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Name Allyl bromide
CAS 106-95-6
EINECS(EC#) 203-446-6
Molecular Formula C3H5Br
MDL Number MFCD00000244
Molecular Weight 120.98
MOL File 106-95-6.mol

Chemical Properties

Appearance Allyl bromide is a highly flammable, colorless to light yellow liquid with an unpleasant, pungent odor.
Melting point  -119 °C
Boiling point  70-71 °C(lit.)
density  1.398 g/mL at 25 °C(lit.)
vapor density  4.2 (vs air)
vapor pressure  18.66kPa at 25℃
refractive index  n20/D 1.469(lit.)
Fp  28 °F
storage temp.  2-8°C
solubility  Chloroform (Soluble)
form  Liquid
color  Clear colorless to slightly colored
Specific Gravity 1.398
Odor unpleasant
Stability: Stable. Flammable. Incompatible with strong oxidizing agents.
explosive limit 4.3-7.3%(V)
Water Solubility  insoluble
Sensitive  Light Sensitive
Merck  14,288
BRN  605308
Dielectric constant 7.0
Exposure limits ACGIH: TWA 0.1 ppm; STEL 0.2 ppm (Skin)
LogP 1.79
CAS DataBase Reference 106-95-6(CAS DataBase Reference)
NIST Chemistry Reference 1-Propene, 3-bromo-(106-95-6)
EPA Substance Registry System 106-95-6(EPA Substance)

Safety Data

Hazard Codes  F,T,N
Risk Statements 
R11:Highly Flammable.
R23/25:Toxic by inhalation and if swallowed .
R34:Causes burns.
R50:Very Toxic to aquatic organisms.
Safety Statements 
S16:Keep away from sources of ignition-No smoking .
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection .
S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) .
S60:This material and/or its container must be disposed of as hazardous waste .
S61:Avoid release to the environment. Refer to special instructions safety data sheet .
RIDADR  UN 1099 3/PG 1
WGK Germany  2
RTECS  UC7090000
Autoignition Temperature 554 °F
HazardClass  3
PackingGroup  I
HS Code  29033036
storage Allyl bromide should be stored separate from oxidizing materials and alkalis in a cool, dry, well-ventilated location in tightly closed containers.
Precautions Workers should wear positive pressure self-contained breathing apparatus (SCBA), goggles and a face shield, protective clothing for high concentrations of vapor, chemical protective clothing that is specifi cally recommended by the manufacturer to avoid poisoning. Workers should be careful as allyl bromide reacts with oxidizing materials and alkalis.
Safety Profile
Poison by ingestion and intraperitoneal routes. Mdly toxic by inhalation. Human mutation data reported. See also ALLYL CHLORIDE and ALLYL COMPOUNDS. Dangerous fire and explosion hazard when exposed to heat, flame, or oxidizers. When heated to decomposition it emits toxic fumes of Br-. To fight fire, use alcohol foam, water spray or mist, CO2, dry chemical
Hazardous Substances Data 106-95-6(Hazardous Substances Data)
LD50 orally in Rabbit: 120 mg/kg

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