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trans-1,3-Dichloropropene Structure

trans-1,3-Dichloropropene

Chemical Properties

Boiling point 97-112 °C(lit.)
Density  1.198 g/mL at 25 °C(lit.)
vapor pressure  79.1 at 50 °C, 523.5 at 100 °C (Wilding et al., 2002)
refractive index  n20/D 1.472(lit.)
Flash point 78 °F
storage temp.  0-6°C
solubility  Miscible with acetone, benzene, carbon tetrachloride, heptane, methanol (Worthing and Hance, 1991), methylene chloride, chloroform, trichloroethylene, and 1,1,2,2-tetrachloroethane.
color  Colorless to Light yellow to Light orange
Specific Gravity 1.217
Water Solubility  2.8g/L(20 ºC)
Merck  14,3075
Henry's Law Constant 1.3 x 10-3 atm?m3/mol (Pankow and Rosen, 1988) 0.793 x 10-3 atm?m3/mol at 20 °C, 1.87 at 40 °C (static headspace-GC, Kim et al., 2003)
Exposure limits ACGIH TLV: TWA 1 ppm for cis and trans isomers (adopted).
Stability Stable. Flammable. Incompatible with strong oxidizing agents, aluminium, aluminium alloys, some metal salts and halogens. May be light sensitive.
CAS DataBase Reference 10061-02-6(CAS DataBase Reference)
NIST Chemistry Reference 1-Propene, 1,3-dichloro-, (E)-(10061-02-6)
EPA Substance Registry System trans-1,3-Dichloropropene (10061-02-6)

Safety Information

Hazard Codes  T,N,Xn,F
Risk Statements  10-20/21-25-36/37/38-43-50/53-40-22-39/23/24/25-23/24/25-11-52/53-65-24/25-20
Safety Statements  36/37-45-60-61-16-7
RIDADR  UN 1992 3/PG 3
WGK Germany  3
RTECS  UC8310000
HazardClass  3.2
PackingGroup  III
HS Code  29032990
Hazardous Substances Data 10061-02-6(Hazardous Substances Data)
Toxicity LC50 (96-hour) for bluegill sunfish 7.1 mg/L and rainbow trout 7.1 mg/L (Worthing and Hance, 1991); acute oral LD50 of the isomeric mixture for male and female rats 713 and 470 mg/kg, respectively (Verschueren, 1983).

MSDS

Usage And Synthesis

Preparation Products And Raw materials

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