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3587-60-8

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Identification

Name
Benzylchloromethyl ether
CAS
3587-60-8
Synonyms
BENZYL CHLOROMETHYL ETHER
BENZYLOXYMETHYL CHLORIDE
(CHLOROMETHOXYMETHYL)BENZENE
Benzene, [(chloromethoxy)methyl]-
(Chloromethoxymethyl)benzene, Benzyloxymethyl chloride
Chloromethyl benzyl ether
Benzyl chloromethyl ether ,98%
α-Chloromethoxytoluene
EINECS(EC#)
252-527-2
Molecular Formula
C16H16Cl2O
MDL Number
MFCD00000886
Molecular Weight
295.2
MOL File
3587-60-8.mol

Chemical Properties

Appearance
Colorless liquid
Boiling point 
102 °C/14 mmHg (lit.)
bp 
102 °C14 mm Hg(lit.)

density 
1.126 g/mL at 20 °C(lit.)

refractive index 
n20/D 1.527

Fp 
91 °C
storage temp. 
2-8°C

form 
Liquid
color 
Clear colorless to pale yellow
Water Solubility 
Soluble in water [2.7 g/L (25 C)]
Detection Methods
GC,NMR
BRN 
1364034
InChIKey
LADPCMZCENPFGV-UHFFFAOYSA-N
CAS DataBase Reference
3587-60-8(CAS DataBase Reference)
NIST Chemistry Reference
Benzyl chloromethyl ether(3587-60-8)

Safety Data

Hazard Codes 
T,Xn
Risk Statements 
R45:May cause cancer.
R22:Harmful if swallowed.
R23:Toxic by inhalation.
R37/38:Irritating to respiratory system and skin .
R41:Risk of serious damage to eyes.
R48/22:Harmful: danger of serious damage to health by prolonged exposure if swallowed .
R36/37/38:Irritating to eyes, respiratory system and skin .
R20/21/22:Harmful by inhalation, in contact with skin and if swallowed .
Safety Statements 
S53:Avoid exposure-obtain special instruction before use .
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S39:Wear eye/face protection .
S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection .
S36:Wear suitable protective clothing .
RIDADR 
UN 2810 6.1/PG 3

WGK Germany 
3


19-21
HazardClass 
6.1(b)
PackingGroup 
III
HS Code 
29093090

Raw materials And Preparation Products

Raw materials
Formaldehyde

Material Safety Data Sheet(MSDS)

Hazard Information

Chemical Properties
Colorless liquid
Uses
Benzyl chloromethyl ether is employed in the introduction of benzoyloxy- and hydroxymethyl groups.
Synthesis Reference(s)
Synthesis, p. 762, 1983 DOI: 10.1055/s-1983-30506

Spectrum Detail

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