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(3S,4R)-4-Acetoxy-3-[(R)-1-(tert-butyldimethylsilyloxy)ethyl]azetidin-2-one Structure

(3S,4R)-4-Acetoxy-3-[(R)-1-(tert-butyldimethylsilyloxy)ethyl]azetidin-2-one

Chemical Properties

Melting point 107-109 °C(lit.)
alpha  51 º (c=1, chloroform)
Boiling point 358.3±27.0 °C(Predicted)
Density  1.03±0.1 g/cm3(Predicted)
storage temp.  2-8°C
solubility  almost transparency in Methanol
form  powder to crystal
pka 12.86±0.60(Predicted)
color  White to Almost white
optical activity [α]20/D +51°, c = 1 in chloroform
InChI InChI=1S/C13H25NO4Si/c1-8(18-19(6,7)13(3,4)5)10-11(16)14-12(10)17-9(2)15/h8,10,12H,1-7H3,(H,14,16)/t8-,10+,12-/m1/s1
InChIKey GWHDKFODLYVMQG-UBHAPETDSA-N
SMILES N1[C@H](OC(C)=O)[C@@H]([C@H](O[Si](C(C)(C)C)(C)C)C)C1=O
CAS DataBase Reference 76855-69-1(CAS DataBase Reference)

Safety Information

Hazard Codes  Xi,N
Risk Statements  36-43-51/53
Safety Statements  24-26-37-61
RIDADR  UN 3077 9/PG 3
WGK Germany  2
HazardClass  9
PackingGroup  III
HS Code  29337900
Storage Class 11 - Combustible Solids
Hazard Classifications Aquatic Chronic 2
Eye Irrit. 2
Skin Sens. 1

MSDS

Usage And Synthesis

(3S,4R)-4-Acetoxy-3-[(R)-1-(tert-butyldimethylsilyloxy)ethyl]azetidin-2-one Supplier