Hexylacetat

Bezeichnung:Hexylacetat

CAS-Nr142-92-7

Englisch Name:Hexyl acetate

CBNumberCB0161882

SummenformelC8H16O2

Molgewicht144.21

MOL-Datei142-92-7.mol

Synonyma

Hexylacetat

Hexylacetat physikalisch-chemischer Eigenschaften

Schmelzpunkt	?80 °C (lit.)
Siedepunkt	168-170 °C (lit.)
Dichte	0.87 g/mL at 25 °C (lit.)
Dampfdruck	5 hPa (20 °C)
FEMA	2565 \| HEXYL ACETATE
Brechungsindex	n20/D 1.409(lit.)
Flammpunkt	99 °F
storage temp.	Store below +30°C.
Löslichkeit	0.4g/l
Aggregatzustand	Liquid
Farbe	Clear colorless to pale yellow
Geruch (Odor)	at 10.00 % in dipropylene glycol. fruity green apple banana sweet
Geruchsart	fruity
Odor Threshold	0.0018ppm
Wasserlöslichkeit	immiscible
JECFA Number	128
BRN	1747138
Dielectric constant	4.4199999999999999
LogP	3.3 at 30℃
CAS Datenbank	142-92-7(CAS DataBase Reference)
NIST chemische Informationen	Hexyl ethanoate(142-92-7)
EPA chemische Informationen	Acetic acid, hexyl ester (142-92-7)

Sicherheit

R-Sätze:	10
S-Sätze:	16
RIDADR	UN 3272 3/PG 3
WGK Germany	1
RTECS-Nr.	AI0875000
TSCA	Yes
HazardClass	3
PackingGroup	III
HS Code	29153990
Giftige Stoffe Daten	142-92-7(Hazardous Substances Data)
Toxizität	LD50 orally in Rabbit: 36100 mg/kg LD50 dermal Rabbit > 5000 mg/kg

Gefahreninformationscode (GHS)

Hexyl acetate Chemische Eigenschaften,Einsatz,Produktion Methoden

R-Sätze Betriebsanweisung:
R10:Entzündlich.
S-Sätze Betriebsanweisung:
S16:Von Zündquellen fernhalten - Nicht rauchen.
Beschreibung
Hexyl acetate has a pleasant fruity odor and bittersweet taste suggestive of pear. May be synthesized from n-hexyl alcohol and excess acetic anhydride at the boil or with an excess of acetic acid in the presence of concentrated sulfuric acid.
Chemische Eigenschaften
Hexyl Acetate is a liquid with a sweet-fruity, pear-like odor. It is present in a number of fruits and alcoholic beverages and is used in fruit aroma compositions.
Chemische Eigenschaften
clear colorless to pale yellowish liquid
Chemische Eigenschaften
Hexyl acetate has a pleasant fruity, apple, cherry, pear, floral odor and bittersweet taste suggestive of pear.
Occurrence
Reported found in fruital aromas (e.g., Fragaria vesca) and essential oils. Also reported found in apple, apricot, banana, sweet cherry, citrus peel oils and juices, blueberry, black currants, guava, grapes, melon, peach, pear, raspberry, blackberry, strawberry, peas, sauerkraut, rye bread, cheeses, roasted beef, beer, rum, cognac, whiskies, cider, sherry, grape wines, coffee, tea, soybean, olive, passion fruit, beans, starfruit, mango, cauliflower, pear and apple brandy, quince, origanum, lovage leaf, corn oil, mangosteen (Garcia mangostana), Bourbon vanilla, clary sage, nectarine, naranjilla fruit, Chinese quince and chamomile oil.
Verwenden
n-Hexyl acetate exhibits antimicrobial activity and can be used to improve the safety of minimally processed fruits. It is a fruity smelling fluid used as flavoring agent or in perfumes. It is a green leaf volatile from cabbage Brassica oleracea var. capitata L. It is used as plasticizers.
Verwenden
Hexyl acetate was used to study the activity of diamondback moth sex pheromone and larval frass volatiles, as well as green leaf volatiles from cabbage, on the natural enemies of the pest.
Verwenden
Hexyl Acetate is a flavouring agent due to its fruity odor and it is naturally present in many fruits and alcoholic beverages.
Definition
ChEBI: The acetate ester of hexan-1-ol.
Vorbereitung Methode
n-Hexyl acetate is prepared from n-hexyl alcohol and excess acetic anhydride or with an excess of acetic acid and concentrated sulfuric acid . Its is also prepared from primary and sec-hexyl alcohols .
It is produced by Aldrich Chemical Corp., Milwaukee, WI, and Penta Manufacturing Co., Fairfield, NJ .
synthetische
From n-hexyl alcohol and excess acetic anhydride at the boil or with an excess of acetic acid in the presence of concentrated sulfuric acid
Aroma threshold values
Detection: 2 to 480 ppb
Taste threshold values
Taste characteristics at 15 ppm: fruity, green, fresh, sweet, banana peel, apple and pear.
Synthesis Reference(s)
Tetrahedron Letters, 18, p. 3263, 1977 DOI: 10.1016/S0040-4039(01)83213-5
Allgemeine Beschreibung
A colorless liquid with a mild sweet odor. Flash point 113°F. A moderate fire risk. Inhalation may cause adverse effects. Almost insoluble in water, soluble in alcohol and Propylene glycol, miscible with oils. When heated to high temperatures emits acrid smoke and fumes. Used as a solvent and as a propellant in aerosols.
Air & Water Reaktionen
Highly flammable. Insoluble in water.
Reaktivität anzeigen
Hexyl acetate is an ester. Esters react with acids to liberate heat along with alcohols and acids. Strong oxidizing acids may cause a vigorous reaction that is sufficiently exothermic to ignite the reaction products. Heat is also generated by the interaction of esters with caustic solutions. Flammable hydrogen is generated by mixing esters with alkali metals and hydrides.
Hazard
Combustible.
Health Hazard
May be harmful by inhalation, ingestion, or skin absorption. May cause irritation.
Brandgefahr
Special Hazards of Combustion Products: Vapor may travel considerable distance to a source of ignition and flash back. Container explosion may occur under fire conditions. Forms explosive mixtures in air.
Flammability and Explosibility
Flammable
Biochem/physiol Actions
Hexyl acetate has antimicrobial activity and can be used to improve the safety of minimally processed fruits. Hexyl acetate is a fruity smelling fluid used as flavoring agent or in perfumes. Hexyl acetate is a green leaf volatile from cabbage Brassica oleracea var. capitata L.

Hexyl acetate Upstream-Materialien And Downstream Produkte

Hexylacetat Anbieter Lieferant Produzent Hersteller Vertrieb Händler.

142-92-7, Hexyl acetate Verwandte Suche:

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