Basic information Reaction Safety Related Supplier
ChemicalBook >  Product Catalog >  Organic Chemistry >  Organometallic compounds >  Organonickel >  Bis(triphenylphosphine)nickel(II)chloride

Bis(triphenylphosphine)nickel(II)chloride

Basic information Reaction Safety Related Supplier
Bis(triphenylphosphine)nickel(II)chloride Basic information
Bis(triphenylphosphine)nickel(II)chloride Chemical Properties
Safety Information
MSDS
Bis(triphenylphosphine)nickel(II)chloride Usage And Synthesis
  • Reaction
    1. Catalyst for hydrosilylation of styrene with diphenysilane
    2. Catalyst for carboxylation of various aryl chlorides and other derivatives
    3. Catalyst for C–P cross-coupling reactions of diphenylphosphine oxide with aryl chloride
    4. Catalyst for N?Heterocyclic carbene-assisted cross-coupling reactions of diarylborinic acids with aryl chlorides,tosylates, and sulfamates.
    5. Catalyst for Negishi biaryl ketone synthesis by cross-coupling of amides with aryl zinc halides via carbon-nitrogen bond cleavage.
  • Chemical Propertiesdark green to dark grey crystals or powder
  • UsesCoordination compund.
  • Usessuzuki reaction
  • UsesDichlorobis(triphenylphosphine)nickel(II) is used as a catalyst for cross-coupling of Grignard reagents, hydrosilylations, hydrogenation and polymerization.
  • Purification MethodsWash it with glacial AcOH and dry it in a vacuum over H2SO4 and KOH until AcOH is removed. [Venanzi J Chem Soc 719 1958, Kocienski et al. J Org Chem 54 1215 1989, Beilstein 16 IV 953.]
Bis(triphenylphosphine)nickel(II)chloride Preparation Products And Raw materials
Bis(triphenylphosphine)nickel(II)chloride(14264-16-5)Related Product Information
Bis(triphenylphosphine)nickel(II)chlorideSupplierMore
  • Company Name:Zhengzhou Changkuan Technology Co., Ltd Gold
  • Tel:18530983798 0371-63769919-
  • Email:sales5@changkuantech.com
  •  
  • Company Name:J & K SCIENTIFIC LTD.
  • Tel:400-666-7788 010-82848833-
  • Email:jkinfo@jkchemical.com;market6@jkchemical.com
  •  
  • Company Name:Meryer (Shanghai) Chemical Technology Co., Ltd.
  • Tel:400-660-8290 21-61259100-
  • Email:sh@meryer.com
  •  
  • Company Name:INTATRADE GmbH
  • Tel:+49 3493/605464
  • Email:sales@intatrade.de
  •  
  • Company Name:Alfa Aesar
  • Tel:400-610-6006
  • Email:saleschina@alfa-asia.com
  •