Chloro(1,5-cyclooctadiene)rhodium(I) dimer

1. Catalyst for coupling 1,3-dienes with activate methylene compounds.
2. Rhodium source for various asymmetric hydrogenation systems and asymmetric hydrosilylation of ketones.
3. Rhodium source for asymmetric reductive aldol reaction.
4. Cis-hydroboration of terminal alkynes.
5. Rhodium source for [5 + 2] additions.
6. Highly enantioselective for [2+2+2] carbocyclization reactions.
7. Enantioselective hydroboration of cyclopropenes.

orange crystals

It is a widely used precursor to homogeneous catalysts. This is a chiral catalyst capable of asymmetrically hydrogenating certain prochiral alkenes. Chloro(1,5-cyclooctadiene)rhodium(I) dimer is also used in the synthesis of other metal ligands for use in catalysis.

Chloro(1,5-cyclooctadiene)rhodium(I) dimer ([Rh(COD)Cl]₂) can be:

• Employed for the synthesis of rhodium complex of heterocyclic carbenes (NHCs).
• Modified and coated on the surface of ferrite magnetic nanoparticles for catalyzing hydroformylation reaction of olefins.
• Used for the synthesis of triple-layer structure to be used as a ring-opening polymerization catalyst.
• As an effective catalyst for dehydrogenation of amine-borane adducts (hydrogen storage materials) such as ammonia-borane.

This product has been enhanced for catalytic efficiency.

Not classified