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Name Allyl glycidyl ether
CAS 106-92-3
EINECS(EC#) 203-442-4
Molecular Formula C6H10O2
MDL Number MFCD00005143
Molecular Weight 114.14
MOL File 106-92-3.mol

Chemical Properties

Appearance Allyl glycidyl ether is a colorless liquid with a strong, sweet odor
Melting point  -100 °C
Boiling point  154 °C(lit.)
density  0.962 g/mL at 25 °C(lit.)
vapor density  3.9 (vs air)
vapor pressure  4.7 mm Hg ( 25 °C)
refractive index  n20/D 1.433(lit.)
Fp  135 °F
storage temp.  Refrigerator (+4°C)
solubility  50 g/L (20°C)
form  Liquid
color  Clear colorless
Specific Gravity 0.962
Stability: Stable. Combustible. Incompatible with strong oxidizing agents, acids, bases. May form peroxides in storage if in contact with air.
Water Solubility  50 g/L (20 ºC)
BRN  105871
Henry's Law Constant (x 10-6 atm?m3/mol): 3.83 at 20 °C (approximate - calculated from water solubility and vapor pressure)
Exposure limits NIOSH REL: TWA 5 ppm (22 mg/m3), STEL 10 ppm (44 mg/m3), IDLH 50 ppm; OSHA PEL: ceiling 10 ppm; ACGIH TLV: TWA 5 ppm, STEL 10 ppm.
Contact allergens
Allyl glycidyl ether is a monoglycidyl derivative, used as a reactive epoxy diluent for epoxy resins. As an impurity, it was considered to be the sensitizing agent in a plastic industry worker allergic to 3-glycidyloxypropyl trimethoxysilane, an epoxy silane compound used as a fixing additive in silicone and polyurethane
LogP 0.45 at 25℃
Resin intermediate, stabilizer of chlorinated compounds, vinyl resins, and rubber.
CAS DataBase Reference 106-92-3(CAS DataBase Reference)
NIST Chemistry Reference Oxirane, [(2-propenyloxy)methyl]-(106-92-3)
EPA Substance Registry System 106-92-3(EPA Substance)

Safety Data

Hazard Codes  Xn
Risk Statements 
R20/22:Harmful by inhalation and if swallowed .
R37/38:Irritating to respiratory system and skin .
R40:Limited evidence of a carcinogenic effect.
R41:Risk of serious damage to eyes.
R43:May cause sensitization by skin contact.
R52/53:Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment .
R62:Possible risk of impaired fertility.
R68:Possible risk of irreversible effects.
Safety Statements 
S24/25:Avoid contact with skin and eyes .
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection .
S61:Avoid release to the environment. Refer to special instructions safety data sheet .
RIDADR  UN 2219 3/PG 3
WGK Germany  3
RTECS  RR0875000
Autoignition Temperature 264 °C
HazardClass  3
PackingGroup  III
HS Code  29109000
storage Allyl glycidyl ether should be kept stored in a cool, dark, fi reproof area separated from strong oxidants, strong bases, and strong acids.
Precautions During use and/or handling of allyl glycidyl ether, occupational workers should not be near open flames, sparks, or smoking areas. For temperatures above 48°C, use a closedsystem ventilation and explosion-proof electrical equipment. Workers should use protective gloves, protective clothing, and avoid all contact.
Safety Profile
Confirmed animal carcinogen. Poison by ingestion. Moderately toxic by inhalation and skin contact. Mutation data reported. A severe skin and eye irritant. Can cause central nervous system depression and pulmonary edema. A flammable liquid when exposed to heat or flame; can react with oxidizing materials. To fight fire, use foam, CO2, dry chemical.When heated to decomposition it emits acrid smoke and irritating fumes. See also ALLYL COMPOUNDS
Hazardous Substances Data 106-92-3(Hazardous Substances Data)
LD50 orally in Rabbit: 922 mg/kg LD50 dermal Rabbit 2550 mg/kg
IDLA 50 ppm

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