Supplier Related Products Identification Chemical Properties Safety Data Raw materials And Preparation Products Material Safety Data Sheet(MSDS) Hazard Information Spectrum Detail Well-known Reagent Company Product Information
ChemicalBook >  CAS DataBase List  > 108-85-0

108-85-0

Supplier Related Products Identification Chemical Properties Safety Data Raw materials And Preparation Products Material Safety Data Sheet(MSDS) Hazard Information Spectrum Detail Well-known Reagent Company Product Information

Product Image

Identification

Name
Cyclohexyl bromide
CAS
108-85-0
Synonyms
BROMOCYCLOHEXANE
CYCLOHEXYL BROMIDE
Cyelohexyl bromide
1-Bromocyclohexane
bromo-cyclohexan
Bromocylohexane
Cyclohexane,bromo-
Cyclohexylbromid
Hexahydrobromobenzene
Bromocyclohexane,98%
CYCLOHEXYL BROMIDE 99% (GC)
Bromocyclohexane, 95+%
EINECS(EC#)
203-622-2
Molecular Formula
C6H11Br
MDL Number
MFCD00003819
Molecular Weight
163.06
MOL File
108-85-0.mol

Chemical Properties

Appearance
colourless liquid
Melting point 
-57°C
mp 
-57°C
Boiling point 
166-167 °C (lit.)
bp 
166-167 °C(lit.)

density 
1.324 g/mL at 25 °C(lit.)

vapor density 
5.62 (vs air)
refractive index 
n20/D 1.495(lit.)

Fp 
145 °F

storage temp. 
Sealed in dry,Room Temperature
solubility 
H2O: insoluble
form 
Liquid
color 
Clear colorless to light yellow
Specific Gravity
approximate 1.33 (20℃)
Stability:
Stable. Combustible. Incompatible with strong oxidizing agents, strong bases.
Odor
Unpleasant Odor
Water Solubility 
insoluble
Sensitive 
Air & Light Sensitive
Merck 
14,2730
BRN 
1098373
InChIKey
AQNQQHJNRPDOQV-UHFFFAOYSA-N
CAS DataBase Reference
108-85-0(CAS DataBase Reference)
NIST Chemistry Reference
Cyclohexane, bromo-(108-85-0)
Storage Precautions
Light sensitive
EPA Substance Registry System
Cyclohexane, bromo- (108-85-0)

Safety Data

Hazard Codes 
Xn
Risk Statements 
R36/37/38:Irritating to eyes, respiratory system and skin .
R20:Harmful by inhalation.
R18:In use may form flammable/explosive vapor-air mixture.
Safety Statements 
S23:Do not breathe gas/fumes/vapor/spray (appropriate wording to be specified by the manufacturer) .
S24/25:Avoid contact with skin and eyes .
S37/39:Wear suitable gloves and eye/face protection .
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
WGK Germany 
3

RTECS 
GU7171700

8
TSCA 
Yes
HS Code 
29035990

Raw materials And Preparation Products

Material Safety Data Sheet(MSDS)

Hazard Information

Chemical Properties
colourless liquid
Uses
Bromocyclohexane has been used to study the ionization of equatorial and axial conformational isomers of the chair-bromocyclohexane using vacuum ultraviolet mass-analyzed threshold ionization spectroscopy.
Synthesis Reference(s)
Canadian Journal of Chemistry, 50, p. 3109, 1972 DOI: 10.1139/v72-498
Journal of the American Chemical Society, 112, p. 8212, 1990 DOI: 10.1021/ja00178a080
The Journal of Organic Chemistry, 45, p. 1638, 1980 DOI: 10.1021/jo01297a020
General Description
Axial conformer of bromocyclohexane forms inclusion complexes with 9,9′-bianthryl and exhibits a weak 1,3 diaxial Cl...H interaction. It participates in the alkylation reaction of of para-xylene in the presence of graphite as catalyst to yield hydrocarbon.

Purification Methods
Shake the bromide with 60% aqueous HBr to remove the free alcohol. After removing excess HBr, the sample is dried and fractionally distilled. [IR: Roberts & Chambers J Am Chem Soc 73 5031 1951, Beilstein 5 III 48, 5 IV 67.]

Spectrum Detail

Well-known Reagent Company Product Information

SupplierMore