(tert-Butyl)methylether

Gefahreninformationscode (GHS)

• Bildanzeige (GHS)

  

• Alarmwort

  Achtung

• Gefahrenhinweise

  H225：Flüssigkeit und Dampf leicht entzündbar.

  H315：Verursacht Hautreizungen.

• Sicherheit

  P210：Von Hitze, heißen Oberflächen, Funken, offenen Flammen und anderen Zündquellenarten fernhalten. Nicht rauchen.

  P233：Behälter dicht verschlossen halten.

  P240：Behälter und zu befüllende Anlage erden.

  P241：Explosionsgeschützte [elektrische/Lüftungs-/ Beleuchtungs-/...] Geräte verwenden.

  P242：Nur funkenfreies Werkzeug verwenden.

  P303+P361+P353：BEI BERÜHRUNG MIT DER HAUT (oder dem Haar): Alle kontaminierten Kleidungsstücke sofort ausziehen. Haut mit Wasser abwaschen oder duschen.

tert-Butyl methyl ether Chemische Eigenschaften,Einsatz,Produktion Methoden

• ERSCHEINUNGSBILD

  FARBLOSE FLüSSIGKEIT MIT CHARAKTERISTISCHEM GERUCH.

• PHYSIKALISCHE GEFAHREN

  Die Dämpfe sind schwerer als Luft und können sich am Boden ausbreiten. Fernzündung möglich.

• CHEMISCHE GEFAHREN

  Reagiert sehr heftig mit starken Oxidationsmitteln unter Feuergefahr. Zersetzung bei Kontakt mit Säuren.

• ARBEITSPLATZGRENZWERTE

  TLV: 50 ppm (als TWA); Krebskategorie A3 (bestätigte krebserzeugende Wirkung beim Tier mit unbekannter Bedeutung für den Menschen); (ACGIH 2005).
  MAK: 50 ppm, 180 mg/m? Spitzenbegrenzung: überschreitungsfaktor (I)1.5; Krebserzeugend Kategorie 3B; Schwangerschaft: Gruppe C; (DFG 2005).
  

• AUFNAHMEWEGE

  Aufnahme in den Körper durch Inhalation und durch Verschlucken.

• INHALATIONSGEFAHREN

  Beim Verdampfen bei 20°C kann schnell eine gesundheitsschädliche Kontamination der Luft eintreten.

• WIRKUNGEN BEI KURZZEITEXPOSITION

  WIRKUNGEN BEI KURZZEITEXPOSITION:
  Die Substanz reizt die Haut Verschlucken kann zur Aufnahme in der Lunge führen; Gefahr der Aspirationspneumonie. Exposition weit oberhalb der Arbeitsplatzgrenzwerte kann Bewusstseinstrübung verursachen.

• LECKAGE

  Zündquellen entfernen. Ausgelaufene Flüssigkeit möglichst in abdichtbaren Behältern sammeln. Reste mit Sand oder inertem Absorptionsmittel aufnehmen und an einen sicheren Ort bringen. NICHT in die Kanalisation spülen. Persönliche Schutzausrüstung: Atemschutzfilter für organische Gase und Dämpfe.

• R-Sätze Betriebsanweisung:

  R36/37/38:Reizt die Augen, die Atmungsorgane und die Haut.
  R40:Verdacht auf krebserzeugende Wirkung.
  R38:Reizt die Haut.
  R11:Leichtentzündlich.
  R39/23/24/25:Giftig: ernste Gefahr irreversiblen Schadens durch Einatmen, Berührung mit der Haut und durch Verschlucken.
  R23/24/25:Giftig beim Einatmen, Verschlucken und Berührung mit der Haut.

• S-Sätze Betriebsanweisung:

  S9:Behälter an einem gut gelüfteten Ort aufbewahren.
  S16:Von Zündquellen fernhalten - Nicht rauchen.
  S24:Berührung mit der Haut vermeiden.
  S45:Bei Unfall oder Unwohlsein sofort Arzt zuziehen (wenn möglich, dieses Etikett vorzeigen).
  S36/37:Bei der Arbeit geeignete Schutzhandschuhe und Schutzkleidung tragen.

• Aussehen Eigenschaften

  C5H12O; Methyl-tert.-butylether; farblose Flüssigkeit mit charakteristischem Geruch.

• Gefahren für Mensch und Umwelt

  Tert.-Butylmethylether ist leichtentzündlich und bildet mit Luft explosionsfähige Gemische. Die Dämpfe sind schwerer als Luft. Mit starken Säuren heftige Reaktionen.
  Nach längerer Exposition kann es zu Schläfrigkeit, Schwindel, Erregung, Krämpfen und unter Umständen zu narkosierenden Zuständen kommen. Hautresorption und Hautreizungen möglich. Nach Verschlucken Übelkeit und Erbrechen.
  Schwach wassergefährdender Stoff.

• Schutzmaßnahmen und Verhaltensregeln

  Schutzhandschuhe aus Neopren (nur als kurzzeitiger Spritzschutz).

• Verhalten im Gefahrfall

  Mit flüssigkeitsbindendem Material (z.B. Rench Rapid) aufnehmen. Als Sondermüll entsorgen.
  Kohlendioxid, Schaum, Pulver.

• Erste Hilfe

  Nach Hautkontakt: Mit viel Wasser und Seife abwaschen.
  Nach Augenkontakt: Bei geöffnetem Lidspalt mit viel Wasser mindestens 10 Minuten spülen. Augenarzt konsultieren.
  Nach Einatmen: Frischluft. Atmung überwachen; ggf. Atemspende oder Gerätebeatmung.
  Nach Verschlucken: Erbrechen vermeiden - Aspirationsgefahr! Sofort Arzt konsultieren. Aktivkohle (20 - 40 g in 10%iger Aufschlämmung).
  Nach Kleidungskontakt: Kontaminierte Kleidung sofort ausziehen.
  Ersthelfer: siehe gesonderten Anschlag

• Sachgerechte Entsorgung

  Als Sondermüll entsorgen (Sammelbehälter für halogenfreie Lösungsmittel).

• Beschreibung

  Methyl-tert-butyl ether is a colorless liquid. Molecular weight= 88.17;Boiling point=54℃; Freezing/ Melting point=109℃; Flash point=10℃. Hazard Identification (based on NFPA-704 M Rating System): Health 2, Flammability 3, Reactivity 1. Soluble in water.

• Chemische Eigenschaften

  tert-Butyl methyl ether, also known as MTBE or Methyl tert-butyl ether, is a clear, colorless liquid with a low viscosity that is combustible and has a distinct, turpentine-like odor. It is miscible with organic solvents, but only slightly soluble in water. Methyl tert-butyl ether is very stable under alkaline, neutral, and weakly acidic conditions. In the presence of strong acids, it is cleaved to methanol and isobutene. Depending on reaction conditions the latter can form isobutene oligomers. MTBE does not undergo autoxidation and, in contrast to other ethers, it does not form peroxides with atmospheric oxygen. It improves the antiknock properties when added to motor gasoline.

• History

  tert-Butyl methyl ether was first synthesized (by the classical Williamson ether synthesis) and characterized in 1904. Extensive studies in the United States during World War II demonstrated the outstanding qualities of MTBE as a high-octane fuel component. It was first commercially produced in Italy in 1973 for use as an octane enhancer in gasoline. U.S. production of MTBE started in 1979 after Atlantic Richfield Co. (ARCO) was granted a waiver by the U.S. Environmental Protection Agency (EPA) that allowed MTBE to be blended up to 7 vol % in U.S. unleaded gasoline. The use of other aliphatic ethers was allowed when the U.S. EPA issued its “substantially similar” definition for unleaded gasoline specifications in 1981. Under this definition, any aliphatic ether or ether mixture could be blended in unleaded gasoline as long as the total oxygen contribution from the ethers does not exceed 2.0% oxygen by weight in the gasoline. This allowed MTBE to be blended up to approximately 11 vol % in gasoline.

• Verwenden

  Methyl tert-butyl ether (MTBE) was primarily used as a gasoline additive in unleaded gasoline in the United States prior to 2005, in the manufacture of isobutene, and as a chromatographic eluent especially in high pressure liquid chromatography. It is also a pharmaceutical agent and can be injected into the gallbladder to dissolve gallstones (ATSDR, 1996). tert-Butyl methyl ether is also used in the petrochemical industry. By reversal of its formation reaction, MTBE can be cracked to isobutene and methanol on acidic catalysts at higher temperature than MTBE synthesis.

• synthetische

  tert-butyl methyl ether can be prepared by the reaction of potassium tert-butoxide and bromomethane. Methyl tert-butyl ether also can be obtained by the acid-catalyzed addition of methanol to isobutene. Suitable catalysts are solid acids such as bentonites, zeolites and – commonly used in industrial world scale MTBE-production units – macroporous acidic ion-exchange resins. The reaction is weakly exothermic with a heat of reaction of -37.7 kJ/mol.
  

• Definition

  ChEBI: Methyl tert-butyl ether is an ether having methyl and tert-butyl as the two alkyl components. It has a role as a non-polar solvent, a fuel additive and a metabolite.

• Application

  tert-Butyl methyl ether (MTBE) is a gasoline additive. MTBE undergoes oxidative degradation in the presence of propane-oxidizing bacterial strains. The kinetic studies of heat-assisted persulfate oxidation of MTBE under various parameters suggests that the reaction follows the pseudo-first-order kinetics. MTBE can be synthesized by acid catalyzed reaction between methanol and isobutene. It is an effective alternative to lead containing additives for enhancing the octane rating of gasoline. A study suggests that the addition of MTBE increases the number of active sites during polymerization of propene by stopped-flow method.
  tert-Butyl methyl ether may be used to synthesize fatty acid methyl esters (FAMEs) and glycerol tert-butyl ether via transesterification with canola oil under supercritical conditions.

• Allgemeine Beschreibung

  Methyl tert-butyl ether appears as a colorless liquid with a distinctive anesthetic-like odor. Vapors are heavier than air and narcotic. Boiling point 131°F. Flash point 18°F. Less dense than water and miscible in water. Used as a octane booster in gasoline.

• Air & Water Reaktionen

  Highly flammable. Oxidizes readily in air to form unstable peroxides that may explode spontaneously [Bretherick 1979. p.151-154, 164]. A mixture of liquid air and diethyl ether exploded spontaneously [MCA Case History 616. 1960].

• Reaktivität anzeigen

  Ethers, such as tert-Butyl methyl ether, can act as bases. They form salts with strong acids and addition complexes with Lewis acids. The complex between diethyl ether and boron trifluoride is an example. Ethers may react violently with strong oxidizing agents. In other reactions, which typically involve the breaking of the carbon-oxygen bond, ethers are relatively inert.

• Hazard

  Slightly toxic by ingestion and inhalation. Flammable when exposed to heat or flame. Upper respiratory tract irritant and kidney damage. Questionable carcinogen.

• Health Hazard

  INHALATION: May cause dizziness or suffocation. Contact may irritate or burn eyes or skin. May be harmful if swallowed.

• Industrielle Verwendung

  Methyl tert-butyl ether (MTBE) is used as an octane enhancer in gasoline. EPA regulations allow up to 2.7 wt.% oxygen in gasoline which allows 15 vol.% MTBE in gasoline. Other alkyl ethers can also be blended into gasoline up to the 2.7 wt% oxygen requirement. The stability of MTBE to oxidation and peroxide formation gives this unsymmetrical ether an advantage over other ethers in various extraction and reaction solvent applications.

• Sicherheitsprofil

  Poison by intravenous route. Slightly toxic by ingestion and inhalation. Flammable when exposed to heat or flame. When heated to decomposition it emits acrid smoke and irritating fumes. See also ETHERS.

• mögliche Exposition

  Used as an organic solvent; as an octane booster in unleaded gasolines; in making other chemicals; and in medicine to dissolve gall stones

• Erste Hilfe

  If this chemical gets into the eyes, remove any contact lenses at once and irrigate immediately for at least 15 min, occasionally lifting upper and lower lids. Seek medical attention immediately. If this chemical contacts the skin, remove contaminated clothing and wash immediately with soap and water. Seek medical attention immediately. If this chemical has been inhaled, remove from exposure, begin rescue breathing (using universal precautions, including resuscitation mask) if breathing has stopped and CPR if heart action has stopped. Transfer promptly to a medical facility. When this chemical has been swallowed, get medical attention. Give large quantities of water and induce vomiting. Do not make an unconscious person vomit.

• Carcinogenicity

  EPA has not classified methyl tert-butyl ether with respect to potential carcinogenicity. There is evidence for the carcinogenicity of MTBE in animals. MTBE causes leukemias/lymphomas in female rats, renal tubular tumors and Leydig cell tumors in male rats, and hepatocellular tumors in mice. Positive animal carcinogenicity data and some further concordance in tumor sites for formaldehyde and TBA, metabolites of MTBE, provide support for this conclusion. However, uncertainties remain about the nature and extent of risk at very low doses, and about the particular tumor sites that are most relevant to humans.

• Environmental Fate

  tert-Butyl Methyl Ether can be released during manufacturing or blending with gasoline; during the storage, distribution, and transfer of MTBE-blended gasoline; and from spills or leaks or fugitive emissions at automotive service stations (U.S. EPA, 1994a). Vapor emissions from MTBE-blended gasoline may also contribute to atmospheric levels (U.S. EPA, 1988). It is not expected to persist in the atmosphere because it undergoes destruction from reactions with hydroxyl radicals. A total atmospheric lifetime for MTBE of approximately 3 and 6.1 days has been reported in polluted urban air and in nonpolluted rural air, respectively (U.S. EPA, 1993a). Based upon its vapor pressure and Henry s law constant, MTBE is highly volatile and would be expected to evaporate rapidly from soil surfaces or water. It may be fairly persistent when introduced into subsurface soils or to groundwater since volatilization to the atmosphere is reduced or eliminated. It does not readily degrade in surface waters due to hydrolysis or other abiotic processes. It is also resistant to biodegradation (U.S. EPA, 1993a). It is usually removed from surface waters very rapidly because of its high volatility. If released as part of a gasoline mixture from leaking underground storage tanks, its relatively high water solubility combined with little tendency to sorb to soil particles encourages migration to local groundwater supplies (U.S. EPA, 1993a).

• Lager

  Color Code—Red: Flammability Hazard: Store in a flammable liquid storage area or approved cabinet away from ignition sources and corrosive and reactive materials. Prior to working with MTBE you should be trained on its 1766 Methyl-tert-butyl ether proper handling and storage. Store in tightly closed containers in a cool, well-ventilated area away from strong oxidizers, strong acids. Where possible, automatically pump liquid from drums or other storage containers to process containers. Drums must be equipped with self-closing valves, pressure vacuum bungs, and flame arresters. Use only nonsparking tools and equipment, especially when opening and closing containers of this chemical. Wherever this chemical is used, handled, manufactured, or stored, use explosion-proof electrical equipment and fittings.

• Versand/Shipping

  UN2398 Methyl tert-butyl ether, Hazard Class: 3; Labels: 3-Flammable liquid.

• läuterung methode

  Purify as for n-butyl methyl ether. [Beilstein 1 IV 1615.]

• Inkompatibilitäten

  May form explosive mixture with air. May be able to form unstable peroxides. Much less likely to form peroxides than other ethers. Incompatible with strong acids. Incompatible with oxidizers (chlorates, nitrates, peroxides, permanganates, perchlorates, chlorine, bromine, fluorine, etc.); contact may cause fires or explosions. Keep away from alkaline materials, strong bases, strong acids, oxoacids, epoxides. May accumulate static electrical charges, and cause ignition of its vapors.

• Waste disposal

  Dissolve or mix the material with a combustible solvent and burn in a chemical incinerator equipped with an afterburner and scrubber. All federal, state, and local environmental regulations must be observed.

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(tert-Butyl)methylether Anbieter Lieferant Produzent Hersteller Vertrieb Händler.

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