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Ruthenium(III) chloride

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Ruthenium(III) chloride Basic information
Ruthenium(III) chloride Chemical Properties
  • Melting point:>300°C
  • Density 3.11 g/cm3
  • storage temp. Store at +5°C to +30°C.
  • form Powder
  • color Dark brown to black
  • PH<2 (H2O, 20℃)Aqueous solution
  • Water Solubility soluble
  • Sensitive Hygroscopic
  • Merck 14,8302
  • Stability:hygroscopic
  • CAS DataBase Reference14898-67-0(CAS DataBase Reference)
Safety Information
  • Hazard Codes C
  • Risk Statements 34-52/53-22
  • Safety Statements 26-36/37/39-45-61
  • RIDADR UN 3260 8/PG 2
  • WGK Germany 2
  • RTECS VM2650000
  • TSCA Yes
  • HS Code 2843 90 90
  • HazardClass 8
  • PackingGroup III
MSDS
Ruthenium(III) chloride Usage And Synthesis
  • Chemical Propertiesdark brown to black powder
  • UsesCatalyzes the synthesis of 2-ethyl-3-methylquinolines from primary aromatic amines and triallylamine.1
  • Purification MethodsDissolve the salt in H2O, filter and concentrate to crystallisation in the absence of air to avoid oxidation. Evaporate the solution in a stream of HCl gas while being heated just below its boiling point until a syrup is formed and finally to dryness at 80-100o and dried in a vacuum over H2SO4. When heated at 700o in the presence of Cl2 the insoluble -form is obtained [Grube in Handbook of Preparative Inorganic Chemistry (Ed. Brauer) Academic Press Vol II p 1598 1965, Carlsen et al. J Org Chem 46 3936 1981].
Ruthenium(III) chloride Preparation Products And Raw materials
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