Supplier Product Identification Physical and Chemical Properties First Aid Measures Handling and Storage Hazards Identification Exposure Controls/Personal Protection Fire Fighting Measures Accidental Release Measures Stability and Reactivity Transport Information
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Allyl 2,3-epoxypropyl ether(106-92-3)

Supplier Product Identification Physical and Chemical Properties First Aid Measures Handling and Storage Hazards Identification Exposure Controls/Personal Protection Fire Fighting Measures Accidental Release Measures Stability and Reactivity Transport Information

Product Identification

Product Name
Allyl 2,3-epoxypropyl ether
Synonyms
((2-Propenyloxy)methyl)oxirane
1-(Allyloxy)-2,3-epoxypropane
Allyl 2,3-epoxypropyl ether
CAS
106-92-3
Formula
C6H10O2
Molecular Weight
114.15
EINECS
203-442-4
RTECS
RR0875000
RTECS Class
Tumorigen; Mutagen; Primary Irritant
Beilstein/Gmelin
105871
Beilstein Reference
5-17-03-00012
EC Index Number
603-038-00-1
EC Class
Flammable; Carcinogenic Category 3; Mutagenic Category 3; Toxic for reproduction Category 3; Harmful; Irritant; Sensitising; Dangerous for the Environment

Physical and Chemical Properties

Appearance
Colorless liquid, characteristic, sweet odor.
Solubility in water
141 g/L
Melting Point
-100
Boiling Point
154
Vapor Pressure
5
Density
0.9798 g/cm3
Partition Coefficient
.36
Usage
Stabilizer of chlorinated compounds, vinyl resins, rubber, resin intermediate.
Saturation Concentration
6200 ppm (0.62%) at 25 C (1)
Vapor Density
3.94
Odor threshold
44 mg/m3
Refractive Index
1.4349 (20 C)

First Aid Measures

Ingestion
Never give anything by mouth to an unconscious person. Get medical aid immediately. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water.
Inhalation
Get medical aid immediately. Remove from exposure to fresh air immediately. Do not use mouth-to-mouth respiration if victim ingested or inhaled the substance; induce artificial respiration with the aid of a pocket mask equipped with a one-way valve or other proper respiratory medical device.
Skin
Get medical aid immediately. Immediately flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse.
Eyes
Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately.

Handling and Storage

Storage
Keep away from heat, sparks, and flame. Keep away from sources of ignition. Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances. Flammables-area.
Handling
Wash thoroughly after handling. Use only in a well ventilated area. Do not get in eyes, on skin, or on clothing. Empty containers retain product residue, (liquid and/or vapor), and can be dangerous. Keep container tightly closed. Avoid contact with heat, sparks and flame. Use and store under nitrogen. Use only in a chemical fume hood. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose empty containers to heat, sparks or open flames. Do not breathe vapors.

Hazards Identification

Inhalation
Inhalation may be fatal as a result of spasm, inflammation, edema of the larynx and bronchi, chemical pneumonitis and pulmonary edema. Aspiration may lead to pulmonary edema. May cause burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting. Inhalation at high concentrations may cause CNS depression and asphixiation. Harmful if inhaled.
Skin
Causes severe skin irritation. May be harmful if absorbed through the skin. May cause cyanosis of the extremities. May cause sensitization by skin contact.
Eyes
Causes severe eye irritation. May cause reversible inflammation and corneal injury with opacity. Vapors may also cause corneal opacity.
Ingestion
May cause gastrointestinal irritation with nausea, vomiting and diarrhea. May be harmful if swallowed. May cause central nervous system depression.
Hazards
Vapors may form explosive mixtures with air. Vapors may travel to source of ignition and flash back. Most vapors are heavier than air. They will spread along ground and collect in low or confined areas (sewers, basements, tanks). Vapor explosion hazard indoors, outdoors or in sewers. May polymerize explosively when heated or involved in a fire. Runoff to sewer may create fire or explosion hazard. Containers may explode when heated. Many liquids are lighter than water.
EC Risk Phrase
R 10 20/22 40 41 43 52/53 62 68
EC Safety Phrase
S 24/25 26 36/37/39 61
UN (DOT)
2219

Exposure Controls/Personal Protection

Personal Protection
Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure.
Respirators
A respiratory protection program that meets OSHA's 29 CFR 1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant a respirator's use.
Exposure Effects
Repeated exposure may cause sensitization dermatitis.
Exposure limit(s)
OSHA PEL: C 10 ppm (45 mg/m3) NIOSH REL: TWA 5 ppm (22 mg/m3) ST 10 ppm (44 mg/m3) skin NIOSH IDLH: 50 ppm
Poison Class
3

Fire Fighting Measures

Flash Point
48
Fire Fighting
Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Use water spray to keep fire-exposed containers cool. Runoff from fire control or dilution water may cause pollution. Extinguishing media: Use water spray to cool fire-exposed containers. Water may be ineffective. Do NOT use straight streams of water. In case of fire, use carbon dioxide, dry chemical powder or appropriate foam.
Fire Potential
HIGHLY FLAMMABLE.

Accidental Release Measures

Small spills/leaks
Clean up spills immediately, using the appropriate protective equipment. Remove all sources of ignition. Absorb spill using an absorbent, non-combustible material such as earth, sand, or vermiculite. Use a spark-proof tool. Provide ventilation.

Stability and Reactivity

Disposal Code
1
Incompatibilities
Oxidizing agents, acids, bases.
Stability
Stable under normal temperatures and pressures.
Decomposition
Carbon monoxide, carbon dioxide, acrid smoke and fumes.
Combustion Products
Fire may produce irritating, corrosive and/or toxic gases.

Transport Information

UN Number
2219
Hazard Class
3
Packing Group
III
HS Code
2910 90 00
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