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Benzenesulfonic acid

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Benzenesulfonic acid Basic information
Benzenesulfonic acid Chemical Properties
  • Melting point:30-60 °C
  • Boiling point:137℃
  • Density 1.32
  • refractive index 1.5151 (estimate)
  • Flash point:>230 °F
  • storage temp. Store below +30°C.
  • solubility H2O: soluble0.1g/10 mL, clear, colorless
  • form Damp Crystalline Solid or Fused Mass
  • pka0.7(at 25℃)
  • color Yellow to light brown
  • PH2 (H2O, 20℃)(saturated solution)
  • Water Solubility soluble
  • Sensitive Hygroscopic
  • Merck 14,1070
  • BRN 742513
  • Stability:Stable. Incompatible with strong oxidizing agents, bases, many organic compounds.
  • InChIKeySRSXLGNVWSONIS-UHFFFAOYSA-N
  • CAS DataBase Reference98-11-3(CAS DataBase Reference)
  • NIST Chemistry ReferenceBenzenesulfonic acid(98-11-3)
  • EPA Substance Registry SystemBenzenesulfonic acid(98-11-3)
Safety Information
  • Hazard Codes C
  • Risk Statements 22-34
  • Safety Statements 26-36/37/39-45-36
  • RIDADR UN 2583 8/PG 2
  • WGK Germany 1
  • RTECS DB4200000
  • TSCA Yes
  • HazardClass 8
  • PackingGroup III
  • HS Code 29041000
  • Hazardous Substances Data98-11-3(Hazardous Substances Data)
  • ToxicityLD50 orally in Rabbit: 1175 mg/kg
MSDS
Benzenesulfonic acid Usage And Synthesis
  • DescriptionBenzene sulfonic acid is an organo sulfur compound with the formula C6H5SO3H. It is the simplest aromatic sulfonic acid. It forms colorless deliquescent sheet crystals or a white waxy solid that is soluble in water and ethanol, slightly soluble in benzene and insoluble in carbon disulfide and diethyl ether. It is often stored in the form of alkali metal salts. Its aqueous solution is strongly acidic.
  • Chemical Propertiesgreen solid
  • DefinitionChEBI: The simplest member of the class of a benzenesulfonic acids that consists of a benzene carrying a single sulfo group.
  • DefinitionA white crystalline acid made by sulfonation of benzene. Any further substitution onto the benzene ring is directed into the 3 position.
  • Definitionbenzenesulphonic acid: A colourlessdeliquescent solid, C6H5SO2OH,m.p. 43–44°C, usually found as anoily liquid. It is made by treating benzenewith concentrated sulphuricacid. Its alkyl derivatives are used asdetergents.
  • ApplicationThe alkali metal salt of benzene sulfonic acid was once widely used in the production of phenol :
    C6H5SO3Na + 2 NaOH → C6H5ONa + Na2SO3
    C6H5ONa + HCl → C6H5OH + NaCl
    The process has been largely displaced by the Hock process, which generates less waste. Benzene sulfonic acid is mainly consumed by conversion to other specialty chemicals. A variety of pharmaceutical drugs are prepared as salts of benzene sulfonic acid and are known as besylates or besilates.
  • PreparationBenzene sulfonic acid is prepared from the sulfonation of benzene using concentrated sulfuric acid :
    This conversion illustrates aromatic sulfonation, which has been called "one of the most important reactions in industrial organic chemistry.".
  • ReactionsBenzene sulfonic acid exhibits the reactions typical of other aromatic sulfonic acids, forming sulfonamides , sulfonyl chloride, and esters. The sulfonation is reversed above 220 °C. Dehydration with phosphorus pentoxide gives benzene sulfonic acid anhydride ((C6H5SO2)2O). Conversion to the corresponding benzene sulfonyl chloride (C6H5SO2Cl) is effected with phosphorus penta chloride. It is a strong acid, being dissociated in water.
  • General DescriptionDeliquescent needles or large plates.
  • Air & Water ReactionsSlightly soluble in water.
  • Reactivity ProfileBenzenesulfonic acid reacts with bases and many organic compounds.
  • Fire HazardFlash point data for Benzenesulfonic acid are not available, however Benzenesulfonic acid is probably combustible.
  • Safety ProfilePoison by ingestion, sbn contact, and probably inhalation. A severe skin and eye irritant. See also SULFATES and SULFONATES.
  • Purification MethodsPurify benzenesulfonic acid by dissolving it in a small volume of distilled H2O and stirring with slightly less than the theoretical amount of BaCO3. When effervescence is complete and the solution is still acidic, filter off the insoluble barium benzenesulfonate. The salt is collected and dried to constant weight in vacuo, then suspended in H2O and stirred with a little less than the equivalent (half mol.) of sulfuric acid. The insoluble BaSO4 (containing a little barium benzenesulfonate) is filtered off and the filtrate containing the free acid is evaporated in a high vacuum. The oily residue will eventually crystallise when completely anhydrous. A 32% commercial acid is allowed to fractionally crystallise at room temperature over P2O5 in a vacuum desiccator giving finally colourless deliquescent plates m 52.5o. The anhydrous crystalline acid is deliquescent and should be stored over anhydrous Na2SO4 in the dark and should be used in subdued sunlight as it darkens under sunlight. The main impurity is Fe which readily separates as the Fe salt in the early fractions [Taylor & Vincent J Chem Soc 3218 1952]. The S-benzylisothiuronium salt has m 148o (from EtOH/H2O). It is an IRRITANT to the skin and eyes. [See Adams & Marvel Org Synth Coll Vol I 84 1941, Michael & Adair Chem Ber 10 585 1877, Beilstein 11 IV 27.]
Benzenesulfonic acid Preparation Products And Raw materials
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