Dibutylether

Bezeichnung:Dibutylether

CAS-Nr142-96-1

Englisch Name:Dibutyl ether

CBNumberCB2775063

SummenformelC8H18O

Molgewicht130.23

MOL-Datei142-96-1.mol

Synonyma

Dibutylether

Di-n-butylether

1,1'-Oxybisbutan

Dibutylether physikalisch-chemischer Eigenschaften

Schmelzpunkt	-98 °C (lit.)
Siedepunkt	142-143 °C (lit.)
Dichte	0.764 g/mL at 25 °C (lit.)
Dampfdichte	4.48 (vs air)
Dampfdruck	4.8 mm Hg ( 20 °C)
Brechungsindex	n20/D 1.399(lit.)
Flammpunkt	77 °F
storage temp.	Store at <= 20°C.
Löslichkeit	H2O: soluble0.113g/L at 20°C
Aggregatzustand	Liquid
Farbe	Clear colorless
PH	5.2 (0.2g/l, H2O, 20℃)
Relative polarity	1.7
Geruch (Odor)	Mild, ether-like.
Säure-Base-Indikators(pH-Indikatoren)	5.2
Explosionsgrenze	0.9-8.5%(V)
Wasserlöslichkeit	0.03 g/100 mL (20 ºC)
Merck	14,1569
BRN	1732752
Dielectric constant	3.1（25℃）
Stabilität	Stable. Flammable. May form peroxides in storage. Incompatible with strong oxidizing agents.
InChIKey	DURPTKYDGMDSBL-UHFFFAOYSA-N
LogP	3.35
CAS Datenbank	142-96-1(CAS DataBase Reference)
NIST chemische Informationen	n-Butyl ether(142-96-1)
EPA chemische Informationen	Butyl ether (142-96-1)

Sicherheit

Kennzeichnung gefährlicher	Xi
R-Sätze:	10-36/37/38-52/53
S-Sätze:	61-24/25
RIDADR	UN 1149 3/PG 3
WGK Germany	2
RTECS-Nr.	EK5425000
Selbstentzündungstemperatur	365 °F
Hazard Note	Irritant
TSCA	Yes
HazardClass	3
PackingGroup	III
HS Code	29091990
Giftige Stoffe Daten	142-96-1(Hazardous Substances Data)
Toxizität	LD50 orally in rats: 7.4 g/kg (Smyth)

Gefahreninformationscode (GHS)

Dibutyl ether Chemische Eigenschaften,Einsatz,Produktion Methoden

ERSCHEINUNGSBILD
FARBLOSE FLüSSIGKEIT.
PHYSIKALISCHE GEFAHREN
Fließen, Schütten o.ä. kann zu elektrostatischer Aufladung führen.
CHEMISCHE GEFAHREN
Bildung explosionsfähiger Peroxide, besonders im wasserfreien Zustand. Reagiert mit Oxidationsmitteln. Reagiert sehr heftig mit Stickstofftrichlorid (NCl3).
ARBEITSPLATZGRENZWERTE
TLV nicht festgelegt (ACGIH 2005).
MAK nicht festgelegt (DFG 2005).
AUFNAHMEWEGE
Aufnahme in den Körper durch Inhalation der Dämpfe.
INHALATIONSGEFAHREN
Nur ungenügende Angaben vorhanden über die Geschwindigkeit, mit der eine gesundheitsschädliche Konzentration in der Luft beim Verdampfen bei 20°C erreicht wird.
WIRKUNGEN BEI KURZZEITEXPOSITION
WIRKUNGEN BEI KURZZEITEXPOSITION:
Die Substanz reizt die Augen, die Haut und die Atemwege. Möglich sind Auswirkungen auf Zentralnervensystem und Leber.
WIRKUNGEN NACH WIEDERHOLTER ODER LANGZEITEXPOSITION
Die Flüssigkeit entfettet die Haut.
LECKAGE
Ausgelaufene Flüssigkeit möglichst in abdichtbaren Behältern sammeln. Reste mit Sand oder inertem Absorptionsmittel aufnehmen und an einen sicheren Ort bringen. Persönliche Schutzausrüstung: Atemschutzgerät, A/P2-Filter für organische Dämpfe und schädlichen Staub.
R-Sätze Betriebsanweisung:
R10:Entzündlich.
R36/37/38:Reizt die Augen, die Atmungsorgane und die Haut.
R52/53:Schädlich für Wasserorganismen, kann in Gewässern längerfristig schädliche Wirkungen haben.
S-Sätze Betriebsanweisung:
S61:Freisetzung in die Umwelt vermeiden. Besondere Anweisungen einholen/Sicherheitsdatenblatt zu Rate ziehen.
Aussehen Eigenschaften
C8H18O; Butylether, Di-n-butylether. Farblose Flüssigkeit mit chrakteristischem Geruch.
Gefahren für Mensch und Umwelt
Reizt die Atmungsorgane, Augen und die Haut.
Nach Einatmen Atemnot oder Narkose. Kann zu Leber- und Nierenschäden führen.
Gefährliche Zersetzungsprodukte sind Peroxide.
Entzündlich.
LD₅₀ (oral, Ratte): 7400 mg/kg
Schutzmaßnahmen und Verhaltensregeln
Geeignete Schutzhandschuhe als kurzzeitiger Spritzschutz.
Verhalten im Gefahrfall
Mit flüssigkeitsbindendem Material, z.B. Rench Rapid aufnehmen. Der Entsorgung zuführen. Nachreinigen.
Kohlendioxid, Wasser, Schaum, Pulver.
Brennbar. Dämpfe schwerer als Luft. Mit Luft Bildung explosionsfähiger Gemische möglich.
Erste Hilfe
Nach Hautkontakt: Mit reichlich Wasser abwaschen.
Nach Augenkontakt: Mit reichlich Wasser bei geöffnetem Lidspalt mindestens 10 Minuten ausspülen. Augenarzt hinzuziehen.
Nach Einatmen: Frischluft.
Nach Verschlucken: Reichlich Wasser trinken lassen. Erbrechen auslösen. Arzt hinzuziehen.
Nach Kleidungskontakt: Kontaminierte Kleidung entfernen.
Ersthelfer: siehe gesonderten Anschlag
Sachgerechte Entsorgung
Als halogenfreie, organische Lösemittelabfälle.
Beschreibung
Butyl ether (dibutyl ether) is a colorless, stable liquid, with a mild ether-like odor. It is immiscible with water, with a specific gravity of 0.8, which is lighter than water. Butyl ether is a moderate fire risk and will form explosive peroxides on aging. Flammable range is 1.5%–7.6% in air, with a boiling point of 286°F (141°C) and a flash point of 77°F (25°C). Ignition temperature is 382°F (194°C), and the vapor density is 4.5, which is heavier than air. In addition to flammability, butyl ether is toxic on prolonged inhalation. The four-digit UN identification number is 1149. The NFPA 704 designation is health 2, flammability 3, and reactivity 1. The primary use is as a solvent.
Chemische Eigenschaften
Dibutyl ether is a flammable, colorless liquid with a mild, ethereal odor.
Verwenden
Dibutyl ether is used mainly as a solvent for organic materials such as resins, oils, hydrocarbons, esters, gums, and alkaloids. It is also used as an extracting agent in metal separation, as a reacting medium in organic synthesis processes, and as a solvent in teaching, research and analytical laboratories.
Verwenden
Di-n-butyl ether is used as a solvent for Grignard, Witting and alkyl lithium reactions. It is also used as a solvent for oils and fats and some natural and synthetic resins. It is considered as a replacement for terathydofuran in organic synthesis due to its less water and peroxide and high boiling point. In the pharmaceutical industry, it is used in the manufacturing process of active pharmaceutical ingredient such as procarbazine and cefaclor. In addition to this, it is used as an important solvent for the application of the coating.
Allgemeine Beschreibung
Di-n-butyl ether is a clear colorless liquid with an ethereal odor. Flash point below 141°F. Less dense than water and insoluble in water. Vapors heavier than air. Irritates the eyes, nose, throat, and respiratory tract.
Air & Water Reaktionen
Dibutyl ether is flammable and oxidises readily in air to form unstable peroxides which may spontaneously explode. Mixtures of liquid air and Dibutyl ether will also spontaneously combust and explode. The product is insoluble in water.
Reaktivität anzeigen
Ethers, such as BUTYL ETHER can act as bases. They form salts with strong acids and addition complexes with Lewis acids. The complex between diethyl ether and boron trifluoride is an example. Ethers may react violently with strong oxidizing agents. In other reactions, which typically involve the breaking of the carbon-oxygen bond, ethers are relatively inert.
Hazard
Toxic on prolonged inhalation. Flammable, moderate fire risk. May form explosive peroxides, especially in anhydrous form.
Health Hazard
Inhalation causes irritation of nose and throat. Liquid irritates eyes and may irritate skin on prolonged contact. Ingestion causes irritation of mouth and stomach.
Brandgefahr
Behavior in Fire: Vapor is heavier than air and may travel a considerable distance to a source of ignition and flash back.
Chemische Reaktivität
Reactivity with Water No reaction; Reactivity with Common Materials: No reaction; Stability During Transport: Stable; Neutralizing Agents for Acids and Caustics: Not pertinent; Polymerization: Not pertinent; Inhibitor of Polymerization: Not pertinent.
Industrielle Verwendung
n-Butyl ether is used in synthesis reactions that require an anhydrous, inert solvent. This ether is a valuable extraction solvent for aqueous solutions because of its low water solubility. n-Butyl ether when mixed with ethanol or butanol is an excellent solvent for ethyl cellulose.
Sicherheitsprofil
Mildly toxic by inhalation, ingestion, and skin contact. Human systemic effects by inhalation: conjunctiva irritation and unspecified nasal effects. An experimental skin and human eye irritant. See also ETHERS. Dangerous fire hazard when exposed to heat, flame, oroxidizers. Incompatible with NCL and oxidizing materials. To fight fire, use alcohol foam, dry chemical. When heated to decomposition it emits acrid smoke and fumes.
mögliche Exposition
Di-n-butyl ether is used as a solvent for hydrocarbons, fatty materials; extracting agent in used metals separation; solvent purification, making other chemicals. Incompatibilities: May form explosive mixture with air. May accumulate static electrical charges, and may cause ignition of its vapors. Incompatible with strong acids; oxidizers. Contact with air or light may form unstable and explosive peroxides, especially anhydrous form.
Erste Hilfe
If this chemical gets into the eyes, remove anycontact lenses at once and irrigate immediately for at least15 min, occasionally lifting upper and lower lids. Seek medical attention immediately. If this chemical contacts the skin,remove contaminated clothing and wash immediately withsoap and water. Seek medical attention immediately. If thischemical has been inhaled, remove from exposure, begin rescue breathing (using universal precautions, includingresuscitation mask) if breathing has stopped and CPR if heartaction has stopped. Transfer promptly to a medical facility.When this chemical has been swallowed, get medical attention. Give large quantities of water and induce vomiting. Donot make an unconscious person vomit.
Environmental Fate
Butyl ether has the ability to dissolve lipids. As a result, it causes irritation and pain on contact with the eyes and nasal mucosa. It also causes dermal irritation and dermatitis on contact with the skin. Damage caused by butyl ether appears to be scattered loss of epithelial cells due to solution of phospholipid cell membranes. At the central nervous system (CNS) level, butyl ether, like other volatile organic solvents, depresses the CNS by dissolving in the lipid membrane of the cells and disrupting the lipid matrix. These effects are known as membrane fluidization. At the molecular level, membrane fluidization disrupts solute gradient homeostasis, which is essential for cell function.
Lager
Color Code—Red: Flammability Hazard: Store ina flammable liquid storage area or approved cabinet awayfrom ignition sources and corrosive and reactive materials.Prior to working with butyl ether you should be trained onits proper handling and storage. Before entering confinedspace where this chemical may be present, check to makesure that an explosive concentration does not exist. Butylether must be stored in a cool, dark place, separated fromoxidizers (such as perchlorates, peroxides, permanganates,chlorates, and nitrates), since violent reactions occur. Storein tightly closed containers in a cool, well-ventilated area.Protect storage containers from physical damage. Sourcesof ignition, such as smoking and open flames, are prohibited where Butyl ether is handled, used, or stored. Metalcontainers involving the transfer of 5 gallons or more ofbutyl ether should be grounded and bonded. Drums must beequipped with self-closing valves, pressure vacuum bungs,and flame arresters. Use only nonsparking tools and equipment, especially when opening and closing containers ofButyl ether.
Versand/Shipping
UN1149 Butyl ethers & Dibutyl ethers, Hazard Class: 3; Labels: 3—Flammable liquid
läuterung methode
Peroxides (detected by the liberation of iodine from weakly acid HCl solutions of 2% KI) can be removed by shaking 1L of ether with 5-10mL of a solution comprising of 6.0g of ferrous sulfate and 6mL conc H2SO4 and 110mL of water, with aqueous Na2SO3, or with acidified NaI, water, then aqueous Na2S2O3. After washing with dilute NaOH, KOH, or Na2CO3, then water, the ether is dried with CaCl2 and distilled. It can be further dried by distillation from CaH2 or Na (after drying with P2O5), and stored in the dark with Na or NaH. The ether can also be purified by treating with CS2 and NaOH, expelling the excess sulfide by heating. The ether is then washed with water, dried with NaOH and distilled [Kusama & Koike J Chem Soc Jpn, Pure Chem Sect 72 229 1951]. Other purification procedures include passage through an activated alumina column to remove peroxides, or through a column of silica gel, and distillation after adding about 3% (v/v) of a 1M solution of MeMgI in n-butyl ether. [Beilstein 1 IV 1520.]
Toxicity evaluation
Production of butyl ether and its use as an extracting agent and a solvent may result in its release to the environment through various waste streams. If released to air, a vapor pressure of 6.0 mmHg at 25°C indicates that butyl ether will exist solely as a vapor in the ambient atmosphere. Vaporphase butyl ether reacts in the atmosphere with hydroxyl radicals; the half-life for this reaction in air has been estimated to be 13 h. Direct photolysis is not expected to be an important removal process since aliphatic ethers do not absorb light in the environmental spectrum. If released to soil, butyl ether is expected to have high mobility based on its estimated adsorption coefficient (Koc) of 51. Volatilization from moist soil surfaces may be an important fate process based on its reported Henry’s law constant of 6.0×10^-3 atm m³ mol^-1. Butyl ether is expected to volatilize from dry soil surfaces based on its reported vapor pressure. If released into water, butyl ether is not expected to adsorb to suspended solids and sediment in water based on its Koc. Aqueous screening studies indicate biodegradation may be an important fate process in both soil and water; for example, butyl ether reached 3–4% of its theoretical biological oxygen demand (BOD) over 4 weeks using an activated sludge seed. Volatilization from water surfaces is expected to occur based on this compound’s estimated Henry’s law constant. Estimated volatilization half-lives for a model river and model lake have been reported to be 3.5 h and 4.6 days, respectively. Bioconcentration factors (BCFs) ranging from 30 to 114 in carp suggest that bioconcentration in aquatic organisms is moderate to high. Butyl ether is not expected to undergo hydrolysis in the environment due to the lack of hydrolyzable functional groups.
Inkompatibilitäten
Forms explosive mixture with air. Mayaccumulate static electrical charges, and may cause ignitionof its vapors. Incompatible with strong acids and oxidizers.Contact with air or light may form unstable and explosiveperoxides, especially anhydrous form.
Waste disposal
Dissolve or mix the material with a combustible solvent and burn in a chemical incinerator equipped with an afterburner and scrubber. All federal, state, and local environmental regulations must be observed.

Dibutyl ether Upstream-Materialien And Downstream Produkte

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