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2-Fluorotoluene

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2-Fluorotoluene Basic information
2-Fluorotoluene Chemical Properties
  • Melting point:-62 °C (lit.)
  • Boiling point:113-114 °C (lit.)
  • Density 1.001 g/mL at 25 °C (lit.)
  • vapor density 3.8 (vs air)
  • vapor pressure 21 mm Hg ( 20 °C)
  • refractive index n20/D 1.473(lit.)
  • Flash point:55 °F
  • storage temp. Store below +30°C.
  • form Liquid
  • Specific Gravity1.001
  • color Clear colorless to slightly yellow
  • explosive limit1.3%(V)
  • Water Solubility immiscible
  • Merck 14,4180
  • BRN 1853362
  • CAS DataBase Reference95-52-3(CAS DataBase Reference)
  • NIST Chemistry ReferenceBenzene, 1-fluoro-2-methyl-(95-52-3)
  • EPA Substance Registry Systemo-Fluorotoluene (95-52-3)
Safety Information
  • Hazard Codes F,Xi
  • Risk Statements 11-36/37/38
  • Safety Statements 16-26-33-36-37/39
  • RIDADR UN 2388 3/PG 2
  • WGK Germany 3
  • RTECS XT2579000
  • Hazard Note Flammable/Irritant
  • TSCA Yes
  • HazardClass 3
  • PackingGroup II
  • HS Code 29036990
  • ToxicityLD50 orally in Rabbit: > 5000 mg/kg LD50 dermal Rabbit > 2000 mg/kg
MSDS
2-Fluorotoluene Usage And Synthesis
  • Chemical Propertiesclear colorless to slightly yellow liquid
  • UsesIt is employed in organic synthesis.
  • General DescriptionA colorless liquid with an aromatic odor. May sink or float on water.
  • Air & Water ReactionsHighly flammable. Insoluble in water.
  • Reactivity Profile2-Fluorotoluene is of generally low reactivity. Reacts with strong oxidizing agents and strong reducing agents. Also may be incompatible with many amines, nitrides, azo/diazo compounds, alkali metals, and epoxides [USCG, 1999].
  • Health HazardInhalation of vapor may cause respiratory irritation. Prolonged and repeated vapor exposures may produce systemic toxic effects.
  • Purification MethodsDry o-fluorotoluene with P2O5 or CaSO4 and fractionally distil it through a silvered vacuum-jacketed glass column with 1/8th-in glass helices. A high reflux ratio is necessary because of the closeness of the boiling points of the o-, m-and p-isomers [Potter & Saylor J Am Chem Soc 37 90 1951]. [Beilstein 5 H 290, 5 III 676, 5 IV 799.]
2-Fluorotoluene Preparation Products And Raw materials
2-Fluorotoluene(95-52-3)Related Product Information
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