ChemicalBook CAS DataBase List 87-60-5

87-60-5

Name	3-Chloro-2-methylaniline
CAS	87-60-5
EINECS(EC#)	201-756-6
Molecular Formula	C7H8ClN
MDL Number	MFCD00007766
Molecular Weight	141.6
MOL File	87-60-5.mol

Synonyms

2-AMINO-6-CHLOROTOLUENE 3-CHLORO-2-METHYLANILINE 3-chloro-2-methylbenzenamine 3-CHLORO-O-TOLUIDINE 6-CHLORO-2-AMINO TOLUENE 6-CHLORO-2-TOLUIDINE 6COT AKOS BBS-00003567 Azoic Diazo Component 46 CI 37080 FAST SCARLET TR BASE LABOTEST-BB LTBB000775 TIMTEC-BB SBB007550 1-Amino-3-chloro-2-methylbenzene 2-amino-6-chloro-toluen 2-Methyl-3-chloroaniline 3-Chlor-2-toluidin 3-chloro-2-methyl-benzenamin 3-Chloro-2-methylphenylamine 3-chloro-2-toluidin(czech)

Chemical Properties

Appearance	The chloromethylanilines are colorless or white crystalline solids or liquids, some have a mild fishy odor.
Melting point	2 °C (lit.)
Boiling point	115-117 °C/10 mmHg (lit.)
density	1.185 g/mL at 25 °C(lit.)
refractive index	n20/D 1.588(lit.)
Fp	>230 °F
storage temp.	Store below +30°C.
solubility	4.5g/l
form	Liquid
pka	pK1:2.49(+1) (25°C)
color	Clear yellow to red or red-brown
Specific Gravity	1.19
Water Solubility	1g/L at 20℃
BRN	471697
InChI	1S/C7H8ClN/c1-5-6(8)3-2-4-7(5)9/h2-4H,9H2,1H3
InChIKey	ZUVPLKVDZNDZCM-UHFFFAOYSA-N
SMILES	Cc1c(N)cccc1Cl
LogP	2.4
CAS DataBase Reference	87-60-5(CAS DataBase Reference)
NIST Chemistry Reference	Benzenamine, 3-chloro-2-methyl-(87-60-5)
EPA Substance Registry System	87-60-5(EPA Substance)

Safety Data

Hazard Codes	C,N,Xn
Risk Statements	R22:Harmful if swallowed. R34:Causes burns. R43:May cause sensitization by skin contact. R51/53:Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment . R36/37/38:Irritating to eyes, respiratory system and skin . less more
Safety Statements	S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice . S36/37/39:Wear suitable protective clothing, gloves and eye/face protection . S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) . S61:Avoid release to the environment. Refer to special instructions safety data sheet . S37/39:Wear suitable gloves and eye/face protection . less more
RIDADR	UN 3429 6.1/PG 3
WGK Germany	2
RTECS	XU4760000
TSCA	Yes
HazardClass	6.1
PackingGroup	III
HS Code	29214300
Storage Class	6.1C - Combustible acute toxic Cat.3 toxic compounds or compounds which causing chronic effects
Hazard Classifications	Acute Tox. 4 Oral Resp. Sens. 1 Skin Corr. 1B
Safety Profile	Poison by ingestion. Mutation data reported. When heated to decomposition it emits toxic fumes of Cl and NOx. See also other chloro toluidine entries. less more
Hazardous Substances Data	87-60-5(Hazardous Substances Data)

Raw materials And Preparation Products

Hazard Information

Potential Exposure

Most of the isomers are used in dyestuff manufacture. The 3-chloro-para isomer is used to kill birds. It is marketed as pelleted bait for control of bird populations.

First aid

If this chemical gets into the eyes, remove any contact lenses at once and irrigate immediately for at least 15 minutes, occasionally lifting upper and lower lids. Seek medical attention immediately. If this chemical contacts the skin, remove contaminated clothing and wash immediately with soap and water. Seek medical attention immediately. If this chemical has been inhaled, remove from exposure, begin rescue breathing (using universal precautions, including resuscitation mask) if breathing has stopped and CPR if heart action has stopped. Transfer promptly to a medical facility. When this chemical has been swallowed, get medical attention. Give large quantities of water and induce vomiting. Do not make an unconscious person vomit.

Shipping

UN2239 Chlorotoluidines, solid, Hazard Class: 6.1; Labels: 6.1-Poisonous materials. UN3429 Chlorotoluidines, liquid, Hazard Class: 6.1; Labels: 6.1- Poisonous materials

Incompatibilities

Incompatible with oxidizers, strong acids; chloroformates, and acid anhydrides, isocyanates, aldehydes forming fire and explosive hazards.

Description

The chloromethylanilines are colorless orwhite crystalline solids or liquids, some have a mild fishyodor. Molecular weight (all isomers) =141.61. HazardIdentification (based on NFPA 704 M Rating System): (87-60-5) Health 2, Flammability 1, Reactivity 0. All are soluble in water and include:

Chemical Properties

clear yellow to red or red-brown liquid

Chemical Properties

The chloromethylanilines are colorless or white crystalline solids or liquids, some have a mild fishy odor.

Uses

Intermediate.

Preparation

By 1-Methyl-2-nitrobenzene chlorination byproducts 3-Chloro-2-methylbenzenamine?reduction.

Hazard

Toxic by ingestion or inhalation.

storage

Color Code—Blue: Health Hazard/Poison: Store ina secure poison location. Prior to working with chloromethylanilines you should be trained on its proper handling andstorage. Store in tightly closed containers in a cool, well-ventilated area. Sources of ignition, such as smoking and openflames, are prohibited where Choromethyl anilines are handled, or stored in a manner that could create a potential fireor explosion hazard. A regulated, marked area should beestablished where this chemical is handled, used, or stored incompliance with OSHA Standard 1910.1045.

References

[1] Materials Research Bulletin, 2013, vol. 48, # 5, p. 1885 - 1890
[2] Bulletin of the Korean Chemical Society, 2012, vol. 33, # 9, p. 2851 - 2852
[3] Patent: CN104725242, 2017, B. Location in patent: Paragraph 0026-0027
[4] Journal of the Chemical Society. Perkin Transactions 1, 2001, # 9, p. 955 - 977
[5] Synthetic Communications, 1981, vol. 11, # 11, p. 925 - 930

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87-60-5

Chemical Properties

Safety Data

Raw materials And Preparation Products

Raw materials

Preparation Products

Hazard Information

Potential Exposure

First aid

Shipping

Incompatibilities

Description

Chemical Properties

Chemical Properties

Uses

Preparation

Hazard

storage

References

Material Safety Data Sheet(MSDS)

Questions And Answer

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Spectrum Detail

Well-known Reagent Company Product Information

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