Iodmonochlorid Produkt Beschreibung

Iodine monochloride Struktur
7790-99-0
  • CAS-Nr.7790-99-0
  • Bezeichnung:Iodmonochlorid
  • Englisch Name:Iodine monochloride
  • Synonyma:Iodmonochlorid
    ICl;IODOCHLORIDE;iodochlorine;WIJS REAGENT;CHLOROIODIDE;WIJS SOLUTION;WIJS' REAGENT;WIJS CHLORIDE;Iodine monochL;Iodmonochlorid
  • CBNumber:CB8664819
  • Summenformel:ClI
  • Molgewicht:162.36
  • MOL-Datei:7790-99-0.mol
Iodmonochlorid physikalisch-chemischer Eigenschaften
  • Schmelzpunkt: :25-27°C
  • Siedepunkt: :97.4 °C (lit.)
  • Dichte :3.24 g/mL at 25 °C (lit.)
  • Dampfdichte :5.5 (vs air)
  • Flammpunkt: :96-98°C
  • storage temp.  :2-8°C
  • Löslichkeit :acetic acid: soluble(lit.)
  • Aggregatzustand :Liquid
  • Farbe :Red-brown
  • PH :<1 (H2O, 20°C)
  • Wasserlöslichkeit :decomposes
  • Sensitive  :Moisture Sensitive
  • Merck  :14,5017
  • BRN  :3902972
  • Stabilität: :Stable. Incompatible with organic materials, strong bases, metals. Air, light and moisture sensitive.
  • CAS Datenbank :7790-99-0(CAS DataBase Reference)
  • NIST chemische Informationen :Iodine monochloride(7790-99-0)
  • EPA chemische Informationen :Iodine chloride (ICl) (7790-99-0)
Sicherheit

Iodine monochloride Chemische Eigenschaften,Einsatz,Produktion Methoden

  • R-Sätze Betriebsanweisung: R34:Verursacht Verätzungen.
    R42:Sensibilisierung durch Einatmen möglich.
    R35:Verursacht schwere Verätzungen.
    R10:Entzündlich.
    R40:Verdacht auf krebserzeugende Wirkung.
  • S-Sätze Betriebsanweisung: S26:Bei Berührung mit den Augen sofort gründlich mit Wasser abspülen und Arzt konsultieren.
    S36/37/39:Bei der Arbeit geeignete Schutzkleidung,Schutzhandschuhe und Schutzbrille/Gesichtsschutz tragen.
    S45:Bei Unfall oder Unwohlsein sofort Arzt zuziehen (wenn möglich, dieses Etikett vorzeigen).
    S23:Gas/Rauch/Dampf/Aerosol nicht einatmen(geeignete Bezeichnung(en) vom Hersteller anzugeben).
  • Chemische Eigenschaften dark red or brown solid and/or liquid
  • Physikalische Eigenschaften Colorless gas; mold-like pungent odor; melting point 6.45°C; sublimes at4.77°C; supercools to a colorless liquid that boils at 4.5°C; liquid density2.8g/mL at 6°C; soluble in water.
  • Verwenden Iodine monochloride is used to estimate theiodine values of fats and oils and as a topicalanti-infective (Merck 1996).
  • Verwenden In Wijs' solution (iodine monochloride in glacial acetic acid), used to determine iodine values of fats and oils.
  • synthetische Iodine monochloride is prepared by the action of liquid or dry chlorine on astoichiometric quantity of solid iodine. Aqueous solutions of ICl are preparedby passing chlorine gas into a suspension of iodine in moderately stronghydrochloric acid:
    5I2 + 4HCl + 3Cl2 → 10ICl + 2H2
    Alternatively, iodine monochloride may be made by oxidation of iodine withiodic acid in strong hydrochloric acid solution:
    2I2 + HIO3 + 2HCl → 2ICl + 3HIO
  • Allgemeine Beschreibung Black crystals or a reddish brown oily liquid with a pungent odor. Melting point 27°C (alpha form) or 14°C (beta form). Corrosive to metals and tissue.
  • Air & Water Reaktionen Reacts with air to form iodine pentaoxide (I2O5), which decomposes into iodine (I2) and oxygen (O2) with heat beginning at 275°C and proceeding rapidly at 350°C. Soluble in water; reacts with water or steam to produce toxic and corrosive fumes [Lewis].
  • Reaktivität anzeigen Iodine monochloride is moderately explosive when heated [Lewis]. Reacts with rubber and many organic materials. Enflames (after a period of delay) with aluminum foil [Mellor 2:119(1946-1947)]. Reacts dangerously with other active metals. Reacts vigorously with cadmium sulfide, lead sulfide, silver sulfide, and zinc sulfide [Mellor 2, Supp. 1:502(1956)]. Combines very exothermically with phosphorus trichloride [Mellor 2, Supp. 1:502(1956)]. Forms Iodine pentaoxide in air which reacts explosively when warmed with carbon, sulfur, sugar, resin, or powdered combustible elements [Mellor 8: 841(1946-1947)].
  • Hazard Toxic by ingestion and inhalation, strong irritant to eyes and skin.
  • Health Hazard Iodine monochloride is highly corrosive tothe skin. Contact with the skin causes burns and dark patches. Upon contact, washimmediately with 15-20% HCl. Vapors areirritating to the skin, eyes, and mucous mem branes. The compound is moderate to highlytoxic by an oral route. The lethal dose in ratsis 59 mg/kg (NIOSH 1986).
  • Health Hazard TOXIC; inhalation, ingestion or contact (skin, eyes) with vapors, dusts or substance may cause severe injury, burns or death. Reaction with water or moist air will release toxic, corrosive or flammable gases. Reaction with water may generate much heat that will increase the concentration of fumes in the air. Fire will produce irritating, corrosive and/or toxic gases. Runoff from fire control or dilution water may be corrosive and/or toxic and cause pollution.
  • Brandgefahr Non-combustible, substance itself does not burn but may decompose upon heating to produce corrosive and/or toxic fumes. Vapors may accumulate in confined areas (basement, tanks, hopper/tank cars etc.). Substance will react with water (some violently), releasing corrosive and/or toxic gases and runoff. Contact with metals may evolve flammable hydrogen gas. Containers may explode when heated or if contaminated with water.
  • läuterung methode Purify it by repeated fractional crystallisation from its melt at low temperatures. The black crystals melt to a red-brown liquid. [Cornog & Karges Inorg Synth I 165 1939.]
Iodine monochloride Upstream-Materialien And Downstream Produkte
Upstream-Materialien
Downstream Produkte
Iodmonochlorid Anbieter Lieferant Produzent Hersteller Vertrieb Händler.
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7790-99-0, Iodine monochloride Verwandte Suche:
  • IodineMonochlorideForSynthesis(5X25Grams)
  • Iodinemonochloride,97%
  • Iodinechloride,ACS
  • Iodine monochloride, ACS
  • Iodine monochloride solution (Wijs' chloride)
  • Chloroiodide solution, Iodine according to Wijs for the iodine value determination, Iodine monochloride solution, Wijs solution
  • Chloroiodide solution, Wijs solution
  • Iodine Monochloride, Reagent
  • IODOMONOCHLORIDE
  • IODOCHLORIDE
  • IODINE SOLUTION ACCORDING TO WIJS
  • iodochlorine
  • Protochlorure D'iode
  • protochlorured’iode
  • protochlorured’iode(french)
  • IODINE MONOCHLORIDE, A.C.S. REAGENT
  • Wijs solution, 0,1 mol Cl/l, volumetric solution
  • Iodine monochloride, 99.998% metals basis
  • WIJS SOL. FOR DET. OF IODINE VALUE 0.1
  • IODINE MONOCHLORIDE REAGENT GRADE 98%
  • IODINE MONOCHLORIDE 1.0M SOLUTION &
  • IODINE MONOCHLORIDE, 1.0M SOLUTION IN DI CHLOROMETHANE
  • IODINE MONOCHLORIDE BOTTLE OF 100 G
  • IodineMonochlorideForSynthesis(5X50Grams)
  • IodineMonochlorideForSynthesis
  • Iodine(I) chloride
  • Iodine monochloride, reagent ACS
  • Iodine monochloride solution
  • Iodine monochloride,1M solution in dichloromethane
  • Iodine monochloride,98%
  • Iodine monochL
  • Iodmonochlorid
  • Monochloroiodine
  • (DG) Iodine monochloride 10g [7790-99-0]
  • Iodine chloride/ 98+%
  • Iodine monochloride,Chloroiodide
  • Iodine monochloride, 1M solution in dichloromethane, AcroSeal
  • Iodine Monochloride, 98% 100GR
  • Iodine Monochloride, reagent ACS 25GR
  • Iodine Monochlorid
  • Iodine Monochloride, approx. 0.22N soln. in glacial acetic acid
  • WIJS SOLUTION
  • WIJS' SOLUTION
  • WIJS REAGENT
  • WIJS' REAGENT
  • WIJS IODINE SOLUTION
  • WIJ'S IODINE SOLUTION
  • WIJS CHLORIDE
  • WIJS' CHLORIDE
  • chlorineiodide(cli)
  • ICl
  • Iodine chloride (ICl)
  • iodinechloride(icl)
  • iodinechloride[icl]
  • iodinemonochloride(dot)
  • Chloroiodide solution, Iodine according to Wijs for the iodine valu
  • IODINE MONOCHLORIDE SOLUTION, WIJS
  • IODINE MONOCHLORIDE