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Tris(dibenzylideneacetone)dipalladium-chloroform adduct

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Tris(dibenzylideneacetone)dipalladium-chloroform adduct Basic information
Tris(dibenzylideneacetone)dipalladium-chloroform adduct Chemical Properties
  • Melting point:131-135 °C(lit.)
  • storage temp. Keep in dark place,Sealed in dry,Room Temperature
  • form Crystalline Powder
  • color Purple to black
  • Water Solubility Soluble in organic solvents. Insoluble in water.
  • Sensitive Air & Moisture Sensitive
Safety Information
Tris(dibenzylideneacetone)dipalladium-chloroform adduct Usage And Synthesis
  • Reaction
    1. Used for Pd-catalyzed asymmetric arylation, vinylation, and Allenylation of tert-cyclobutanols via enantioselective C−C Bond cleavage.
    2. Used for synthesis of chiral chromans through the Pd-catalyzed asymmetric allylic alkylation (AAA).
    3. Catalyst for double N-arylation of primary amines to synthesize multisubstituted carbazoles from 2,2‘biphenylylene ditriflates.
    4. Paladium catalyst for regioand enantioselective allylic alkylation of ketones through allyl enol carbonates.
    5. Used for Pd-catalyzed enantioselective C-3 allylation of 3-substituted-1H-indoles using trialkylboranes.
    6. Used for enantioselective construction of spirocyclic oxindolic cyclopentanes by Pd-catalyzed trimethylenemethane-[3+2]-cycloaddition.
    7. Used for Pd-catalyzed insertion of α-diazoesters into vinyl halides to generate α,β-unsaturated γ-amino Esters.
    8. Pd catalyst for decarboxylative asymmetric allylic alkylation of enol carbonates.
    9. Palladium catalyst for asymmetric addition of oxindoles and allenes.
    10. Catalyst for diastereoand enantioselective formal [3+2]-cycloaddition between substituted vinylcyclopropanes and electron-deficient olefins.
    11. Used for Pd-catalyzed asymmetric decarboxylative cycloaddition of vinylethylene carbonates with Michael sacceptors.
    12. Catalyst for enantioselective [6+4] cycloaddition of vinyl oxetanes with azadienes to access ten-membered heterocycles.

  • Chemical Propertiespurple to black crystalline powder
  • Usessuzuki reaction
  • Biological ActivityN -myristoyltransferase-1 (NMT-1) inhibitor that prevents activation of MAPK, PI 3-K and STAT3 signaling pathways. Exhibits antiproliferative activity against melanoma cells in vitro and in vivo . Also used as a cyclization catalyst.
Tris(dibenzylideneacetone)dipalladium-chloroform adduct Preparation Products And Raw materials
Tris(dibenzylideneacetone)dipalladium-chloroform adduct(52522-40-4)Related Product Information
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