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Bis(triphenylphosphine)palladium(II) chloride

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Bis(triphenylphosphine)palladium(II) chloride Basic information
Bis(triphenylphosphine)palladium(II) chloride Chemical Properties
  • Melting point:260°C
  • RTECS RT3578000
  • storage temp. Store below +30°C.
  • form Powder
  • color Yellow
  • Water Solubility Insoluble in water. Soluble in benzene, and toluene.
  • Sensitive Hygroscopic
  • BRN 4935975
  • CAS DataBase Reference13965-03-2(CAS DataBase Reference)
Safety Information
Bis(triphenylphosphine)palladium(II) chloride Usage And Synthesis
  • Reactions
    1. Precatalyst for the carbonylative cyclization of malonate derivatives.
    2. Catalyst used in the double allylation of activated olefins.
    3. Precatalyst for the three-component preparation of 3-arylidene- (or 3-alkenylidene) tetrahydrofurans.
    4. Precatalyst for the homocoupling of terminal alkynes.
    5. Precatalyst in the cross-coupling of alkynylsilanols and aryl halides.
    6. Catalyst for direct Pd-catalyzed alkynylation of N-fused heterocycles.
    7. Catalyst for a tandem Heck reaction/C-H functionalization.
    8. Catalyst for direct arylation of tautomerizable heterocycles. 

  • Chemical Propertiesyellow solid
  • Usessuzuki reaction
  • UsesBis(triphenylphosphine)palladium(II) chloride is used primarily in organometallic catalytic reactions due to the palladium content of the compound. It is also involved in crystalized structures of me tallacyclic complexes which show antiinflammatory and antifungal properties.
  • UsesAs a catalyst of choice in hydrogenation, hydrosilation, carbonylation, oxidation, elimination, reduction, allyl aceate isomerization, dimerization of 1,3-dienes, and C-C bond formation such as Negishi coupling, Suzuki coupling, Kumada coupling, Sonogashira coupling, Heck coupling and Sonogashira-Hagihara coupling reactions. Used in the preparation of tetrakis(triphenylphosphine)palladium, condensed heterocycles such as furoquinolines, diphenylacetylenes, and several other compounds.
  • General Description
    Bis(triphenylphosphine)palladium(II) dichloride is an organometallic complex. It is an efficient cross-coupling catalyst for C-C coupling reaction, such as Negishi coupling, Suzuki coupling, Sonogashira coupling and Heck coupling reaction. Detection of bis(triphenylphosphine)palladium(II) dichloride by electrospray ionization quadrupole ion trap mass spectrometry using different imidazolium salts as the charge carrier has been reported. It is employed as catalyst for the Heck reaction medium.
Bis(triphenylphosphine)palladium(II) chloride Preparation Products And Raw materials
Bis(triphenylphosphine)palladium(II) chloride(13965-03-2)Related Product Information
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