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ChemicalBook >  Product Catalog >  Chemical Reagents >  Organic reagents >  Phosphine ligand >  (11AR)-(+)-10,11,12,13-TETRAHYDRODIINDENO[7,1-DE:1',7'-FG][1,3,2]DIOXAPHOSPHOCIN-5-PHENOXY

(11AR)-(+)-10,11,12,13-TETRAHYDRODIINDENO[7,1-DE:1',7'-FG][1,3,2]DIOXAPHOSPHOCIN-5-PHENOXY

Basic information Reaction Safety Related Supplier
(11AR)-(+)-10,11,12,13-TETRAHYDRODIINDENO[7,1-DE:1',7'-FG][1,3,2]DIOXAPHOSPHOCIN-5-PHENOXY Basic information
(11AR)-(+)-10,11,12,13-TETRAHYDRODIINDENO[7,1-DE:1',7'-FG][1,3,2]DIOXAPHOSPHOCIN-5-PHENOXY Chemical Properties
  • Melting point:104-106°C
  • alpha +216° (c 0.5, CH2Cl2)
  • form solid
  • color white
  • Sensitive moisture sensitive
Safety Information
  • Hazard Codes Xn
  • Risk Statements 22
(11AR)-(+)-10,11,12,13-TETRAHYDRODIINDENO[7,1-DE:1',7'-FG][1,3,2]DIOXAPHOSPHOCIN-5-PHENOXY Usage And Synthesis
  • Reaction
    1. Chiral ligands for rhodium-catalyzed arylation of aldehydes with arylboronic acids.
    2. Chiral ligands for rhodium-catalyzed arylation of imines with arylboronic acids.
    3. Chiral ligands for rhodium-catalyzed arylation of α-ketoesters with arylboronic acids.
    4. Chiral ligands for palladium-catalyzed asymmetric umpolung allylation of aldehydes.
    5. Chiral ligands for rhodium-catalyzed asymmetric hydrogenation of (Z)-β-arylenamides.

(11AR)-(+)-10,11,12,13-TETRAHYDRODIINDENO[7,1-DE:1',7'-FG][1,3,2]DIOXAPHOSPHOCIN-5-PHENOXY Preparation Products And Raw materials
(11AR)-(+)-10,11,12,13-TETRAHYDRODIINDENO[7,1-DE:1',7'-FG][1,3,2]DIOXAPHOSPHOCIN-5-PHENOXY(656233-53-3)Related Product Information
(11AR)-(+)-10,11,12,13-TETRAHYDRODIINDENO[7,1-DE:1',7'-FG][1,3,2]DIOXAPHOSPHOCIN-5-PHENOXYSupplierMore
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