1,1,1,2,2,3,3,4,4,5,5,6,6-Tridecafluor-6-iodhexan

Bezeichnung:1,1,1,2,2,3,3,4,4,5,5,6,6-Tridecafluor-6-iodhexan

CAS-Nr355-43-1

Englisch Name:Perfluoro-1-iodohexane

CBNumberCB1675643

SummenformelC6F13I

Molgewicht445.95

MOL-Datei355-43-1.mol

Synonyma

1,1,1,2,2,3,3,4,4,5,5,6,6-Tridecafluor-6-iodhexan

1,1,1,2,2,3,3,4,4,5,5,6,6-Tridecafluor-6-iodhexan physikalisch-chemischer Eigenschaften

Schmelzpunkt	-45 °C
Siedepunkt	117 °C(lit.)
Dichte	2.063 g/mL at 25 °C(lit.)
Brechungsindex	n20/D 1.329(lit.)
Flammpunkt	117°C
storage temp.	Keep in dark place,Sealed in dry,Room Temperature
Löslichkeit	DMSO (Slightly), Methanol (Slightly)
Aggregatzustand	Oil
Farbe	Pale Pink
Wichte	2.063
Wasserlöslichkeit	insoluble
Sensitive	Light Sensitive
BRN	1802118
Stabilität	Stable.
InChIKey	BULLJMKUVKYZDJ-UHFFFAOYSA-N
CAS Datenbank	355-43-1(CAS DataBase Reference)
NIST chemische Informationen	Perfluorohexyl iodide(355-43-1)
EPA chemische Informationen	Hexane, 1,1,1,2,2,3,3,4,4,5,5,6,6-tridecafluoro-6-iodo- (355-43-1)

Sicherheit

Kennzeichnung gefährlicher	Xi
R-Sätze:	36/37/38
S-Sätze:	23-24/25-37/39-26-37
RIDADR	2810
WGK Germany	3
F	8
Hazard Note	Irritant
TSCA	T
HazardClass	6.1(b)
PackingGroup	III
HS Code	29034700

Gefahreninformationscode (GHS)

Perfluoro-1-iodohexane Chemische Eigenschaften,Einsatz,Produktion Methoden

R-Sätze Betriebsanweisung:
R36/37/38:Reizt die Augen, die Atmungsorgane und die Haut.
S-Sätze Betriebsanweisung:
S23:Gas/Rauch/Dampf/Aerosol nicht einatmen(geeignete Bezeichnung(en) vom Hersteller anzugeben).
S24/25:Berührung mit den Augen und der Haut vermeiden.
S37/39:Bei der Arbeit geeignete Schutzhandschuhe und Schutzbrille/Gesichtsschutz tragen.
S26:Bei Berührung mit den Augen sofort gründlich mit Wasser abspülen und Arzt konsultieren.
Chemische Eigenschaften
liquid
Verwenden
Perfluorohexyl Iodide is an important intermediate in the synthesis of organic fluorides products. It also exhibits estrogenic activity in vitro. Perfluorohexyl Iodide is used in the screening assay for binding affinities of perfluoroalkyl iodide for estrogen receptor alpha and beta isoforms.
Allgemeine Beschreibung
Perfluorohexyl iodide forms 1:1 complexes with a variety of hydrogen-bond acceptors. It has been grafted onto the isocitronellene/propene copolymer by radical reaction yielding a poly(α-olefin) with fluorinated side chains. The radical addition of perfluorohexyl iodide to vinyl acetate, using azo-bis( isobutyronitrile) (AIBN) as an initiator, has been investigated.
Sicherheitsprofil
Explodes in contact with sodium when heated to the boiling point of the iodide. When heated to decomposition it emits toxic fumes of Fí and Ií.
Synthese
To an autoclave (stainless steel, volume:1L) equipped with a mixing tank and a stirrer, C4F9I which compound (1) flow rate 25mL/min, CF2=CF2 (tetrafluoroethylene) which compound (2) flow rate 0.37g/min, (C2F5COO)2 (10 and half hour life temperature: 31°C) which compound (4) flow rate 0.052 mmol/min were supplied, the mixture was prepared by mixing at stirrer. Temperature in the autoclave was 10°C, residence time of the mixture in the autoclave was 10 minutes. The molar ratio (C4F9I/CF2=CF2)of C4F9I and CF2=CF2 in the mixed solution was 41, the amount of (C2F5COO)2 with respect to C4F9I was 0.034 mol%. Only the mixture from the bottom of the autoclave was withdrawn in the absence of gas phase, the mixture was fed to the bottom of tubular reactor (Tankan-shiki, volume: 0.5L). The mixture was not seperated by gas-liquid separation, the mixture was flow towards the outlet from the inlet of the reaction tube in the tube reactor. The temperature of the reaction tube, and a 70°C, the residence time of the mixture in the tubular reactor was set to 20 minutes. The mixture containing a compound Perfluoro-1-iodohexane C6F13I was obtained.

Perfluoro-1-iodohexane Upstream-Materialien And Downstream Produkte

1,1,1,2,2,3,3,4,4,5,5,6,6-Tridecafluor-6-iodhexan Anbieter Lieferant Produzent Hersteller Vertrieb Händler.

355-43-1, Perfluoro-1-iodohexane Verwandte Suche:

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