3-Aminophenol Produkt Beschreibung

3-Aminophenol Struktur
591-27-5
  • CAS-Nr.591-27-5
  • Bezeichnung:3-Aminophenol
  • Englisch Name:3-Aminophenol
  • Synonyma:3-Aminophenol
    furroeg;nakoteg;renaleg;ursoleg;Furro EG;Nako TEG;Renal EG;Ursol EG;c.i.76545;FurBrowEG
  • CBNumber:CB8853903
  • Summenformel:C6H7NO
  • Molgewicht:109.13
  • MOL-Datei:591-27-5.mol
3-Aminophenol physikalisch-chemischer Eigenschaften
  • Schmelzpunkt: :121 °C
  • Siedepunkt: :164 °C11 mm Hg(lit.)
  • Dichte :0.99
  • Brechungsindex :1.5444 (estimate)
  • Flammpunkt: :155 °C
  • storage temp.  :2-8°C
  • Löslichkeit :26g/l
  • Aggregatzustand :Crystalline Powder
  • pka :4.37, 9.82(at 20℃)
  • Colour Index  :76545
  • Farbe :White to pinkish or light gray
  • PH :6.8 (10g/l, H2O, 20℃)
  • Wasserlöslichkeit :35 g/L (20 ºC)
  • Merck  :14,460
  • BRN  :636059
  • Stabilität: :Stable. Combustible. Incompatible with strong oxidizing agents, bases, mineral acids. May be light or air-sensitive.
  • CAS Datenbank :591-27-5(CAS DataBase Reference)
  • NIST chemische Informationen :Phenol, 3-amino-(591-27-5)
Sicherheit
  • Kennzeichnung gefährlicher :Xn,N
  • R-Sätze: :20/22-51/53
  • S-Sätze: :28-61-28A
  • RIDADR  :UN 2512 6.1/PG 3
  • WGK Germany  :2
  • RTECS-Nr. :SJ4900000
  • TSCA  :Yes
  • HazardClass  :6.1
  • PackingGroup  :III
  • HS Code  :29222900
  • Giftige Stoffe Daten :591-27-5(Hazardous Substances Data)
  • Toxizität :LD50 i.p. in mice: 4.5 mg/20g (Koelzer, Giesen)

3-Aminophenol Chemische Eigenschaften,Einsatz,Produktion Methoden

  • R-Sätze Betriebsanweisung: R20/22:Gesundheitsschädlich beim Einatmen und Verschlucken.
    R51/53:Giftig für Wasserorganismen, kann in Gewässern längerfristig schädliche Wirkungen haben.
  • S-Sätze Betriebsanweisung: S28:Bei Berührung mit der Haut sofort abwaschen mit viel . . . (vom Hersteller anzugeben).
    S61:Freisetzung in die Umwelt vermeiden. Besondere Anweisungen einholen/Sicherheitsdatenblatt zu Rate ziehen.
  • Aussehen Eigenschaften C6H7NO; 3-Hydroxyanilin. Farblose bis gelbliche Schuppen mit phenolartigem Geruch.
  • Gefahren für Mensch und Umwelt Gesundheitsschädlich beim Einatmen, Verschlucken und Berührung mit der Haut.
    Methämoglobinbildner. Resorption führt zu Atemnot, Herzrhythmusstörungen, Krämpfen und Cyanose. Schädigt die Nieren.
    Nicht mit starken Oxidationsmitteln in Berührung bringen.
    LD50 (oral, Ratte): 1000 mg/kg
  • Schutzmaßnahmen und Verhaltensregeln Geeignete Schutzhandschuhe als kurzzeitiger Staubschutz.
  • Verhalten im Gefahrfall Trocken aufnehmen. Der Entsorgung zuführen.
    Kohlendioxid, Wasser, Pulver.
    Brennbar. Im Brandfall können nitrose Gase freigesetzt werden.
  • Erste Hilfe Nach Hautkontakt: Mit reichlich Wasser abwaschen.
    Nach Augenkontakt: Mit reichlich Wasser bei geöffnetem Lidspalt mindestens 10 Minuten ausspülen. Sofort Augenarzt hinzuziehen.
    Nach Einatmen: Frischluft.
    Nach Verschlucken: Viel Wasser trinken. Erbrechen auslösen. Arzt hinzuziehen.
    Nach Kleidungskontakt: Kontaminierte Kleidung entfernen.
    Ersthelfer: siehe gesonderten Anschlag

  • Sachgerechte Entsorgung Gelöst in z.B. Ethanol als halogenfreie, organische Lösemittelabfälle.
  • Chemische Eigenschaften Light grey crystal powder
  • Chemische Eigenschaften o-Aminophenol appears as colorless needles or as white crystalline substance turning tan to brown on exposure to air.
  • Verwenden Dye intermediate, manufacture of p-aminosalicylic acid.
  • Verwenden m-Aminophenol (MAP) is an important starting material for dyes, including a variety of leuco (or latent) dyes used in imaging technology, optical bleaches and fluorescent agents, drugs, agricultural chemicals; and high-performance polymers. Although the synthesis of m-aminophenol(s) by the reaction of resorcinol with ammonia or (di)alkylarnines has been known for about 100 years,the preferred manufacturing process had been for many years a route involving the sulfonation of nitrobenzene to m-nitrobenzenesulfonic acid, the reduction of the nitro group to give m-aminobenzenesulfonic acid, followed by the caustic fusion of sodium m-aminobenzenesulfonate to yield sodium m-aminophenolate. The m-aminophenol was isolated/purified by neutralization, filtration, and recrystallization; the overall yield of m-aminophenol from nitrobenzene was estimated by SRI International to be 58%. (Doubtless, process improvements were made by the producers using this process.) The nitrobenzene/sulfonationlreductionlcaustic fusion route is still being used commercially, notably by ACNA in Italy, the largest producer of MAP, as well as a few smaller manufacturers. Sumitomo Chemical Co. used this process as well into the early 1980s and had licensed their knowhow to Hindustani Organic Chemicals, Ltd. of India which started up a plant on this basis with a capacity for MAP of 1.5 mill. lb /yr in 1970.The output of the Indian plant was said to be devoted to making sodium p-aminosalycilate (PAS), a tuberculostatic agent.
  • Definition ChEBI: An aminophenol that is one of three amino derivatives of phenol which has the single amino substituent located meta to the phenolic -OH group.
  • Allgemeine Beschreibung White crystals or off-white flakes.
  • Air & Water Reaktionen 3-Aminophenol may be sensitive to prolonged exposure to air and light. Slightly soluble in water.
  • Reaktivität anzeigen 3-Aminophenol may react with strong oxidizers and mineral acids or bases.
  • Hazard Toxic by ingestion.
  • Brandgefahr Flash point data for 3-Aminophenol are not available. 3-Aminophenol is probably combustible.
  • Sicherheitsprofil Poison by ingestion, subcutaneous, and intraperitoneal routes. An experimental teratogen. Other experimental reproductive effects. Mutation data reported. A skin and eye irritant. When heated to decomposition it emits toxic fumes of NOx,.
  • mögliche Exposition Workers may be exposed to oAminophenol during its use as a chemical intermediate; in the manufacture of azo and sulfur dyes; and in the photographic industry. There is potential for consumer exposure to o-Aminophenol because of its use in dyeing hair, fur, and leather. The compound is a constituent of 75 registered cosmetic products suggesting the potential for widespread consumer exposure. p-Aminophenol is used mainly as a dye, dye intermediate and as a photographic developer; and in small quantities in analgesic drug preparation. Consumer exposure to p-aminophenol may occur from use as a hairdye or as a component in cosmetic preparations. mAminophenol is used mainly as a dye intermediate
  • Versand/Shipping UN2512 Aminophenols (o-; m-; p-), Hazard Class: 6.1; Labels: 6.1-Poisonous materials
  • läuterung methode Crystallise it from hot water or toluene. [Beilstein 13 IV 952.]
  • Inkompatibilitäten These phenol/cresol materials can react with oxidizers; reaction may be violent. Incompatible with strong reducing substances such as alkali metals, hydrides, nitrides, and sulfides. Flammable gas (H2) may be generated, and the heat of the reaction may cause the gas to ignite and explode. Heat may be generated by the acidbase reaction with bases; such heating may initiate polymerization of the organic compound. Reacts with boranes, alkalies, aliphatic amines, amides, nitric acid, sulfuric acid. Phenols are sulfonated very readily (e.g., by concentrated sulfuric acid at room temperature). These reactions generate heat. Phenols are also nitrated very rapidly, even by dilute nitric acid and can explode when heated. Many phenols form metal salts that may be detonated by mild shock.
  • Waste disposal Dissolve or mix the material with a combustible solvent and burn in a chemical incinerator equipped with an afterburner and scrubber. All federal, state, and local environmental regulations must be observed.
3-Aminophenol Upstream-Materialien And Downstream Produkte
Upstream-Materialien
Downstream Produkte
3-Aminophenol Anbieter Lieferant Produzent Hersteller Vertrieb Händler.
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