Pentylacetat

Gefahreninformationscode (GHS)

• Bildanzeige (GHS)

  

• Alarmwort

  Warnung

• Gefahrenhinweise

  H226：Flüssigkeit und Dampf entzündbar.

• Sicherheit

  P210：Von Hitze, heißen Oberflächen, Funken, offenen Flammen und anderen Zündquellenarten fernhalten. Nicht rauchen.

  P233：Behälter dicht verschlossen halten.

  P240：Behälter und zu befüllende Anlage erden.

  P241：Explosionsgeschützte [elektrische/Lüftungs-/ Beleuchtungs-/...] Geräte verwenden.

  P242：Nur funkenfreies Werkzeug verwenden.

  P243：Maßnahmen gegen elektrostatische Entladungen treffen.

Amyl acetate Chemische Eigenschaften,Einsatz,Produktion Methoden

• ERSCHEINUNGSBILD

  FARBLOSE FLüSSIGKEIT MIT CHARAKTERISTISCHEM GERUCH.

• PHYSIKALISCHE GEFAHREN

  Die Dämpfe sind schwerer als Luft.

• CHEMISCHE GEFAHREN

  Reagiert mit Oxidationsmitteln unter Feuer- und Explosionsgefahr. Greift viele Kunststoffe an.

• ARBEITSPLATZGRENZWERTE

  TLV: 50 ppm (als TWA); 100 ppm (als STEL); (ACGIH 2005).
  MAK: 50 ppm, 270 mg/m? Spitzenbegrenzung: überschreitungsfaktor I(1); Schwangerschaft: Gruppe C; (DFG 2008).
  EG Arbeitsplatz-Richtgrenzwerte: 50 ppm, 270 mg/m?(als TWA); 100 ppm, 540 mg/m?(als STEL) (EU 2000).
  

• AUFNAHMEWEGE

  Aufnahme in den Körper durch Inhalation der Dämpfe.

• INHALATIONSGEFAHREN

  Beim Verdampfen bei 20°C tritt langsam eine gesundheitsschädliche Kontamination der Luft ein.

• WIRKUNGEN BEI KURZZEITEXPOSITION

  WIRKUNGEN BEI KURZZEITEXPOSITION:
  Die Substanz reizt die Augen, die Haut und die Atemwege. Exposition in hohen Konzentrationen kann zu Bewusstseinstrübung führen.

• WIRKUNGEN NACH WIEDERHOLTER ODER LANGZEITEXPOSITION

  Die Flüssigkeit entfettet die Haut.

• LECKAGE

  Zündquellen entfernen. Ausgelaufene Flüssigkeit möglichst in abdichtbaren Behältern sammeln. Reste mit Sand oder inertem Absorptionsmittel aufnehmen und an einen sicheren Ort bringen.

• R-Sätze Betriebsanweisung:

  R10:Entzündlich.
  R66:Wiederholter Kontakt kann zu spröder oder rissiger Haut führen.

• S-Sätze Betriebsanweisung:

  S23:Gas/Rauch/Dampf/Aerosol nicht einatmen(geeignete Bezeichnung(en) vom Hersteller anzugeben).
  S25:Berührung mit den Augen vermeiden.
  S24/25:Berührung mit den Augen und der Haut vermeiden.

• Beschreibung

  All isomers of amyl acetate are highly flammable, colorless to yellow, watery liquids. The n- and isoisomers have a persistent, fruity, banana-like or pear-likeodor. The sec-isomer has a mild fruity odor. Molecularweight of isomers 5 130.21. Hazard Identification (basedon NFPA-704 M Rating System): (sec-isomer) Health 2,Flammability 3, Reactivity 0.n-isomer: Boiling point= 121℃; Melting/Freezingpoint=2 72℃; Specific gravity= 0.876 at 20℃; Liquidsurface tension= 5 0.012 N/m at 30℃; Liquid water interfacial tension 5 (estimate) 0.05 N/m at 17℃; Relative vapordensity (air= 1) 5 4.5; Ratio of specific heats of vapor(gas) 5 1.1; Latent heat of vaporization= 3.1 3 105 J/kg;Heat of combustion 5 2 310.8 3 105 J/kg; Vaporpressure= 0.93 kPa at 20℃; Flash point= 16°21℃, 25℃(cc); Autoignition temperature= 360℃; Explosive limits:LEL 5 1.0%; UEL 5 7.5%; Odorthreshold 5 0.0075°7.3 ppm.sec-isomer: Boiling point= 121℃; Melting/Freezingpoint=2 148℃; Critical temperature= 326℃; Criticalpressure= 411.6 psia 5 28.0 atm 5 2.83 MN/m2; Specificgravity= 0.861°0.866 at 20℃; Liquid surface tension 5 28.9 dynes/cm 5 0.0289 N/m at 20℃; Liquidwater interfacial tension 5 (estimate) 0.0441 N/m at20℃; Relative vapor density (air= 1) 5 4.5; Ratio of specific heats of vapor (gas) 5 (estimate).1°1.1 at 20℃;Latent heat of vaporization= (estimate) 5 3.0 3 105 J/kg;Heat of combustion 5 2 14.402 Btu/lb 5 2 8000cal/g 5 2 334.9 3 105 J/kg; Vapor pressure= 7 mmHg at20℃; Flash point= 32℃; Explosive limits: LEL 5 1.1%;UEL 5 7.0%; Odor threshold 5 0.002 ppm.tert-isomer: Boiling point= 125℃; Flash point= 26℃;Explosive limits: LEL 5 1.0%; UEL 5 7.5%; Odor threshold 5 0.08 *0.0006 in water.iso-isomer: Boiling point= 142℃; Melting/Freezingpoint=2 78.5℃; Critical temperature 326.1℃; Criticalpressure= 2.84 MN/m2; Specific gravity= 0.876 at 15℃;Liquid surface tension= 5 0.02477 N/m at 20℃; Liquid waterinterfacial tension5 0.0502 N/m at 15℃; Relative vapor density (air= 1) 5 4.5; Ratio of specific heats of vapor (gas) 5(estimate).1°1.1; Latent heat of vaporization= (estimate) 53.07 3 105 J/kg; Heat of combustion 5 2 334.9 3 105 J/kg;Vapor pressure= 4 mmHg at 20℃; Autoignitiontemperature5 379℃; Flash point= 25℃; Autoignitiontemperature5 379℃; Explosive limits: LEL5 1.2% at 100℃;UEL 5 7.5%; Odor threshold 5 0.015.They all float on water and have poor (slight to negligible)solubility. Water contact forms a flammable, irritatingvapor. Hazard Identification (based on NFPA-704 M RatingSystem): Health 1, Flammability 3, Reactivity 0.*The range of accepted odor threshold values is quite broadand caution should be used in relying on odor alone as awarning of potentially hazardous exposure.

• Chemische Eigenschaften

  All isomers of amyl acetate are highly flammable, colorless to yellow, watery liquids.

• Physikalische Eigenschaften

  Colorless liquid with a sweet, banana-like odor. A detection odor threshold concentration of 275 μg/m³ (52 ppb_v) was reported by Punter (1983). Cometto-Mu?iz and Cain (1991) reported an average nasal pungency threshold concentration of 1,650 ppm_v.

• Verwenden

  A colorless liquid made by adding sulfuric acid to a mixture of amyl alcohol and acetic acid with subsequent recovery by distillation. It is slightly soluble in water but insoluble in alcohol. Amyl acetate was used as one of the solvents in making celluloid film and as fuel for the Alteneck lamp, adopted as the standard light in sensitometry by the International Congress of Photography in 1889.

• Verwenden

  Banana essence. Used as test odorant in studies of olfactory function and in studies of the psychosocial effects of odor.

• Verwenden

  n-Amyl acetate is used as a solvent forlacquers and paints; in fabrics’ printing; innail polish; and as a flavoring agent.

• Vorbereitung Methode

  n-Amyl acetate is the produced by the esterification of N-amyl alcohol with acetic acid.

• Definition

  ChEBI: An acetate ester of pentanol.

• Synthesis Reference(s)

  Synthetic Communications, 21, p. 1545, 1991 DOI: 10.1080/00397919108021051
  Tetrahedron Letters, 50, p. 395, 2009 DOI: 10.1016/j.tetlet.2008.11.024
  The Journal of Organic Chemistry, 45, p. 2915, 1980 DOI: 10.1021/jo01302a035

• Allgemeine Beschreibung

  A mixture of isomers. A clear colorless liquid with a banana-like odor. Flash point varies from 65°F. to 95°F. Less dense (at 7.2 lb / gal) than water and slightly soluble in water. Hence floats on water. Vapors heavier than air.

• Air & Water Reaktionen

  Highly flammable. Slightly soluble in water.

• Reaktivität anzeigen

  AMYL ACETATE is an ester. Esters react with acids to liberate heat along with alcohols and acids. Strong oxidizing acids may cause a vigorous reaction that is sufficiently exothermic to ignite the reaction products. Heat is also generated by the interaction of esters with caustic solutions. Flammable hydrogen is generated by mixing esters with alkali metals and hydrides. Amyl acetate is incompatible with the following: Nitrates; strong oxidizers, alkalis & acids .

• Hazard

  Flammable, high fire risk. Explosive limits in air 1.1–7.5%.

• Health Hazard

  n-Amyl acetate is a narcotic, an irritant tothe eyes and respiratory passage, and at highconcentrations, an anesthesia. Exposure toabout 300 ppm in air for 30 minutes mayproduce eye irritation in humans. Higherconcentrations (>1000 ppm) may produceheadache, somnolence, and narcotic effects.Exposure to 5200 ppm for 8 hours was lethalto rats. It is more toxic than the loweraliphatic esters. An LD50 value in rats iswithin the range 6000 mg/kg.

• Brandgefahr

  HIGHLY FLAMMABLE: Will be easily ignited by heat, sparks or flames. Vapors may form explosive mixtures with air. Vapors may travel to source of ignition and flash back. Most vapors are heavier than air. They will spread along ground and collect in low or confined areas (sewers, basements, tanks). Vapor explosion hazard indoors, outdoors or in sewers. Runoff to sewer may create fire or explosion hazard. Containers may explode when heated. Many liquids are lighter than water.

• Chemische Reaktivität

  Reactivity with Water No reaction; Reactivity with Common Materials: No reaction; Stability During Transport: Stable; Neutralizing Agents for Acids and Caustics: Not pertinent; Polymerization: Not pertinent; Inhibitor of Polymerization: Not pertinent.

• Sicherheitsprofil

  Moderately toxic by intraperitoneal route. Human systemic effects by inhalation: conjunctiva irritation, headache, and somnolence. A human eye irritant. Apparently more toxic than butyl acetate. Chronic toxicity is of a low order. Dangerous fire hazard when exposed to heat or flame; can react with oxidizing materials. Moderately explosive in the form of vapor when exposed to flame. To fight fire, use alcohol foam, dry chemical. When heated to decomposition it emits acrid smoke and irritating fumes. See also ESTERS, AMYL ALCOHOL, and ACETIC ACID.

• mögliche Exposition

  (n-isomer): Primary irritant (w/o allergic reaction), (sec-isomer) Human Data. Amyl acetates are used as industrial solvents and in the manufacturing and dry-cleaning industry; making artificial fruit-flavoring agents; cements, coated papers, lacquers; in medications as an inflammatory agent; pet repellents, insecticides and miticide. Many other uses.

• Erste Hilfe

  If this chemical gets into the eyes, remove anycontact lenses at once and irrigate immediately for at least15 min, occasionally lifting upper and lower lids. Seekmedical attention immediately. If this chemical contactsthe skin, remove contaminated clothing and wash immediately with soap and water. Seek medical attention immediately. If this chemical has been inhaled, remove fromexposure, begin rescue breathing (using universal precautions, including resuscitation mask) if breathing hasstopped and CPR if heart action has stopped. Transferpromptly to a medical facility. When this chemical hasbeen swallowed, get medical attention. Give large quantities of water and induce vomiting. Do not make an unconscious person vomit.

• Carcinogenicity

  Not listed by ACGIH, California Proposition 65, IARC, NTP, or OSHA.

• Source

  Identified among 139 volatile compounds identified in cantaloupe (Cucumis melo var. reticulates cv. Sol Real) using an automated rapid headspace solid phase microextraction method (Beaulieu and Grimm, 2001).

• Environmental Fate

  Chemical/Physical. Hydrolyzes in water forming acetic acid and 1-pentanol.
  At an influent concentration of 985 mg/L, treatment with GAC resulted in an effluent concentration of 119 mg/L. The adsorbability of the carbon used was 175 mg/g carbon (Guisti et al., 1974).

• Lager

  Color Code—Red: Flammability Hazard: Store ina flammable liquid storage area or approved cabinet awayfrom ignition sources and corrosive and reactive materials.Prior to working with this chemical you should be trained onits proper handling and storage. Before entering confinedspace where amyl acetates may be present, check to makesure that an explosive concentration does not exist. Store intightly closed containers in a cool, well-ventilated area, preferably a detached shed. Metal containers involving the transfer of this chemical should be grounded and bonded. Wherepossible, automatically pump liquid from drums or otherstorage containers to process containers. Drums must beequipped with self-closing valves, pressure vacuum bungs,and flame arresters. Use only nonsparking tools and equipment, especially when opening and closing containers ofthis chemical. Sources of ignition, such as smoking andopen flames, are prohibited where this chemical is used,handled, or stored in a manner that could create a potentialfire or explosion hazard.

• Versand/Shipping

  UN1993 Flammable liquids, n.o.s., Hazard Class: 3; Labels: 3-Flammable liquid, Technical Name Required.

• läuterung methode

  Shake the ester with saturated NaHCO3 solution until neutral, washed it with water, dry with MgSO4 and distil it. The ester has also been purfied by repeated fractional distillation through an efficient column or spinning band column. [Timmermann & Hennant-Roland J Chim Phys 52 223 1955, Mumford & Phillips J Chem Soc 75 1950, 1H NMR: Crawford & Foster Can J Phys 34 653 1956, Beilstein 2 IV 152.]

• Inkompatibilitäten

  Vapors may form explosive mixture with air. Incompatible with oxidizers (chlorates, nitrates, peroxides, permanganates, perchlorates, chlorine, bromine, fluorine, etc.); contact may cause fires or explosions. Keep away from alkaline materials, strong bases, strong acids, oxoacids, epoxides, nitrates. May soften certain plastics.

• Filter für giftige stoffe

  The ITSL of 1100 μg/m3 with 24 hour averaging is being adopted for the amyl acetate isomer mixture by AQD at this time.

• Waste disposal

  Dissolve or mix the material with a combustible solvent and burn in a chemical incinerator equipped with an afterburner and scrubber. All federal, state, and local environmental regulations must be observed. In accordance with 40CFR165, follow recommendations for the disposal of pesticides and pesticide containers. Must be disposed properly by following package label directions or by contacting your local or federal environmental control agency, or by contacting your regional EPA office.

Amyl acetate Upstream-Materialien And Downstream Produkte

Pentylacetat Anbieter Lieferant Produzent Hersteller Vertrieb Händler.

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