BIS(TRIMETHYLSILYL)PEROXIDE

BIS(TRIMETHYLSILYL)PEROXIDE Chemische Eigenschaften,Einsatz,Produktion Methoden

• R-Sätze Betriebsanweisung:

  R8:Feuergefahr bei Berührung mit brennbaren Stoffen.
  R10:Entzündlich.

• S-Sätze Betriebsanweisung:

  S17:Von brennbaren Stoffen fernhalten.
  S36/37/39:Bei der Arbeit geeignete Schutzkleidung,Schutzhandschuhe und Schutzbrille/Gesichtsschutz tragen.

• Physikalische Eigenschaften

  bp 41°C/30 mmHg;7 n20 D 1.3970.

• Verwenden

  Bis(trimethylsilyl) peroxide is an organosilicon compound used as a reagent for Bayer-Villiger oxidation of ketones.

• Verwenden

  Bis(trimethylsilyl) peroxide (1) functions as an electrophilic hydroxylating agent for aliphatic, aromatic, and heteroaromatic anions.Reaction of their lithium or Grignard compounds with (1) often affords trimethylsiloxy intermediates, which undergo desilylation with HCl in methanol to give the corresponding alcohols in good yields. In the presence of a catalytic amount of trifluoromethanesulfonic acid, (1) reacts with aromatic compounds to produce the corresponding phenols after acidic workup.In these reactions the Me3SiO? moiety is considered as a synthon of the hydroxyl cation (i.e. OH+).

• synthetische

  obtained in 80–96% yields by reaction of chlorotrimethylsilane with 1,4-diazabicyclo[2.2.2]octane· (H2O2)2,hexamethylenetetramine·H2O2,or hydrogen peroxide–urea in CH2Cl2.

BIS(TRIMETHYLSILYL)PEROXIDE Upstream-Materialien And Downstream Produkte

BIS(TRIMETHYLSILYL)PEROXIDE Anbieter Lieferant Produzent Hersteller Vertrieb Händler.

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