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[1,3-Bis(diphenylphosphino)propane]nickel(II) chloride

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[1,3-Bis(diphenylphosphino)propane]nickel(II) chloride Basic information
[1,3-Bis(diphenylphosphino)propane]nickel(II) chloride Chemical Properties
  • Melting point:213 °C (dec.)(lit.)
  • storage temp. Inert atmosphere,Room Temperature
  • form crystal
  • color red
  • Water Solubility insoluble
  • Hydrolytic Sensitivity4: no reaction with water under neutral conditions
  • InChIKeyZBQUMMFUJLOTQC-UHFFFAOYSA-L
  • CAS DataBase Reference15629-92-2(CAS DataBase Reference)
Safety Information
MSDS
[1,3-Bis(diphenylphosphino)propane]nickel(II) chloride Usage And Synthesis
  • Reaction
    1. Nickel catalyst used in the N-heterocycle-directed cross-coupling of fluorinated arenes with organozinc reagents.
    2. Nickel catalyst used in the (E)-selective semihydrogenation of internal alkynes.
    3. Nickel catalyst used in the borylation of halides and pseudohalides.
  • Chemical Propertiesred to red-brown powder or crystals
  • Usessuzuki reaction.
    Dichloro[bis(1,3-diphenylphosphino)propane]nickel(II) is used as an effective catalyst for Kumada coupling and Suzuki reactions. It also catalyzes other reactions to convert enol ethers, dithioacetals and vinyl sulfides to olefins. Further, it is used as a catalyst for preparation of block-copolythiophenes and solid state metathesis polycondensation.
  • UsesDichloro[bis(1,3-diphenylphosphino)propane]nickel(II) is used as an effective catalyst for Kumada coupling and Suzuki reactions. It also catalyzes other reactions to convert enol ethers, dithioacetals and vinyl sulfides to olefins. Further, it is used as a catalyst for preparation of block-copolythiophenes and solid state metathesis polycondensation.
  • ApplicationCatalyst for:
    Synthesis of block-copolythiophenes
    Suzuki-Miyaura cross-coupling reaction of aryl halides with arylboronic acids
    Solid state metathesis polycondensation
    Polymerization of poly(3-alkoxythiophene)s
    Diastereoselective Nozaki-Hiyama-Kishi coupling reactions of C1-C19 fragment of macrolide antibiotic aplyronine A
    Transfer condensation polymerization of conjugated polymers
    [1,3-Bis(diphenylphosphino)propane]dichloronickel(II) can be used as a precursor to synthesize metal-fullerene coordination complexes by reduction method.
[1,3-Bis(diphenylphosphino)propane]nickel(II) chloride Preparation Products And Raw materials
[1,3-Bis(diphenylphosphino)propane]nickel(II) chloride(15629-92-2)Related Product Information
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