation of essential oils in which it is present.
Definition
ChEBI: A monoterpenoid that is the acetate ester derivative of geraniol.
Aroma threshold values
Detection: 9 to 460 ppb.
Taste threshold values
Taste characteristics at 20 ppm: green, foral, fruity with a citrus nuance.
Allgemeine Beschreibung
Clear colorless liquid with an odor of lavender.
Air & Water Reaktionen
Insoluble in water.
Reaktivität anzeigen
Geranyl acetate should be protected from light. Geranyl acetate reacts with strong oxidizing agents.
Brandgefahr
Geranyl acetate is probably combustible.
Flammability and Explosibility
Non flammable
Sicherheitsprofil
Mildly toxic by ingestion. A human skin irritant. Mutation data reported. Combustible liquid. When heated to decomposition it emits acrid smoke and irritating fumes. See also ESTERS.
läuterung methode
Purify the fragrant smelling geranyl acetate by fractional distillation at as high a vacuum as possible. It is very soluble in EtOH but insoluble in H2O. [Beilstein 2 H 140, 2 I 65, 2 II 153, 2 III 299, 2 IV 204.]

Geranyl acetate Upstream-Materialien And Downstream Produkte

Geranylacetat Anbieter Lieferant Produzent Hersteller Vertrieb Händler.

105-87-3, Geranyl acetate Verwandte Suche:

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