Dodecylbenzolsulfonsäure

Bezeichnung:Dodecylbenzolsulfonsäure

CAS-Nr27176-87-0

Englisch Name:Dodecylbenzenesulphonic acid

CBNumberCB9310467

SummenformelC18H30O3S

Molgewicht326.49

MOL-Datei27176-87-0.mol

Synonyma

Dodecylbenzolsulfonsure

Dodecylbenzolsulfonsäure

Laurylbenzolsulfonsäure

Dodecylbenzolsulfonsäure physikalisch-chemischer Eigenschaften

Schmelzpunkt	10°C
Siedepunkt	82 °C
Dichte	1.06 g/mL at 20 °C(lit.)
Dampfdruck	0Pa at 25℃
Brechungsindex	n20/D 1.51
Flammpunkt	85 °F
storage temp.	2-8°C
Löslichkeit	water, alcohols, glycol ethers, glycols, esters, ketones, aromatic and aliphatic hydrocarbons: soluble
pka	0.7[at 20 ℃]
Aggregatzustand	Colourless Solution
Farbe	Colorless to light yellow
Wasserlöslichkeit	100mg/L at 25℃
Stabilität	Stable. Hygroscopic. Incompatible with bases, oxidizing agents, metals.
LogP	4.78 at 25℃
CAS Datenbank	27176-87-0(CAS DataBase Reference)
EPA chemische Informationen	Dodecylbenzenesulfonic acid (27176-87-0)

Sicherheit

Kennzeichnung gefährlicher	C
R-Sätze:	34-22-10-67
S-Sätze:	26-36/37/39-45-16
RIDADR	UN 2924 3/PG 3
WGK Germany	2
RTECS-Nr.	DB6600000
HazardClass	8
PackingGroup	III
HS Code	34021100
Giftige Stoffe Daten	27176-87-0(Hazardous Substances Data)

Gefahreninformationscode (GHS)

Dodecylbenzenesulphonic acid Chemische Eigenschaften,Einsatz,Produktion Methoden

ERSCHEINUNGSBILD
GELBE BIS BRAUNE FLüSSIGKEIT.
CHEMISCHE GEFAHREN
Zersetzung beim Erhitzen über 205°C unter Bildung giftiger Rauche mit Schwefeloxidenund Schwefelwasserstoff. Reagiert mit Basenund Oxidationsmitteln unter Bildung von Schwefeloxiden. Vergiftungsgefahr. Greift Metalle an.
ARBEITSPLATZGRENZWERTE
TLV nicht festgelegt (ACGIH 2005).
MAK nicht festgelegt (DFG 2005).
AUFNAHMEWEGE
Aufnahme in den Körper durch Inhalation der Dämpfe und durch Verschlucken.
INHALATIONSGEFAHREN
Nur ungenügende Angaben vorhanden über die Geschwindigkeit, mit der eine gesundheitsschädliche Konzentration in der Luft beim Verdampfen bei 20°C erreicht wird.
WIRKUNGEN BEI KURZZEITEXPOSITION
WIRKUNGEN BEI KURZZEITEXPOSITION:
Die Substanz verätzt die Augen, die Haut und die Atemwege. ätzend beim Verschlucken.
LECKAGE
Ausgelaufene Flüssigkeit möglichst in abdichtbaren Nichtmetallbehältern sammeln. Reste vorsichtig mit Kalk oder Natriumbicarbonat neutralisieren. NICHT in die Umwelt gelangen lassen. Chemikalienschutzanzug mit umgebungsluftunabhängigem Atemschutzgerät.
R-Sätze Betriebsanweisung:
R34:Verursacht Verätzungen.
R22:Gesundheitsschädlich beim Verschlucken.
R10:Entzündlich.
S-Sätze Betriebsanweisung:
S26:Bei Berührung mit den Augen sofort gründlich mit Wasser abspülen und Arzt konsultieren.
S36/37/39:Bei der Arbeit geeignete Schutzkleidung,Schutzhandschuhe und Schutzbrille/Gesichtsschutz tragen.
S45:Bei Unfall oder Unwohlsein sofort Arzt zuziehen (wenn möglich, dieses Etikett vorzeigen).
S16:Von Zündquellen fernhalten - Nicht rauchen.
Beschreibung
Dodecylbenzenesulfonic acid is a light yellowto brown liquid with a slight SO2 odor. Molecularweight= 326.54; Boiling point = 315℃; Freezing/Meltingpoint = 10℃. Hazard Identification (based on NFPA-704 MRating System): Health 3, Flammability 1, Reactivity 1.Soluble in water.
Chemische Eigenschaften
brown or tan solid
Verwenden
Dopant for conducting polymers strong acid catalyst for amino cross-linked coatings
Definition
ChEBI: 2-dodecylbenzenesulfonic acid is a member of the class dodecylbenzenesulfonic acids that is benzenesulfonic acid in which the hydrogen at position 2 of the phenyl ring is substituted by a dodecyl group. It has a role as an animal metabolite.
Application
Dodecylbenzenesulphonic acid(DBSA) can be used as a catalyst for the esterification of fatty acids (oleic acids) to produce biodiesel. It can be used as a Bronsted acid catalyst for the green synthesis of quinoxaline derivatives which are used in a variety of pharmacological profiles. It may be electrodeposited with polypyrrole(PPy) films on the aluminium alloy to protect against corrosion. Water based nanofluids with enhanced thermal conductivity and specific heat capacity may be prepared by doping polyanaline (PANI) into dodecylbenzenesulphonic acid. Dodecylbenzenesulphonic acid is also a dopant for conducting polymers and a strong acid catalyst for amino crosslinked coatings.
Allgemeine Beschreibung
Dodecylbenzenesulphonic acid is a colorless liquid. Dodecylbenzenesulphonic acid is soluble in water. Dodecylbenzenesulphonic acid is corrosive to metals and tissue. Dodecylbenzenesulphonic acid is used to make detergents.
Air & Water Reaktionen
Soluble in water.
Reaktivität anzeigen
Dodecylbenzenesulphonic acid is corrosive. When heated to decomposition or on contact with strong acids produces highly toxic fumes of oxides of sulfur. The toxicity and hazards of individual alkylbenzene sulfonic acids must be assessed individually [Kirk-Othmer, 3rd ed., Vol. 22, 1978, p. 45].
Health Hazard
EYES AND SKIN: A 0.5% to 1% concentration in water caused significant irritation. The technical grade is corrosive and may cause irreversible damage to eyes and skin. INGESTION: Irritation of the mouth, esophagus and stomach. Diarrhea, intestinal distention and occasional vomiting.
Brandgefahr
Special Hazards of Combustion Products: May give off SO 3 , SO 2 and H 2 S
Flammability and Explosibility
Not classified
Landwirtschaftliche Anwendung
Insecticide, Adjuvant, Biocide: Dodecylbenzenesulfonic acid and its salts are used as degreasers in meat-cutting rooms. Also used as a laboratory chemical, to make detergents, and in electronically cleaning and pickling baths. Not listed for use in EU countries. Approved for use in the U.S. and other countries. There are 30 global suppliers.
Handelsname
ACCOMPLISH®[C]; ACIDET®; ACIDISOL®; CALSOFT LAS 99®; E 7256®; ELFAN WA sulphonic acid®; NACCONOL 98 SA®; RHODACAL ABSA®
mögliche Exposition
Used as a laboratory chemical. Usedfor cleaning electronic components; emulsifier foragricultural herbicides; in polymerization; in pickling baths;as a wetting agent in various industrial applications Used inthe production of biologically soft detergents, includinghousehold detergents (laundry liquids and powders, dishwashing liquids, and various other cleaners).
Erste Hilfe
If this chemical gets into the eyes, remove anycontact lenses at once and irrigate immediately for at least15 min, occasionally lifting upper and lower lids. Seek medical attention immediately. If this chemical contacts theskin, remove contaminated clothing and wash immediatelywith soap and water. Seek medical attention immediately. Ifthis chemical has been inhaled, remove from exposure,begin rescue breathing (using universal precautions, including resuscitation mask) if breathing has stopped and CPR ifheart action has stopped. Transfer promptly to a medicalfacility. When this chemical has been swallowed, get medical attention. If victim is conscious, administer water ormilk. Do not induce vomiting
Lager
Follow regulations in OSHA29CFR1910.134 or European Standard EN149. Use aNIOSH/MSHA- or European Standard EN149-approvedrespirator; or use an approved supplied-air respirator with afull face-piece operated in the positive-pressure mode, orwith a full face-piece, hood, or helmet in the continuousflow mode; or use a NIOSH/MSHA- or European StandardEN149-approved self-contained breathing apparatus with afull face-piece operated in pressure-demand or other positive-pressure mode.
Versand/Shipping
Dodecylbenzenesulfonic acid requires a shippinglabel of “CORROSIVE.” It falls in Hazard Class 8 andPacking Group II. The symbol “D” identifies proper shipping names which are appropriate for describing materialsfor domestic transportation but may be inappropriate forinternational transportation under the provisions of international regulations (e.g., IMO, ICAO). An alternate propershipping name may be selected when either domestic orinternational transportation is involved.
Inkompatibilitäten
May attack metals, forming flammablehydrogen gas. Keep away from combustible materials.

Dodecylbenzenesulphonic acid Upstream-Materialien And Downstream Produkte

Dodecylbenzolsulfonsäure Anbieter Lieferant Produzent Hersteller Vertrieb Händler.

27176-87-0, Dodecylbenzenesulphonic acid Verwandte Suche:

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