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Phenyl phosphine

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Phenyl phosphine Basic information
Phenyl phosphine Chemical Properties
  • Boiling point:160°C
  • Density 1.001
  • vapor density 3.79 (vs air)
  • vapor pressure 760 mmHg ( 160 °C)
  • refractive index 1.578
  • Flash point:-20°F
  • storage temp. ?20°C
  • form liquid
  • color colorless
  • Water Solubility Insoluble in water.
  • Sensitive Air & Moisture Sensitive
  • BRN 741946
  • InChIKeyRPGWZZNNEUHDAQ-UHFFFAOYSA-N
  • CAS DataBase Reference638-21-1(CAS DataBase Reference)
  • NIST Chemistry ReferencePhenylphosphine(638-21-1)
  • EPA Substance Registry SystemPhosphine, phenyl-(638-21-1)
Safety Information
MSDS
Phenyl phosphine Usage And Synthesis
  • Chemical PropertiesPhenylphosphine is a clear, colorless liquid. Foul odor.
  • Usessuzuki reaction
  • General DescriptionClear colorless liquid.
  • Air & Water ReactionsPyrophoric in air. Insoluble in water. Slowly generates flammable or noxious gases in contact with water.
  • Reactivity ProfilePhenyl phosphine is a reducing agent. They slowly generate flammable or noxious gases in contact with water. Phosphides react quickly upon contact with moisture or acids to give the very toxic gas phosphine; phosphides also can react vigorously with oxidizing materials. In general, materials in this group are incompatible with oxidizers such as atmospheric oxygen. They are violently incompatible with acids, particularly oxidizing acids.
  • Fire HazardFlash point data are not available for Phenyl phosphine, but Phenyl phosphine is probably combustible.
  • Safety ProfilePoison by inhalation. Igmtes spontaneously in air. When heated to decomposition it emits toxic fumes of POx. See also PHOSPHINE.
  • Potential ExposurePolyphosphinate is used as an intermediate or a chemical reagent. Polyphosphinate compounds are used as catalysts and antioxidants disproportionate, when heated to give phosphonic acid derivatives plus PF.
  • ShippingUN2845 Pyrophoric liquids, organic, n.o.s Hazard Class: 4.2, Labels: 4.2-Spontaneously combustible material. Technical Name Required. Note: this chemical is also a strong reducing agent.
  • IncompatibilitiesA strong reducing agent. Incompatible with oxidizers (chlorates, nitrates, peroxides, permanganates, perchlorates, chlorine, bromine, fluorine, etc.); contact may cause fires or explosions. Keep away from alkaline materials, strong bases, strong acids, oxoacids, epoxides. Water reactive; spontaneously combustible in high concentrations in moist air. Potential exposure to gaseous phenylphosphine and phosphorus oxides when heated above 200C. Organophosphates are susceptible to formation of highly toxic and flammable phosphine gas in the presence of strong reducing agents such as hydrideds and active metals. Partial oxidation by oxidizing agents may result in the release of toxic phosphorus oxides.
Phenyl phosphine Preparation Products And Raw materials
Phenyl phosphine(638-21-1)Related Product Information
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