Reaction
- Catalyst for coupling 1,3-dienes with activate methylene compounds.
- Rhodium source for various asymmetric hydrogenation systems and asymmetric hydrosilylation of ketones.
- Rhodium source for asymmetric reductive aldol reaction.
- Cis-hydroboration of terminal alkynes.
- Rhodium source for [5 + 2] additions.
- Highly enantioselective for [2+2+2] carbocyclization reactions.
- Enantioselective hydroboration of cyclopropenes.
Chemical Properties
orange crystals
Uses
It is a widely used precursor to homogeneous catalysts. This is a chiral catalyst capable of asymmetrically hydrogenating certain prochiral alkenes. Chloro(1,5-cyclooctadiene)rhodium(I) dimer is also used in the synthesis of other metal ligands for use in catalysis.
Uses
Chloro(1,5-cyclooctadiene)rhodium(I) dimer ([Rh(COD)Cl]
2) can be:
- Employed for the synthesis of rhodium complex of heterocyclic carbenes (NHCs).
- Modified and coated on the surface of ferrite magnetic nanoparticles for catalyzing hydroformylation reaction of olefins.
- Used for the synthesis of triple-layer structure to be used as a ring-opening polymerization catalyst.
- As an effective catalyst for dehydrogenation of amine-borane adducts (hydrogen storage materials) such as ammonia-borane.
General Description
This product has been enhanced for catalytic efficiency.
Flammability and Explosibility
Not classified