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Bis(triphenylphosphine)nickel(II)chloride Basic information
Bis(triphenylphosphine)nickel(II)chloride Chemical Properties
Safety Information
Bis(triphenylphosphine)nickel(II)chloride Usage And Synthesis
  • Reaction
    1. Catalyst for hydrosilylation of styrene with diphenysilane
    2. Catalyst for carboxylation of various aryl chlorides and other derivatives
    3. Catalyst for C–P cross-coupling reactions of diphenylphosphine oxide with aryl chloride
    4. Catalyst for N?Heterocyclic carbene-assisted cross-coupling reactions of diarylborinic acids with aryl chlorides,tosylates, and sulfamates.
    5. Catalyst for Negishi biaryl ketone synthesis by cross-coupling of amides with aryl zinc halides via carbon-nitrogen bond cleavage.
  • Chemical Propertiesdark green to dark grey crystals or powder
  • UsesCoordination compund.
  • Usessuzuki reaction
  • UsesDichlorobis(triphenylphosphine)nickel(II) is used as a catalyst for cross-coupling of Grignard reagents, hydrosilylations, hydrogenation and polymerization.
  • Purification MethodsWash it with glacial AcOH and dry it in a vacuum over H2SO4 and KOH until AcOH is removed. [Venanzi J Chem Soc 719 1958, Kocienski et al. J Org Chem 54 1215 1989, Beilstein 16 IV 953.]
Bis(triphenylphosphine)nickel(II)chloride Preparation Products And Raw materials
Bis(triphenylphosphine)nickel(II)chloride(14264-16-5)Related Product Information
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