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(Trifluoromethyl)trimethylsilane

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(Trifluoromethyl)trimethylsilane Basic information
(Trifluoromethyl)trimethylsilane Chemical Properties
  • Boiling point:54-55 °C(lit.)
  • Density 0.962 g/mL at 20 °C(lit.)
  • vapor pressure 10.98 psi ( 55 °C)
  • refractive index n20/D 1.386
  • Flash point:14 °F
  • storage temp. 2-8°C
  • form Liquid
  • color Clear colorless
  • Specific Gravity0.962
  • Water Solubility Soluble in alcohol, THF, ether, dichloromethane, aromatic and aliphatic hydrocarbons. Soluble in water(with white smokes).
  • Sensitive Moisture Sensitive
  • Hydrolytic Sensitivity4: no reaction with water under neutral conditions
  • Merck 14,9683
  • BRN 4241868
  • InChIKeyMWKJTNBSKNUMFN-UHFFFAOYSA-N
  • CAS DataBase Reference81290-20-2(CAS DataBase Reference)
Safety Information
MSDS
(Trifluoromethyl)trimethylsilane Usage And Synthesis
  • Chemical Propertiesclear colorless solution
  • UsesNucleophilic addition of the trifluoromethyl group to aldehydes and ketones.1
  • UsesNucleophilic trifluoromethylating reagent.
  • UsesSilicon-based fluorinating reagents for the efficient trifluoromethylation of carbonyls and ethylene diamines. Precursors used for metal-mediated trifluoromethylation of aromatic, heteroaromatic, vinyl substrates, etc.
  • Purification MethodsPurify it by distilling it from trap to trap in a vacuum of 20mm using a bath at 45o and Dry-ice/Me2CO bath for the trap. The liquid in the trap is then washed with ice cold H2O (3x), the top layer is collected, dried (Na2SO4), and the liquid is decanted and fractionated through a helices-packed column at atmospheric pressure. 1H, 1 3C, 1 9F, and 2 9Si NMR can be used for assessing the purity of fractions. [Ruppert et al. Tetrahedron Lett 25 2195 1984, Krishnamurti et al. J Org Chem 56 984 199, Beilstein 4 IV 3892.]
(Trifluoromethyl)trimethylsilane Preparation Products And Raw materials
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