Propylacetat

Bezeichnung:Propylacetat

CAS-Nr109-60-4

Englisch Name:Propyl acetate

CBNumberCB9148631

SummenformelC5H10O2

Molgewicht102.13

MOL-Datei109-60-4.mol

Synonyma

Propylacetat

1-Acetoxypropan

1-Propylacetat

Propylacetat physikalisch-chemischer Eigenschaften

Schmelzpunkt	-95 °C (lit.)
Siedepunkt	102 °C (lit.)
Dichte	0.888 g/mL at 25 °C (lit.)
Dampfdichte	3.5 (vs air)
Dampfdruck	25 mm Hg ( 20 °C)
Brechungsindex	n20/D 1.384(lit.)
FEMA	2925 \| PROPYL ACETATE
Flammpunkt	55 °F
storage temp.	Store below +30°C.
Löslichkeit	water: soluble
Aggregatzustand	Liquid
Farbe	APHA: ≤15
Wichte	0.889 (20/4℃)
Geruch (Odor)	Mild fruity.
Explosionsgrenze	1.7%, 37°F
Odor Threshold	0.24ppm
Geruchsart	fruity
Biologische Quelle	synthetic
Wasserlöslichkeit	2g/100 mL (20 ºC)
Merck	14,7841
JECFA Number	126
BRN	1740764
Henry's Law Constant	5.54 at 37 °C (static headspace-GC, van Ruth et al., 2001)
Expositionsgrenzwerte	TLV-TWA 200 ppm (～840 mg/m³) (ACGIH, MSHA, and OSHA); TLV-STEL 250 ppm (～1050 mg/m³) (ACGIH); IDLH 8000 ppm (NIOSH).
Dielectric constant	6.3（20℃）
Stabilität	Stable. Highly flammable. May react violently with oxidizing agents. May form explosive mixtures with air. Incompatible with strong oxidizing agents, acids, bases.
LogP	1.4 at 25℃
CAS Datenbank	109-60-4(CAS DataBase Reference)
NIST chemische Informationen	n-Propyl acetate(109-60-4)
EPA chemische Informationen	Propyl acetate (109-60-4)

Sicherheit

Kennzeichnung gefährlicher	F,Xi
R-Sätze:	11-36-66-67
S-Sätze:	16-26-29-33
RIDADR	UN 1276 3/PG 2
OEB	A
OEL	TWA: 200 ppm (840 mg/m3), STEL: 250 ppm (1050 mg/m3)
WGK Germany	1
RTECS-Nr.	AJ3675000
Selbstentzündungstemperatur	842 °F
Hazard Note	Irritant/Highly Flammable
TSCA	Yes
HS Code	2915 39 00
HazardClass	3
PackingGroup	II
Giftige Stoffe Daten	109-60-4(Hazardous Substances Data)
Toxizität	LD50 in rats, mice (mg/kg): 9370, 8300 orally (Jenner)
IDLA	1,700 ppm

Gefahreninformationscode (GHS)

Propyl acetate Chemische Eigenschaften,Einsatz,Produktion Methoden

ERSCHEINUNGSBILD
FARBLOSE FLüSSIGKEIT MIT CHARAKTERISTISCHEM GERUCH.
PHYSIKALISCHE GEFAHREN
Die Dämpfe mischen sich leicht mit Luft. Bildung explosionsfähiger Gemische.
CHEMISCHE GEFAHREN
Reagiert mit starken Oxidationsmitteln, starken Basen, starken Säurenund Nitraten unter Feuer- und Explosionsgefahr. Greift Kunststoff an.
ARBEITSPLATZGRENZWERTE
TLV: 200 ppm (als TWA); 250 ppm (als STEL); (ACGIH 2005).
MAK: 100 ppm, 420 mg/m? Spitzenbegrenzung: überschreitungsfaktor I(2); Schwangerschaft: Gruppe D; (DFG 2005).
AUFNAHMEWEGE
Aufnahme in den Körper durch Inhalation der Dämpfe und durch Verschlucken.
INHALATIONSGEFAHREN
Beim Verdampfen bei 20°C kann schnell eine gesundheitsschädliche Kontamination der Luft eintreten.
WIRKUNGEN BEI KURZZEITEXPOSITION
WIRKUNGEN BEI KURZZEITEXPOSITION:
Der Dampf reizt die Augen, die Haut und die Atemwege. Exposition weit oberhalb der Arbeitsplatzgrenzwerte kann Bewusstseinstrübung verursachen.
WIRKUNGEN NACH WIEDERHOLTER ODER LANGZEITEXPOSITION
Die Flüssigkeit entfettet die Haut.
LECKAGE
Belüftung. Ausgelaufene Flüssigkeit möglichst in abdichtbaren Behältern sammeln. Reste mit Sand oder inertem Absorptionsmittel aufnehmen und an einen sicheren Ort bringen. NICHT in die Kanalisation spülen. Persönliche Schutzausrüstung: Atemschutzfilter für organische Gase und Dämpfe.
R-Sätze Betriebsanweisung:
R11:Leichtentzündlich.
R36:Reizt die Augen.
R66:Wiederholter Kontakt kann zu spröder oder rissiger Haut führen.
R67:Dämpfe können Schläfrigkeit und Benommenheit verursachen.
S-Sätze Betriebsanweisung:
S16:Von Zündquellen fernhalten - Nicht rauchen.
S26:Bei Berührung mit den Augen sofort gründlich mit Wasser abspülen und Arzt konsultieren.
S29:Nicht in die Kanalisation gelangen lassen.
S33:Maßnahmen gegen elektrostatische Aufladungen treffen.
Beschreibung
Propyl acetate, also known as propyl ethanoate, is an organic compound with a molecular formula of C5H10O2. It is a clear and colourless liquid with with a mild fruity odor. It is highly flammable with a flash point of 14°C and a flammability rating of 3. It is highly miscible with all common organic solvents (alcohols, ketones, glycols, esters) but has only slight miscibility in water. Propyl acetate is found in apple and formed by the esterification of acetic acid and 1-propanol (known as acondensation reaction), often via Fischer–Speier esterification, with sulfuric acid as a catalyst and water produced as a byproduct. It is primarily intended as a solvent in the coatings and printing inks industries. It is widely used in fragrances and as a flavor additive due to its odor. It also acts as a good solvent for cellulose nitrate, acrylates, alkyd resins, rosin, plasticizers, waxes, oils and fats.
Chemische Eigenschaften
Propyl acetate has a fruity (pear–raspberry) odor with a pleasant, bittersweet flavor reminiscent of pear on dilution. The Odor Threshold is 70 milligram per cubic meter and 2.8 milligram per cubic meter (New Jersey Fact Sheet).
Physikalische Eigenschaften
Clear, colorless, flammable liquid with a pleasant, pear-like odor. Experimentally determined detection and recognition odor threshold concentrations were 200 μg/m³ (48 ppb_v) and 600 μg/m³ (140 ppb_v), respectively (Hellman and Small, 1974). An odor threshold concentration of 240 ppb_v was determined by a triangular odor bag method (Nagata and Takeuchi, 1990). Cometto-Mu?iz and Cain (1991) reported an average nasal pungency threshold concentration of 17,575 ppm_v.
Occurrence
Reported found in apple, apple juice, apricot, banana, black currants, guava, grapes, melon, peach, pears, pineapple, plum, strawberry, tomato, vinegar, wheat and rye bread, feta cheese, Gruyere cheese, domiati cheese, yogurt, beef fat, beer, cognac, bourbon and malt whiskey, cider, grape wines, cocoa, potato chips, honey, passion fruit, starfruit, fig, prickly pear, jackfruit, litchi, sake, loquat, mountain papaya, arrack, nectarine and pepino fruit.
Verwenden
n-Propyl acetate is used as a solvent for cellulose derivatives, plastics, and resins; in flavors and perfumes; and in organic synthesis.
synthetische
Propyl Acetate is formed by the esterification of acetic acid and 1-propanol with sulfuric acid as a catalyst and water produced as a byproduct. or By direct acetylation of propyl alcohol.
Definition
ChEBI: Propyl acetate is an acetate ester obtained by the formal condensation of acetic acid with propanol. It has a role as a fragrance and a plant metabolite. It derives from a propan-1-ol.
Vorbereitung Methode
n-Propyl acetate is manufactured from acetic acid and a mixture of propene and propane in the presence of a zinc chloride catalyst. It is used as a solvent for nitrocellulose- based lacquers, waxes, polyamide inks, acrylic inks, and insecticide formulations .
Manufacturers include Eastman Chemical Company, Hoechst Celanese Corporation, and Union Carbide Corporation.
Aroma threshold values
Detection: 2.7 to 11 ppm. Aroma characteristics at 1.0%: pungent, solventlike ethereal, fruity lift, green banana sweet with an apple and tropical fruit nuance.
Taste threshold values
Taste characteristics at 10 to 15 ppm: bubble gum estery, fruity, ethereal, tutti-frutti, banana and honey.
Allgemeine Beschreibung
N-propyl acetate appears as a clear colorless liquid with a pleasant odor. Flash point 58°F. Less dense than water, Vapors are heavier than air.
Air & Water Reaktionen
Highly flammable. Slightly soluble in water.
Reaktivität anzeigen
Propyl acetate is an ester. Propyl acetate is colorless, highly flammable liquid, moderately toxic. Dangerous fire hazard when exposed to heat, flame, sparks, or strong oxidizers. When heated to decomposition Propyl acetate emits acrid smoke and irritating fumes [Lewis, 3rd ed., 1993, p. 1093].
Hazard
Flammable, dangerous fire risk, explosive limits in air 2–8%. Eye and upper respiratory tract irritant.
Health Hazard
The acute toxicity of n-propyl acetate islow in test animals. The toxicity, however,is slightly greater than ethyl acetate andisopropyl acetate. Exposure to its vaporsproduces irritation of the eyes, nose, andthroat and narcotic effects. A 5-hour expo sure to 9000- and 6000-ppm concentrationsproduced narcotic symptoms in cats andmice, respectively (Flury and Wirth 1933).A 4-hour exposure to 8000 ppm was lethalto rats. Ingestion of the liquid can cause narcotic action. A high dose can cause death. Adose of 3000 mg/kg by subcutaneous admin istration was lethal to cats. The liquid maycause mild irritation upon contact with skin
LD50 value, oral (mice): 8300 mg/kg.
Brandgefahr
HIGHLY FLAMMABLE: Will be easily ignited by heat, sparks or flames. Vapors may form explosive mixtures with air. Vapors may travel to source of ignition and flash back. Most vapors are heavier than air. They will spread along ground and collect in low or confined areas (sewers, basements, tanks). Vapor explosion hazard indoors, outdoors or in sewers. Runoff to sewer may create fire or explosion hazard. Containers may explode when heated. Many liquids are lighter than water.
Flammability and Explosibility
Highly flammable
Sicherheitsprofil
Moderately toxic by intraperitoneal and subcutaneous routes. Mildly toxic by ingestion and inhalation. Human systemic effects by inhalation: lachrymation, cough. A skin irritant. A narcotic at high concentrations. Isopropyl acetate is slightly less narcotic than normal propyl acetate. A flammable liquid and dangerous fire hazard when exposed to heat, flame, or oxidizers. Explosive in the form of vapor when exposed to heat or flame. Can react vigorously with oxidizing materials. To fight fire, use alcohol foam, CO2, dry chemical. When heated to decomposition it emits acrid smoke and irritating fumes.
mögliche Exposition
Propyl acetate is a used as a solvent for plastics and cellulose ester resins; perfume ingredient; component of food flavoring. It is also used as a chemical intermediate.
Environmental Fate
Photolytic. Reported rate constants for the reaction of n-propyl acetate and OH radicals in the atmosphere and aqueous solution are 2.7 x 10^-12 cm³/molecule?sec (Hendry and Kenley, 1979) and 2.30 x 10^-13 cm³/molecule?sec (Wallington et al., 1988b).
Chemical/Physical. Slowly hydrolyzes in water forming acetic acid and 1-propanol.
At an influent concentration of 1,000 mg/L, treatment with GAC resulted in an effluent concentration of 248 mg/L. The adsorbability of the carbon used was 149 mg/g carbon (Guisti et al., 1974).
Versand/Shipping
UN1276 n-Propyl acetate, Hazard Class: 3; Labels: 3-Flammable liquid.
läuterung methode
Wash the ester with saturated aqueous NaHCO3 until neutral, then with saturated aqueous NaCl. Dry it with MgSO4 and fractionally distil it. [Beilstein 2 IV 138.]
Inkompatibilitäten
Contact with nitrates, strong oxidizers; strong alkalis; strong acids; may pose risk of fire and explosions. Attacks plastic.
Filter für giftige stoffe
The final ITSL for n-propyl acetate is 8,350 μg/m3, 8-hour average.
Waste disposal
Dissolve or mix the material with a combustible solvent and burn in a chemical incinerator equipped with an afterburner and scrubber. All federal, state, and local environmental regulations must be observed.
Einzelnachweise
1.https://en.wikipedia.org/wiki/Propyl_acetate
2.http://www.hmdb.ca/metabolites/HMDB34237
3.http://www.eastman.com/Pages/ProductHome.aspx?product=71001052
4.http://www.khchemicals.com/zh/categories/acetates/n-propyl-acetate/
5.https://www.alfa.com/zh-cn/catalog/L15355/
6.http://product-finder.basf.com/group/corporate/product-finder/en/brand/N_PROPYL_ACETATE

Propyl acetate Upstream-Materialien And Downstream Produkte

Propylacetat Anbieter Lieferant Produzent Hersteller Vertrieb Händler.

109-60-4, Propyl acetate Verwandte Suche:

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