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3,4,7,8-Tetramethyl-1,10-phenanthroline

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3,4,7,8-Tetramethyl-1,10-phenanthroline Basic information
3,4,7,8-Tetramethyl-1,10-phenanthroline Chemical Properties
  • Melting point:277-280 °C(lit.)
  • Boiling point:368.78°C (rough estimate)
  • Density 1.0937 (rough estimate)
  • refractive index 1.5635 (estimate)
  • storage temp. Sealed in dry,Room Temperature
  • solubility Soluble in 1,4-dioxane, acetone, dichloromethane, N,N-dimethylformamide, N,N-dimethylacetamide, methanol and hot toluene.
  • pka6.37±0.10(Predicted)
  • form Fine Crystalline Powder
  • color Light beige
  • Water Solubility 1.512mg/L(25.04 ºC)
  • BRN 171279
  • InChIKeyNPAXPTHCUCUHPT-UHFFFAOYSA-N
  • CAS DataBase Reference1660-93-1(CAS DataBase Reference)
  • EPA Substance Registry System1,10-Phenanthroline, 3,4,7,8-tetramethyl- (1660-93-1)
Safety Information
MSDS
3,4,7,8-Tetramethyl-1,10-phenanthroline Usage And Synthesis
  • Description

    3,4,7,8-Tetramethyl-1,10-phenanthroline is used as a metal-chelating agent. For instance, it is used in the synthesis of heteroleptic cationic Ir(III) complex: 3,4,7,8-tetramethyl-1,10-phenanthroline-bis[2-(2’,4’-difluorophenyl)pyridine]iridium(III) hexafluorophosphate. It is used as a ligand to form dinuclear Cu(II) hypocrelin B complexes. It also forms tetraaqua(3,4,7,8-tetramethyl-1,10-phenanthroline-kappa2N,N′)zinc(II) thiosulfate complex with zinc.

  • Reference

    Y. Sun, YJ. Hou, QX. Zhou, WH. Lei, JR. Chen, XS. Wang, BW. Zhang, Dinuclear Cu(II) hypocrellin B complexes with enhanced photonuclease activity, Inorganic Chemistry, 2010, vol. 49, pp. 10108-10116

  • Chemical Propertieslight beige fine crystalline powder
  • UsesMetal-chelating agent
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