Dichlormethan

Gefahreninformationscode (GHS)

• Bildanzeige (GHS)

  

• Alarmwort

  Warnung

• Gefahrenhinweise

  H315：Verursacht Hautreizungen.

  H319：Verursacht schwere Augenreizung.

  H336：Kann Schläfrigkeit und Benommenheit verursachen.

  H351：Kann vermutlich Krebs verursachen.

• Sicherheit

  P201：Vor Gebrauch besondere Anweisungen einholen.

  P202：Vor Gebrauch alle Sicherheitshinweise lesen und verstehen.

  P261：Einatmen von Staub vermeiden.

  P302+P352：BEI BERÜHRUNG MIT DER HAUT: Mit viel Wasser/... (Hersteller kann, falls zweckmäßig, ein Reinigungsmittel angeben oder, wenn Wasser eindeutig ungeeignet ist, ein alternatives Mittel empfehlen) waschen.

  P305+P351+P338：BEI KONTAKT MIT DEN AUGEN: Einige Minuten lang behutsam mit Wasser spülen. Eventuell vorhandene Kontaktlinsen nach Möglichkeit entfernen. Weiter spülen.

  P308+P313：BEI Exposition oder falls betroffen: Ärztlichen Rat einholen/ärztliche Hilfe hinzuziehen.

Dichloromethane Chemische Eigenschaften,Einsatz,Produktion Methoden

• ERSCHEINUNGSBILD

  FARBLOSE FLüSSIGKEIT MIT CHARAKTERISTISCHEM GERUCH.

• PHYSIKALISCHE GEFAHREN

  Die Dämpfe sind schwerer als Luft. Fließen, Schütten o.ä. kann zu elektrostatischer Aufladung führen.

• CHEMISCHE GEFAHREN

  Bei Kontakt mit heißen Gegenständen oder Flammen Zersetzung unter Bildung giftiger und ätzender Rauche. Reagiert heftig mit Metallen wie Aluminium- und Magnesiumpulver, starken Basenund starken Oxidationsmitteln. Feuer- und Explosionsgefahr. Greift einige Kunststoff-, Gummi- und Beschichtungsarten an.

• ARBEITSPLATZGRENZWERTE

  TLV: 50 ppm (als TWA) Krebskategorie A3 (bestätigte krebserzeugende Wirkung beim Tier mit unbekannter Bedeutung für den Menschen); BEI vorhanden (ACGIH 2005).
  MAK: Krebserzeugend Kategorie 3A; (DFG 2005).
  

• AUFNAHMEWEGE

  Aufnahme in den Körper durch Inhalation und durch Verschlucken.

• INHALATIONSGEFAHREN

  Beim Verdampfen bei 20 °C kann sehr schnell eine gesundheitsschädliche Kontamination der Luft eintreten.

• WIRKUNGEN BEI KURZZEITEXPOSITION

  WIRKUNGEN BEI KURZZEITEXPOSITION:
  Die Substanz reizt die Augen, die Haut und die Atmungsorgane. Exposition kann Bewusstseinstrübung verursachen. Exposition kann zur Bildung von Carboxyhämoglobin führen.

• WIRKUNGEN NACH WIEDERHOLTER ODER LANGZEITEXPOSITION

  Wiederholter oder andauernder Hautkontakt kann Dermatitis hervorrufen. Möglich sind Auswirkungen auf Zentralnervensystemund Leber. Möglicherweise krebserzeugend für den Menschen.

• LECKAGE

  Persönliche Schutzausrüstung: Atemschutzfilter für organische Gase und Dämpfe. NICHT in die Umwelt gelangen lassen. Belüftung. Ausgelaufene Flüssigkeit möglichst in abdichtbaren Behältern sammeln. Reste mit Sand oder inertem Absorptionsmittel aufnehmen und an einen sicheren Ort bringen.

• R-Sätze Betriebsanweisung:

  R40:Verdacht auf krebserzeugende Wirkung.
  R39/23/24/25:Giftig: ernste Gefahr irreversiblen Schadens durch Einatmen, Berührung mit der Haut und durch Verschlucken.
  R23/24/25:Giftig beim Einatmen, Verschlucken und Berührung mit der Haut.
  R11:Leichtentzündlich.

• S-Sätze Betriebsanweisung:

  S23:Gas/Rauch/Dampf/Aerosol nicht einatmen(geeignete Bezeichnung(en) vom Hersteller anzugeben).
  S24/25:Berührung mit den Augen und der Haut vermeiden.
  S36/37:Bei der Arbeit geeignete Schutzhandschuhe und Schutzkleidung tragen.
  S45:Bei Unfall oder Unwohlsein sofort Arzt zuziehen (wenn möglich, dieses Etikett vorzeigen).
  S16:Von Zündquellen fernhalten - Nicht rauchen.
  S7:Behälter dicht geschlossen halten.

• Aussehen Eigenschaften

  CH2Cl2.
  Farblose, süßlich riechende Flüssigkeit

• Gefahren für Mensch und Umwelt

  Gefährliche Reaktion z.B. mit Alkali- und Erdalkalimetallen sowie mit starken Basen.
  Verschlucken verursacht Übelkeit und Erbrechen. Nach Resorption großer Mengen treten zentralnervöse Störungen, Störung der Atem- und Herztätigkeit sowie Leber- und Nierenschäden auf.
  Kann möglicherweise Krebs erzeugen.
  Wassergefährdender Stoff (WGK 2).

• Schutzmaßnahmen und Verhaltensregeln

  Im Abzug arbeiten! Dampf nicht einatmen. Berührung mit den Augen und der Haut vermeiden.
  Latex- und Neoprenhandschuhe sind nicht beständig! Höchstens als sehr kurzzeitigen Spritzschutz verwenden.

• Verhalten im Gefahrfall

  Kleine Mengen im Abzug verdampfen lassen. Verschüttete größere Mengen mit Absorptionsmaterial (z. B. Rench Rapid) aufnehmen. Der Entsorgung zuführen.
  Brände mit CO₂-Löscher bekämpfen. Atemschutz: Kombinationsfilter ABEK.

• Erste Hilfe

  Nach Hautkontakt: Mit reichlich Wasser und Seife abwaschen.
  Nach Augenkontakt: Mit viel Wasser mindestens 15 Minuten bei geöffnetem Lidspalt spülen. Augenarzt!
  Nach Einatmen: Frischluft. Arzt.
  Nach Verschlucken: Wasser trinken; kein Erbrechen. Arzt!
  Nach Kleidungskontakt: Kontaminierte Kleidung ausziehen.
  Ersthelfer: siehe gesonderten Anschlag

• Sachgerechte Entsorgung

  Als Sondermüll (halogenhaltige Lösungsmittel) entsorgen.

• Beschreibung

  Dichloromethane is a colorless liquid with an ethereal, but penetrating odor. Its miscibility in alcohol and ether and slight solubility in water has made it an ideal solvent and otherwise extremely versatile chemical. It has been used industrially (solvent and paint remover), as a drug (inhalation anesthetic) and as an agricultural chemical (growth regulator and fertilizer). It is narcotic in high concentrations and carcinogenic. Inhalation exposure to this substance irritates the nose and throat and affects the central nervous system.

• Chemische Eigenschaften

  Dichloromethane is a colorless liquid with a mild, sweet odor. It does not occur naturally in the environment. It is made from methane gas or wood alcohol. Industrial uses of dichloromethane are extensive, as a solvent in paint strippers, as a propellant in aerosols, and as a process solvent in the manufacturing of drugs. dichloromethane is also used as a metal cleaning and fi nishing solvent, and it is approved as an extraction solvent for spices and hops. Exposure to dichloromethane occurs in workplaces by breathing fumes from paint strippers that contain it (check the label), breathing fumes from aerosol cans that use it (check the label), and breathing contaminated air near waste sites.

• Physikalische Eigenschaften

  Clear, colorless liquid with a sweet, penetrating, ethereal odor. Leonardos et al. (1969) determined an odor threshold concentration of 214.0 ppm_v. The average least detectable odor threshold concentrations of technical grade methylene chloride in water at 60 °C and in air at 40 °C were 5.6 and 24 mg/L, respectively (Alexander et al., 1982).

• Verwenden

  Methylene chloride is primarily used as a paint remover solvent. It is also used as an aerosol propellant, processing solvent in the production of steroids, antibiotics, vitamins, and tablet coatings. Additionally, it serves as a degreasing agent, particularly in electronics manufacturing. Methylene chloride is utilized as a urethane foamblowing agent as well. It finds application in metal cleaning, production of polycarbonate resins and triacetate fibers, film processing, ink formulations, and as an extraction solvent for spice oleoresins, caffeine, and hops. Due to its high volatility, it is commonly employed as a solvent in various extraction processes. Methylene chloride possesses strong solvent power for cellulose esters, fats, oils, resins, and rubber. It is more soluble in water compared to other chlorinated solvents. In the past, it was approved for use as an insecticide for commodity fumigation of strawberries, citrus fruits, and grains.

• Verwenden

  Dichloromethane, also called methylene chloride, is widely used as a solvent, as a degreasing and cleaning reagent, in paint removers, and in extractions oforganic compounds from water for analyses.

• Definition

  ChEBI: Dichloromethane is a member of the class of chloromethanes that is methane in which two of the hydrogens have been replaced by chlorine. A dense, non-flammible colourless liquid at room temperature (b.p. 40℃, d = 1.33) which is immiscible with water, it is widely used as a solvent, a paint stripper, and for the removal of caffeine from coffee and tea. It has a role as a polar aprotic solvent, a carcinogenic agent and a refrigerant. It is a member of chloromethanes and a volatile organic compound.

• Vorbereitung Methode

  Dichloromethane was first prepared by Regnault in 1840 by the chlorination of methyl chloride in sunlight. It became an industrial chemical of importance during the Second World War. Two commercial processes are currently used for the production of dichloromethane—hydrochlorination of methanol and direct chlorination of methane (Rossberg et al., 1986; Holbrook, 1993). The predominant method of manufacturing dichloromethane uses as a first step the reaction of hydrogen chloride and methanol to give methyl chloride. Excess methyl chloride is then mixed with chlorine and reacts to give dichloromethane, with chloroform and carbon tetrachloride as co-products. This reaction is usually carried out in the gas phase thermally but can also be performed catalytically or photolytically. At low temperature and high pressure, the liquid-phase process is capable of giving high selectivity for dichloromethane (Rossberg et al., 1986; Holbrook, 1993).

• Reaktionen

  Methylene chloride reacts violently in the presence of alkali or alkaline earth metals and will hydrolyze to formaldehyde in the presence of an aqueous base. Alkylation reactions occur at both functions, thus di-substitutions result.

• Allgemeine Beschreibung

  Dichloromethane has been tested as a solvent medium for the dipyridine-chromium(VI) oxide. Solubility was reported to be 12.5g/100ml. Role of quantity of TiO₂ loading on activated carbon support employed in the photodecomposition of dichloromethane has been investigated.

• Air & Water Reaktionen

  Methylene chloride is a colourless liquid with a mild, sweet odour. Somewhat water soluble. Subject to slow hydrolysis which is accelerated by light.

• Reaktivität anzeigen

  Dichloromethane reacts vigorously with active metals such as lithium, sodium and potassium, and with strong bases such as potassium tert-butoxide. Dichloromethane is incompatible with strong oxidizers, strong caustics and chemically active metals such as aluminum or magnesium powders. The liquid will attack some forms of plastic, rubber and coatings. Dichloromethane reacts with sodium-potassium alloy, (potassium hydrogen + N-methyl-N-nitrosurea), nitrogen tetraoxide and liquid oxygen. Dichloromethane also reacts with titanium. On contact with water Dichloromethane corrodes iron, some stainless steels, copper and nickel. Dichloromethane is incompatible with alkali metals. Dichloromethane is incompatible with amines, zinc and alloys of aluminum, magnesium and zinc. Dichloromethane is liable to explode when mixed with dinitrogen pentaoxide or nitric acid. Mixtures of Dichloromethane in air with methanol vapor are flammable.

• Hazard

  Toxic. A narcotic. Central nervous systemimpairment and carboxyhemoglobinemia. Possiblecarcinogen.

• Health Hazard

  Dichloromethane is classified as only slightly toxic by the oral and inhalation routes. Exposure to high concentrations of dichloromethane vapor (>500 ppm for 8 h) can lead to lightheadedness, fatigue, weakness, and nausea. Contact of the compound with the eyes causes painful irritation and can lead to conjunctivitis and corneal injury if not promptly removed by washing. Dichloromethane is a mild skin irritant, and upon prolonged contact (e.g., under the cover of clothing or shoes) can cause burns after 30 to 60 min exposure. Dichloromethane is not teratogenic at levels up to 4500 ppm or embryotoxic in rats and mice at levels up to 1250 ppm.

• Brandgefahr

  Special Hazards of Combustion Products: Dissociation products generated in a fire may be irritating or toxic.

• Flammability and Explosibility

  Noncombustible. Dichloromethane vapor concentrated in a confined or poorly ventilated area can be ignited with a high-energy spark, flame, or high-intensity heat source.

• Chemische Reaktivität

  Reactivity with Water No reaction; Reactivity with Common Materials: No reaction; Stability During Transport: Stable; Neutralizing Agents for Acids and Caustics: Not pertinent; Polymerization: Not pertinent; Inhibitor of Polymerization: Not pertinent.

• Sicherheitsprofil

  Confirmed carcinogen with experimental carcinogenic and tumorigenic data. Poison by intravenous route. Moderately toxic by ingestion, subcutaneous, and intraperitoneal routes. Mildly toxic by inhalation. Human systemic effects by ingestion and inhalation: paresthesia, somnolence, altered sleep time, convulsions, euphoria, and change in cardlac rate. An experimental teratogen. Experimental reproductive effects. An eye and severe skin irritant. Human mutation data reported. It is flammable in the range of 12-19% in air but ignition is difficult. It will not form explosive mixtures with air at ordinary temperatures. Mixtures in air with methanol vapor are flammable. It will form explosive mixtures with an atmosphere having a high oxygen content, in liquid O2, N2O4, K, Na, NaK. Explosive in the form of vapor when exposed to heat or flame. Reacts violently with Li, NaK, potassiumtert- butoxide, (KOH + N-methyl-Nnitrosourea). It can be decomposed by contact with hot surfaces and open flame, and then yield toxic fumes that are irritating and give warning of their presence. When heated to decomposition it emits highly toxic fumes of phosgene and Cl-.

• mögliche Exposition

  Methylene chloride is used mainly as a low-temperature extractant of substances which are adversely affected by high temperature. It can be used as a solvent for oil, fats, waxes, bitumen, cellulose acetate; and esters. It is also used as a paint remover; as a degreaser; and in aerosol propellants

• Erste Hilfe

  If this chemical gets into the eyes, remove anycontact Tenses at once and irrigate immediately for at least5 min, occasionally lifing upper and lower lids. Seek medi-cal attention immediately. If this chemical contacts the skin,remove contaminated clothing and wash immediately withsoap and water. Seek medical attention immediately. If thisChemical has been inhaled, remove from exposure, begin res-cue breathing (using universal precautions, including resusci-ation mask) if breathing has stopped and CPR if heart actionhas stopped. Transfer promptly to a medical facility. Whenthis chemical has been swallowed, get medical attention.Give large quantities of water and induce vomiting. Do notmake an unconscious person vomit. Medical observation isrecommended for 24- 48 h after breathing overexposure, aspulmonary edema may be delayed. As first aid for pulmonaryedema, a doctor or authorized paramedic may consideradministering a corticosteroid spray.

• Carcinogenicity

  Dichloromethane is reasonably anticipated to be a human carcinogen based on sufficient evidence of carcinogenicity from studies in experimental animals.

• Environmental Fate

  Biological. Complete microbial degradation to carbon dioxide was reported under anaerobic conditions by mixed or pure cultures. Under enzymatic conditions formaldehyde was the only product reported (Vogel et al., 1987). In a static-culture-flask screening test, methylene chloride (5 and 10 mg/L) was statically incubated in the dark at 25 °C with yeast extract and settled domestic wastewater inoculum. After 7 d, 100% biodegradation with rapid adaptation was observed (Tabak et al., 1981).
  Under aerobic conditions with sewage seed or activated sludge, complete biodegradation was observed between 6 h to 1 wk (Rittman and McCarty, 1980).
  Soil. Methylene chloride undergoes biodegradation in soil under aerobic and anaerobic conditions. Under aerobic conditions, the following half-lives were reported: 54.8 d in sand (500 ppb); 1.3, 9.4, and 191.4 d at concentrations of 160, 500, and 5,000 ppb, respectively, in sandy loam soil; 12.7 d (500 ppb) in sandy clay loam soil; 7.2 d (500 ppb) following a 50-d lag time. Under anaerobic conditions, the half-life of methylene chloride in clay following a 70-d lag time is 21.5 d (Davis and Madsen, 1991). The estimated volatilization half-life of methylene chloride in soil is 100 d (Jury et al., 1990).
  Photolytic. Reported photooxidation products via OH radicals include carbon dioxide, carbon monoxide, formyl chloride, and phosgene (Spence et al., 1976). In the presence of water, phosgene hydrolyzes to HCl and carbon dioxide, whereas formyl chloride hydrolyzes to hydrogen chloride and carbon monoxide (Morrison and Boyd, 1971).
  Chemical/Physical. Under laboratory conditions, methylene chloride hydrolyzed with subsequent oxidation and reduction to produce methyl chloride, methanol, formic acid, and formaldehyde (Smith and Dragun, 1984). The experimental half-life for hydrolysis in water at 25 °C is approximately 18 months (Dilling et al., 1975).

• Lager

  Color Code—Blue: Health Hazard/Poison: Storein a secure poison location. Prior to working with thischemical you should be trained on its proper handling andstorage. Before entering confined space where this chemicalmay be present, check to make sure that an explosive concentration does not exist. Methylene chloride must be storedto avoid contact with strong oxidizers (such as perchlorates,peroxides, chlorates, nitrates, or permanganates), strongcaustics, and chemically active metals (such as aluminum,magnesium powder, sodium, potassium, or lithium) becauseviolent reactions occur. Store in tightly closed containers ina cool, well-ventilated area away from heat and moisture. Aregulated, marked area should be established where thischemical is handled, used, or stored in compliance withOSHA Standard 1910.1045.

• Versand/Shipping

  UN1593Dichloromethane, Hazard Class: 6.1; Labels: 6.1-Poisonous materials

• läuterung methode

  Shake it with portions of conc H2SO4 until the acid layer remains colourless, then wash with water, aqueous 5% Na2CO3, NaHCO3 or NaOH, then water again. Pre-dry with CaCl2, and distil it from CaSO4, CaH2 or P2O5. Store it away from bright light in a brown bottle with Linde type 4A molecular sieves, in an atmosphere of dry N2. Other purification steps include washing with aqueous Na2S2O3, passage through a column of silica gel, and removal of carbonyl-containing impurities as described under Chloroform. It has also been purified by treatment with basic alumina, distillation, and stored over molecular sieves under nitrogen [Puchot et al. J Am Chem Soc 108 2353 1986]. Dichloromethane from Japanese sources contained MeOH as stabiliser which is not removed by distillation. It can, however, be removed by standing over activated 3A Molecular Sieves (note that 4A Sieves cause the development of pressure in bottles), passed through activated Al2O3 and distilled [Gao et al. J Am Chem Soc 109 5771 1987]. It has been fractionated through a platinum spinning band column, degassed, and distilled onto degassed molecular sieves Linde 4A (heated under high vacuum at over 450o until the pressure readings reached the low values of 10-6 mm, ~1-2hours ). Stabilise it with 0.02% of 2,6-di-tert-butyl-p-cresol [Mohammad & Kosower J Am Chem Soc 93 2713 1971]. [Beilstein 1 IV 35.] Rapid purification: Reflux over CaH2 (5% w/v) and distil it. Store it over 4A molecular sieves.

• Toxicity evaluation

  Dichloromethane is usually released to the atmosphere. It can react withhydroxyl radicals with a half-life of about a fewmonths. Dichloromethane released to water can be evaporated to atmosphere with a half-life of 35.6 h at moderate mixing conditions. Some of dichloromethane in water can be biodegraded completely within several hours and a few days. Small part of dichloromethane released to water can be degraded by hydrolysis. However, hydrolysis is not an important process under natural condition and may take 18 months or more to degrade completely. Dichloromethane released to soil will go to the soil surface and then the atmosphere. Some part of dichloromethane in soil will leak to the groundwater and water cycle.
  DCM’s production and use as solvent, chemical intermediate, grain fumigant, paint stripper and remover,metal degreaser, and refrigerant may result in its release to the environment through various waste streams. Vapor-phase DCM is expected to be degraded in the atmosphere by reaction with photochemically produced hydroxyl radicals; the half-life for this reaction in air is estimated to be approximately 119 days (in the absence of direct photolysis). If released to soil,DCMis expected to have very high mobility based on an estimated Koc of 24. Volatilization from moist soil surfaces is expected to be an important fate process based on an estimated Henry’s law constant of 3.25×10^-3 atm-m³ mol^-1. DCM may volatilize from dry soil surfaces based on its vapor pressure. Biodegradation in soil may occur. DCM, when released into water, is not expected to adsorb to suspended solids and sediment in water based on the estimated Koc. Biodegradation is possible in natural waters but will probably be very slow compared with evaporation.

• Inkompatibilitäten

  Incompatible with strong oxidizers, caustics; chemically active metals, such as aluminum, magnesium powders; potassium, lithium, and sodium; concentrated nitric acid causing fire and explosion hazard. Contact with hot surfaces or flames causes decomposition producing fumes of hydrogen chloride and phosgene gas. Attacks some forms of plastics, rubber and coatings. Attacks metals in the presence of moisture.

• Waste disposal

  Consult with environmental regulatory agencies for guidance on acceptable disposal practices. Generators of waste containing this contaminant (≥100 kg/mo) must conform to EPA regulations governing storage, transportation, treatment, and waste disposal. Incineration, preferably after mixing with another combustible fuel; care must be exercised to assure complete combustion to prevent the formation of phosgene; an acid scrubber is necessary to remove the halo acids produced.

• Verordnung (Regulations)

  Several jurisdictions have acted to reduce the use and release of various volatile organic compounds, including dichloromethane. The California Air Resources Board was one of the first jurisdictions to regulate dichloromethane; in 1995, it limited the levels of total volatile organic compounds (VOCs) contained in aerosol coating products. Subsequent regulations prevented manufacture, sale, supply, or application of any aerosol coating product containing dichloromethane (Air Resources Board, 2001). California has also prohibited the manufacture, sale, or use of automotive cleaning and degreasing products containing dichloromethane.
  In Japan, the environmental quality standards for dichloromethane state that outdoor air levels shall not exceed 0.15 mg/m3 (Ministry of the Environment Government of Japan, 2014).
  A guideline value of 3 mg/m3 for 24-hour exposure is recommended by WHO. In addition, the weekly average concentration should not exceed one seventh (0.45 mg/m3) of this 24-hour guideline (WHO, 2000).
  In the European Union, the VOC Solvent Emissions Directive (Directive 1999/13/EC) was implemented for new and existing installations on 31 October 2007 (European Commission,1999). The Directive aims to reduce industrial emissions of VOCs from solvent-using activities, such as printing, surface cleaning, vehicle coating, dry cleaning, and manufacture of footwear and pharmaceutical products. Installations conducting such activities are required to comply either with emission limit values or with a reduction scheme. Reduction schemes allow the operator to reduce emissions by alternative means, such as by substituting products with a lower solvent content or changing to solvent-free production processes. The Solvents Directive was implemented in 2010 into the Industrial Emission Directive 2010/75/EU (IED).

Dichloromethane Upstream-Materialien And Downstream Produkte

Dichlormethan Anbieter Lieferant Produzent Hersteller Vertrieb Händler.

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