Anisaldehyd Produkt Beschreibung

p-Anisaldehyde Struktur
123-11-5
  • CAS-Nr.123-11-5
  • Bezeichnung:Anisaldehyd
  • Englisch Name:p-Anisaldehyde
  • Synonyma:Anisaldehyd
    PMOB;Anisal;Obepin;AUBEPINE;NSC 5590;123-11-5;p-AnisaL;FEMA 2670;AUBE'PINE;Aubépine
  • CBNumber:CB7491195
  • Summenformel:C8H8O2
  • Molgewicht:136.15
  • MOL-Datei:123-11-5.mol
Anisaldehyd physikalisch-chemischer Eigenschaften
  • Schmelzpunkt: :-1 °C
  • Siedepunkt: :248 °C(lit.)
  • Dichte :1.121
  • Dampfdichte :4.7 (vs air)
  • Dampfdruck :<1 hPa (20 °C)
  • FEMA  :2670 | P-METHOXYBENZALDEHYDE
  • Brechungsindex :n20/D 1.573(lit.)
  • Flammpunkt: :228 °F
  • storage temp.  :Store below +30°C.
  • Löslichkeit :2g/l
  • Aggregatzustand :Liquid
  • Farbe :Clear colorless to yellow
  • PH :7 (2g/l, H2O, 20℃)
  • Geruch (Odor) :sweetish odor
  • Explosionsgrenze :1.4-5.3%(V)
  • Wasserlöslichkeit :Miscible with acetone, alcohol, ether, chloroform and benzene. Immiscible with water.
  • Decomposition  :> 160°C
  • Sensitive  :Air Sensitive
  • Merck  :14,663
  • JECFA Number :878
  • BRN  :471382
  • InChIKey :ZRSNZINYAWTAHE-UHFFFAOYSA-N
  • CAS Datenbank :123-11-5(CAS DataBase Reference)
  • NIST chemische Informationen :Benzaldehyde, 4-methoxy-(123-11-5)
  • EPA chemische Informationen :Benzaldehyde, 4-methoxy- (123-11-5)
Sicherheit

p-Anisaldehyde Chemische Eigenschaften,Einsatz,Produktion Methoden

  • R-Sätze Betriebsanweisung: R22:Gesundheitsschädlich beim Verschlucken.
    R36/37/38:Reizt die Augen, die Atmungsorgane und die Haut.
    R39/23/24/25:Giftig: ernste Gefahr irreversiblen Schadens durch Einatmen, Berührung mit der Haut und durch Verschlucken.
    R23/24/25:Giftig beim Einatmen, Verschlucken und Berührung mit der Haut.
    R11:Leichtentzündlich.
  • S-Sätze Betriebsanweisung: S26:Bei Berührung mit den Augen sofort gründlich mit Wasser abspülen und Arzt konsultieren.
    S36:DE: Bei der Arbeit geeignete Schutzkleidung tragen.
    S45:Bei Unfall oder Unwohlsein sofort Arzt zuziehen (wenn möglich, dieses Etikett vorzeigen).
    S36/37:Bei der Arbeit geeignete Schutzhandschuhe und Schutzkleidung tragen.
    S16:Von Zündquellen fernhalten - Nicht rauchen.
    S7:Behälter dicht geschlossen halten.
  • Beschreibung p-Methoxybenzaldehyde has a characteristic hawthorne odor and a pungent, anise-like flavor. It has a bitter flavor above 30 - 40 ppm. May be prepared by methylation and oxidation of p-cresol and also by oxidation of anethole.
  • Chemische Eigenschaften p-Methoxybenzaldehyde has a sweet, floral odor and a pungent, anise-like flavor. It has a bitter flavor above 30 to 40 ppm.
  • Chemische Eigenschaften clear colorless to pale yellowish liquid
  • Chemische Eigenschaften p-Anisaldehyde occurs in many essential oils, often together with anethole. It is a colorless to slightly yellowish liquid with a sweet, mimosa, hawthorn odor. p-Anisaldehyde can be hydrogenated to anise alcohol and readily oxidizes to anisic acid when exposed to air. Synthetic routes to anisaldehyde start from p-cresyl methyl ether, which is oxidized, for example, by manganese dioxide or by oxygen or peroxy compounds in the presence of transition metal catalysts .
    Another industrial process uses electrochemical oxidation in the presence of lower aliphatic alcohols via the corresponding anisaldehyde dialkyl acetal . Anisaldehyde may also be produced by methylation of 4-hydroxybenzaldehyde, which is easily obtained by oxidation of p-cresol or by Vilsmeier formylation of anisol.
  • Occurrence Reported found in essential oils and extracts of vanilla, Acacia farmesiana Willd., Magnoila salicifolia Maxim., Erica arborea, Pirus communis, Boswellia serrata, and others; also in anise, fennel and star anise (especially when aged due to the oxidation of anethole), cranberry, black currant, cinnamon and basil.
  • Verwenden p-Anisaldehyde is a flavoring agent that is a colorless or faintly yellow liquid, hawthorn-like odor. It is miscible in alcohol, ether, and most fixed oils, soluble in propylene glycol, insoluble in glycerin, water, and mineral oil. It is obtained by synthesis. It is also termed anise aldehyde and p-methoxybenzaldehyde.
  • Verwenden Perfumery and toilet soaps; odor resembles that of coumarin, but the aldehyde must be mixed with other odorous substances to yield an agreeable odor. Also used in organic syntheses.
  • synthetische By methylation and oxidation of p-cresol and also by oxidation of anethole.
  • Aroma threshold values Aroma characteristics at 1.0%: sweet powdery, spicy creamy, fruity, vanilla and hay-like. Coumarin, almond, anisic with berry nuances.
  • Taste threshold values Taste characteristics at 5 to 10 ppm: sweet powdery, vanilla creamy, spice anise, nutty, cherry pit and almond-like nuances.
  • Synthesis Reference(s) Chemical and Pharmaceutical Bulletin, 42, p. 1041, 1994 DOI: 10.1248/cpb.42.1041
    Tetrahedron Letters, 43, p. 1395, 2002 DOI: 10.1016/S0040-4039(02)00027-8
  • Sicherheitsprofil Moderately toxic by ingestion. A skin irritant. Mutation data reported. Combustible liquid. When heated to decomposition it emits acrid smoke and irritating fumes
  • Stoffwechsel Anisic aldehyde undergoes a very slight degree of demethylation with oxidation of its aldehyde group to an acid group, the major metabolite excreted being anisic acid (Williams, 1959).
  • läuterung methode Wash the aldehyde with saturated aqueous NaHCO3, then H2O, steam distil, extract the distillate with Et2O, dry (MgSO4) the extract, filter and distil this under a vacuum and N2. Store it in glass ampules under N2 in the dark. [Beilstein 8 IV 252.]
p-Anisaldehyde Upstream-Materialien And Downstream Produkte
Upstream-Materialien
Downstream Produkte
Anisaldehyd Anbieter Lieferant Produzent Hersteller Vertrieb Händler.
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123-11-5, p-Anisaldehyde Verwandte Suche:
  • Natural p-Anisaldehyde
  • Anisaldehyde test solution(ChP)
  • Анисовый альдегид, Кратежин, 4-Methoxybenzaldehyde, p-Anisaldehyde, Anisic aldehyde, Anisaldehyde
  • LABOTEST-BB LT00920037
  • 4-ANISALDEHYDE
  • AKOS BBS-00003185
  • ANISALDEHYDE extrapure
  • 4-Methoxybenzaldehyde, p-Anisaldehyde, Aub&#x00e9:pine
  • Anisaldehyde solution
  • p-Methoxybenzafdehyde
  • P-METHOXYBENZALDEHYDE
  • PARA ANISALDEHYDE
  • PARA ANISIC ALDEHYDE
  • P-ANISALDEHYDE
  • P-ANISIC ALDEHYDE
  • FEMA 2670
  • AUBEPINE
  • AUBE'PINE
  • ANISALDEHYDE
  • ANISALDEHYDE,4-
  • ANISIC ALDEHYDE-P
  • ANISIC ALDEHYDE
  • p-Anisaldehyde (contains Acetic Acid, H2SO4) Ethanol Solution [for TLC Stain]
  • 4-Methoxybenzaldehyde, Aub&#x00e9:pine
  • Anisic aldehyde,Anisaldehyde,p-Anisic aldehyde,p-Methoxybenzaldehyde
  • p-methoxybenzaldehyde(p-Anisaldehyde, 99.5%)
  • 4-Methoxybenzaldehyde
  • p-Anisaldehyde,4-Methoxybenzaldehyde, Aubépine
  • 4-Methoxybenzaldehyde, extra pure
  • 4-Methoxybenzaldehyde,4-Methoxybenzaldehyde, p-Anisaldehyde, Aubépine
  • NSC 5590
  • p-Anisaldehyde, 99+% 100ML
  • p-Anisaldehyde, 99+% 500ML
  • p-Anisaldehyde, 99+% 5ML
  • p-Anisaldehyde 98%
  • p-Anisaldehyde (contains Acetic Acid, H2SO4) Ethanol Solution
  • <i>p</i>-Anisaldehyde
  • 123-11-5
  • p-methoxybenzaldehyde,Anisaldehyde ,
  • 4-methoxy-benzaldehyd
  • Anisal
  • Benzaldehyde,4-methoxy-
  • Methyl-p-oxybenzaldehyde
  • Obepin
  • p-Formylanisole
  • 4-Methoxybenzaldehyde for synthesis
  • Aubépine
  • 4-Methoxybenzaldehyde/p-Anisaldehyde
  • 4-Methoxybenzylaldehyde
  • Anisaldehyde 98+ %
  • AnisaldehydeMetoxybenzaldehyd
  • p-methoxybezaldehyde
  • P-methyoxybenzaldehyde
  • ANISALDEHYDE, STANDARD FOR GC
  • P-ANISALDEHYDE 97.5+% FCC
  • Anis Aldehyde FCC
  • P-Methoxybenzaldehyde136.15
  • AnisaldehydePure