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tert-Butyl bromoacetate
- Product Name:tert-Butyl bromoacetate
- Synonyms: 1-Butylbromoacetate Acetic acid, bromo-, tert-butyl ester aceticacid,bromo-,1,1-dimethylethylester BrCH2C(O)OC(CH3)3 2-BROMOACETIC ACID-TERT-BUTYL ESTER BROMOACETIC ACID TERT-BUTYL ESTER BUTYLBROMOACETATE-TERT TERT-BUTYL 2-BROMOACETATE
- CAS:5292-43-3
- MF:C6H11BrO2
- MW:195.05
- EINECS:226-133-6
- Product Categories: ACID BASED BROMO COMPOUNDS C6 to C7 Carbonyl Compounds Esters organic chemical Building Blocks C6 to C7 Carbonyl Compounds Chemical Synthesis Organic Building Blocks Pharmaceutical intermediates
- Mol File:5292-43-3.mol
-
tert-Butyl bromoacetate Chemical Properties
- Boiling point:50 °C10 mm Hg(lit.)
- Density 1.338
- refractive index n
20/D 1.445(lit.)
- Flash point:121 °F
- storage temp. 0-6°C
- form Liquid
- Specific Gravity1.333 (20/4℃)
- color Clear colorless to yellow
- Water Solubility Miscible with ethanol, chloroform and ethyl acetate. Immiscible with water.
- Sensitive Lachrymatory
- BRN 1753010
- InChIKeyBNWCETAHAJSBFG-UHFFFAOYSA-N
- CAS DataBase Reference5292-43-3(CAS DataBase Reference)
- NIST Chemistry ReferenceAcetic acid, bromo-, 1,1-dimethylethyl ester(5292-43-3)
- EPA Substance Registry SystemAcetic acid, bromo-, 1,1-dimethylethyl ester(5292-43-3)
- Hazard Codes Xi,F
- Risk Statements 10-36/37/38
- Safety Statements 26-24/25-16
- RIDADR UN 1993 3/PG 3
- WGK Germany 3
- F 19
- Hazard Note Irritant/Flammable/Lachrymatory
- TSCA T
- HazardClass 3
- PackingGroup III
- HS Code 29159080
- Language:EnglishProvider:t-Butyl 2-bromo acetate
- Language:EnglishProvider:SigmaAldrich
- Language:EnglishProvider:ACROS
- Language:EnglishProvider:ALFA
tert-Butyl bromoacetate Usage And Synthesis
- Chemical Propertiesclear colorless to yellow liquid
- Usestert-Butyl Bromoacetate is a halogenated t-butyl acetate commonly used as an alkylating agent. tert-Butyl Bromoacetate is used in the synthesis of collagenase inhibitors.
- Purification MethodsDissolve the ester in Et2O, wash it well with ice cold 10% aqueous K2CO3, dry it over CaCl2, filter and evaporate the Et2O, then fractionate it through a Vigreux column (p 11) in a vacuum. LACHRYMATORY. [Abramovitch et al. J Am Chem Soc 64 2274 1942, Abramovitch & Hauser J Am Chem Soc 65 986 1943, Beilstein 2 III 482.]
tert-Butyl bromoacetate Preparation Products And Raw materials
- 1,5-Dibromopentane Ethyl bromoacetate Butyl acetate BUTYL OLEATE tert-Butanol CELLULOSE ACETATE Buprofezin tert-Butyl chloroacetate tert-Butyl cyanoacetate Methyl acrylate tert-Butyl carbazate TRIS(TRIMETHYLSILYL) PHOSPHATE TERT-BUTYL 2,4-DIBROMOBUTYRATE 2-BROMOPROPIONIC ACID TERT-BUTYL ESTER tert-Butyl bromoacetate Dibutyl phthalate Bromine Ammonium acetate
tert-Butyl bromoacetateSupplierMore
- Company Name:Yancheng Longshen Chemical Co.,Ltd. Gold
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- Company Name:Nanjing Vital Chemical Co., Ltd. Gold
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- Company Name:Kingfirst Chemical (Nanjing) Co.,Ltd Gold
- Tel:+86-025-84522992 84524602 13805186390
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About tert-Butyl bromoacetate
Aug 19，2019