13716-12-6

Name Tri-tert-butylphosphine
CAS 13716-12-6
EINECS(EC#) 237-266-4
Molecular Formula C12H27P
MDL Number MFCD00015006
Molecular Weight 202.32
MOL File 13716-12-6.mol
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Chemical Properties

Appearance Colorless to light yellow liqui
Melting point  30-35 °C(lit.)
Boiling point  102-103 °C13 mm Hg(lit.)
density  0.861 g/mL at 25 °C
Fp  1 °F
storage temp.  Flammables area
form  solid
Specific Gravity 0.68
Water Solubility  insoluble
Hydrolytic Sensitivity 9: reacts extremely rapidly with atmospheric moisture - may be pyrophoric - glove box or sealed system required
Sensitive  Air & Moisture Sensitive
Detection Methods GC
BRN  1738613
InChI InChI=1S/C12H27P/c1-10(2,3)13(11(4,5)6)12(7,8)9/h1-9H3
InChIKey BWHDROKFUHTORW-UHFFFAOYSA-N
SMILES P(C(C)(C)C)(C(C)(C)C)C(C)(C)C
CAS DataBase Reference 13716-12-6(CAS DataBase Reference)
NIST Chemistry Reference Tri-tert-butylphosphine(13716-12-6)
Storage Precautions Air sensitive;Moisture sensitive;Store under inert gas;Store under argon gas
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Safety Data

Symbol(GHS)  Flame (GHS02)Corrosion (GHS05)
GHS02,GHS05
Signal word  Danger
Hazard statements  H250-H314
Precautionary statements  P231+P232-P260-P280-P303+P361+P353-P305+P351+P338-P370+P378
Hazard Codes  F,C
Risk Statements 
R17:Spontaneously flammable in air.
R34:Causes burns.
R67:Vapors may cause drowsiness and dizziness.
R65:Harmful: May cause lung damage if swallowed.
R63:Possible risk of harm to the unborn child.
R48/20:Harmful: danger of serious damage to health by prolonged exposure through inhalation .
R11:Highly Flammable.
Safety Statements 
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) .
S62:If swallowed, do not induce vomiting: seek medical advice immediately and show this container or label .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection .
S25:Avoid contact with eyes .
S43:In case of fire, use ... (indicate in the space the precise type of fire-fighting equipment. If water increases the risk add-Never use water) .
S27:Take off immediately all contaminated clothing .
S16:Keep away from sources of ignition-No smoking .
RIDADR  UN 2846 4.2/PG 1
WGK Germany  3
F  10-19-23
HazardClass  4.2
PackingGroup  I
HS Code  29319090
Storage Class 4.2 - Pyrophoric and self-heating hazardous materials
Hazard Classifications Carc. 2
Eye Dam. 1
Flam. Liq. 2
Pyr. Liq. 1
Skin Corr. 1B
STOT SE 3

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