ChemicalBook CAS DataBase List 99-98-9

99-98-9

Name	N,N-Dimethyl-1,4-phenylenediamine
CAS	99-98-9
EINECS(EC#)	202-807-5
Molecular Formula	C8H12N2
MDL Number	MFCD00007860
Molecular Weight	136.19
MOL File	99-98-9.mol

Synonyms

4-AMINODIMETHYLANILINE 4-AMINO-N,N-DIMETHYLANILINE 4-ANIMODIMETHYLANILINE 4-DIMETHYLAMINOANILINE DIMETHYL(N,N-)-P-PHENYLENEDIAMINE Dimethyl-p-phenylenediamine N,N-DIMETHYL-1,4-PHENYLENEDIAMINE N,N-DIMETHYL-P-PHENYLENEDIAMINE P-AMINODIMETHYLANILINE P-DIMETHYLAMINOAZOBENZENE WURSTER'S RED 4-(dimethylamino)benzenamine 4-(dimethylamino)phenylamine 4-Benzenediamine,N,N-dimethyl-1 C.I. 76075 c.i.76075 ci76075 Crategine dimethyl-4-phenylenediamine Dimethyl-paraphenylenediamine

Chemical Properties

Appearance	grey to black solid
Melting point	34-36 °C(lit.)
Boiling point	262 °C(lit.)
density	1.09
refractive index	1.5914 (estimate)
Fp	130 °C
storage temp.	2-8°C
solubility	Chloroform (Slightly), Methanol (Slightly), Water (Slightly)
form	crystalline
pka	6?+-.0.12(Predicted)
color	black
Stability:	Stable. Incompatible with acid chlorides, acid anhydrides, strong acids, strong oxidizing agents. Combustible.
Water Solubility	11 g/L (20 ºC)
Sensitive	Light Sensitive
Merck	14,3254
BRN	508105
Cosmetics Ingredients Functions	HAIR DYEING
InChI	1S/C8H12N2/c1-10(2)8-5-3-7(9)4-6-8/h3-6H,9H2,1-2H3
InChIKey	BZORFPDSXLZWJF-UHFFFAOYSA-N
SMILES	CN(C)c1ccc(N)cc1
CAS DataBase Reference	99-98-9(CAS DataBase Reference)
NIST Chemistry Reference	1,4-Benzenediamine, N,N-dimethyl-(99-98-9)
Storage Precautions	Air sensitive;Light sensitive
EPA Substance Registry System	99-98-9(EPA Substance)

Safety Data

Symbol(GHS)	GHS06
Signal word	Danger
Hazard statements	H300+H310-H331
Precautionary statements	P262-P264-P280-P301+P310-P302+P352+P310-P304+P340+P311
Hazard Codes	T
Risk Statements	R23/24/25:Toxic by inhalation, in contact with skin and if swallowed . R36/37/38:Irritating to eyes, respiratory system and skin . less more
Safety Statements	S28:After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer) . S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) . S36/37/39:Wear suitable protective clothing, gloves and eye/face protection . S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice . less more
RIDADR	UN 2811 6.1/PG 2
WGK Germany	3
RTECS	ST0874000
F	8-10-23
Hazard Note	Toxic/Keep Cold
TSCA	Yes
HazardClass	6.1
PackingGroup	II
HS Code	29215900
Storage Class	6.1A - Combustible acute toxic Cat. 1 and 2 very toxic hazardous materials
Hazard Classifications	Acute Tox. 1 Dermal Acute Tox. 2 Oral Acute Tox. 3 Inhalation
Hazardous Substances Data	99-98-9(Hazardous Substances Data)

Raw materials And Preparation Products

Hazard Information

General Description

Colorless to reddish-violet solid. Used in the production of methylene blue and photographic developer. Used as a chemical intermediate for dyes and diazonium chloride salts and as an analytical reagent to detect chloroamine in water.

Reactivity Profile

DIMETHYL-P-PHENYLENEDIAMINE neutralizes acids in exothermic reactions to form salts plus water. May be incompatible with isocyanates, halogenated organics, peroxides, phenols (acidic), epoxides, anhydrides, and acid halides. Flammable gaseous hydrogen may be generated in combination with strong reducing agents, such as hydrides. Incompatible with strong oxidizers, strong acids and acid anhydrides. Also incompatible with alkalis .

Health Hazard

Lowest toxic dose with skin effect is 14 mg/kg. Irritant to skin and eyes.

Fire Hazard

When heated to decomposition, DIMETHYL-P-PHENYLENEDIAMINE emits toxic fumes of nitrogen oxides.

Description

Dimethyl-p-phenylenediamine is a colorless toreddish-violet crystalline solid; Molecular weight= 136.23;Boiling point = 262℃; Freezing/Melting point = 41℃;Flash point = 90℃. Insoluble in water

Chemical Properties

grey to black solid

Uses

Base for production of methylene blue, photodeveloper, reagent for detection of hydrogen sulfide, reagent for cellulose, organic synthesis, reagent for certain bacteria.

Definition

ChEBI: N,N-dimethyl-1,4-phenylenediamine is a substituted aniline and a diamine.

Synthesis Reference(s)

Chemistry Letters, 9, p. 439, 1980
Tetrahedron Letters, 34, p. 2441, 1993 DOI: 10.1016/S0040-4039(00)60436-7

Hazard

Toxic by ingestion or inhalation of vapor.

First aid

If this chemical gets into the eyes, remove any contact lenses at once and irrigate immediately for at least15 min, occasionally lifting upper and lower lids. Seek medical attention immediately. If this chemical contacts the skin,remove contaminated clothing and wash immediately withsoap and water. Seek medical attention immediately. If thischemical has been inhaled, remove from exposure, begin rescue breathing (using universal precautions, including resuscitation mask) if breathing has stopped and CPR if heart actionhas stopped. Transfer promptly to a medical facility. Whenthis chemical has been swallowed, get medical attention.Give large quantities of water and induce vomiting. Do notmake an unconscious person vomit.

storage

Color Code—Blue: Health Hazard/Poison: Storein a secure poison location. Store in cool, dry place awayfrom strong oxidizers and acids.

Shipping

Phenylenediamines require a shipping label of“POISONOUS/TOXIC MATERIALS.” T

Material Safety Data Sheet(MSDS)

Spectrum Detail

Well-known Reagent Company Product Information

Supplier

Shanghai Aladdin Bio-Chem Technology Co.,LTD

Telephone400-6206333 13167063860

Websitehttp://www.aladdin-e.com/

Nanjing Kaitian Chemical Co., Ltd

Telephone 15951673915

Websitehttp://njkt01.com

Ningbo jinuo chemical co., LTD

Telephone0574-87314919 057487319282

Websitehttps://cn.nbinno.com

Huaian Jiamu Biotechnology Co., Ltd.

Telephone0517-83187139 18205232085

Websitehttps://www.jiamu-bio.com

Meryer (Shanghai) Chemical Technology Co., Ltd.

Telephone4006356688 18621169109

Websitehttp://www.x-labseek.com/

Alfa Aesar

Telephone400-6106006

Websitehttp://chemicals.thermofisher.cn

TCI (Shanghai) Development Co., Ltd.

Telephone021-67121386

Websitehttps://www.tcichemicals.com/CN/zh/

Energy Chemical

Telephone 400-0056266

Websitehttp://www.energy-chemical.com

Shanghai Longsheng chemical Co.,Ltd.

Telephone58099637 13585536065

Websitehttp://www.shlshg.com

Shanghai Hanhong Scientific Co.,Ltd.

Telephone021-54306202 13764082696

Websitehttps://www.hanhongsci.com

Shandong Xiya Chemical Co., Ltd

Telephone13355009207 13355009207

Websitehttp://www.xiyashiji.com

Syntechem Co.,Ltd

Telephone

Websitehttp://www.syntechem.com/

Sichuan Kulinan Technology Co., Ltd

Telephone400-1166-196 18981987031

Websitehttp://www.hx-r.com/

China Langchem Inc.

Telephone0086-21-58956006

Websitehttps://www.chemicalbook.com/ShowSupplierProductsList19141/0_EN.htm

Sinopharm Chemical Reagent Co,Ltd.

Telephone86-21-63210123

Websitehttp://www.reagent.com.cn

Nanjing Kaitian Chemical Co., Ltd.

Telephone+86 (25) 5860-8846

Websitehttp://www.kt-chem.com/

Maya High Purity Chemicals

Telephone+86 (573) 82222445 (0)18006601000 452520369

Websitehttps://www.chemicalbook.com/ShowSupplierProductsList15221/0_EN.htm

Spectrum Chemical Manufacturing Corp.

Telephone021-021-021-67601398-809-809-809 15221380277

Websitehttps://www.spectrumchemical.com/OA_HTML/index.jsp?minisite=10020&respid=22372&language=US

1of4

Related Products

Send Inquriy