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ChemicalBook >  Product Catalog >  Chemical Reagents >  Organic reagents >  Phosphine ligand >  (11AR)-(+)-10,11,12,13-TETRAHYDRODIINDENO[7,1-DE:1',7'-FG][1,3,2]DIOXAPHOSPHOCIN-5-BIS(R)-1PHENYLETHYL]AMINE

(11AR)-(+)-10,11,12,13-TETRAHYDRODIINDENO[7,1-DE:1',7'-FG][1,3,2]DIOXAPHOSPHOCIN-5-BIS(R)-1PHENYLETHYL]AMINE

Basic information Reaction Safety Related Supplier
(11AR)-(+)-10,11,12,13-TETRAHYDRODIINDENO[7,1-DE:1',7'-FG][1,3,2]DIOXAPHOSPHOCIN-5-BIS(R)-1PHENYLETHYL]AMINE Basic information
(11AR)-(+)-10,11,12,13-TETRAHYDRODIINDENO[7,1-DE:1',7'-FG][1,3,2]DIOXAPHOSPHOCIN-5-BIS(R)-1PHENYLETHYL]AMINE Chemical Properties
  • Melting point:98-100°C
  • alpha +300° (c 1.0, CH2Cl2)
  • storage temp. ?20°C
  • form solid
  • color white
  • optical activity[α]22/D +337°, c = 1 in chloroform
  • Sensitive moisture sensitive
  • InChIKeyZXLQLIDJAURBDD-HRPAVAKOSA-N
Safety Information
(11AR)-(+)-10,11,12,13-TETRAHYDRODIINDENO[7,1-DE:1',7'-FG][1,3,2]DIOXAPHOSPHOCIN-5-BIS(R)-1PHENYLETHYL]AMINE Usage And Synthesis
  • Reaction
    1. Chiral ligands for copper-catalyzed asymmetric allylic alkylation with dialkylzincs.
    2. Chiral ligands for copper-catalyzed asymmetric conjugate addition of diethylzinc to enones.
    3. Chiral ligands for palladium-catalyzed asymmetric hydrosilylation of styrenes
    4. Chiral ligands for copper-catalyzed asymmetric ring-opening of oxabicyclic alkenes with Grignard reagents.
    5. Chiral ligands for nickel-catalyzed asymmetric hydrovinylation of α-alkyl vinylarenes.
    6. Chiral ligands for iridium-catalyzed asymmetric hydrogenation of cyclic enamines.
    7. Chiral ligands for iridium-catalyzed asymmetric hydrogenation of cyclic imines.
    8. Chiral ligands for gold-catalyzed asymmetric [2 + 2] cycloaddition reaction.
    9. Chiral ligands for rhodium-catalyzed asymmetric hydroacylation of salicylaldehydes to homoallylic sulfides.
    10. Chiral ligands for palladium-catalyzed asymmetric carboamination reactions. 



(11AR)-(+)-10,11,12,13-TETRAHYDRODIINDENO[7,1-DE:1',7'-FG][1,3,2]DIOXAPHOSPHOCIN-5-BIS(R)-1PHENYLETHYL]AMINE Preparation Products And Raw materials
(11AR)-(+)-10,11,12,13-TETRAHYDRODIINDENO[7,1-DE:1',7'-FG][1,3,2]DIOXAPHOSPHOCIN-5-BIS(R)-1PHENYLETHYL]AMINE(500997-69-3)Related Product Information
(11AR)-(+)-10,11,12,13-TETRAHYDRODIINDENO[7,1-DE:1',7'-FG][1,3,2]DIOXAPHOSPHOCIN-5-BIS(R)-1PHENYLETHYL]AMINESupplierMore
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