13292-87-0

Name Borane-methyl sulfide complex
CAS 13292-87-0
EINECS(EC#) 236-313-6
Molecular Formula C2H9BS
MDL Number MFCD00013189
Molecular Weight 75.97
MOL File 13292-87-0.mol

Chemical Properties

Appearance CLEAR COLOURLESS SOLUTION
Melting point  -40--37°C
Boiling point  ~34 °C
density  1.287 g/mL at 25 °C
refractive index  1.4570
Fp  65 °F
storage temp.  2-8°C
solubility  Miscible with ethyl ether, tetrahydrofurane, dichloromethane, benzene, xylene, hexane, diglyme, dimethyl ether, ethyl acetate, toluene, methylene chloride and other aprotic solvents.
form  Solution
color  Colorless to pale yellow
Specific Gravity 0.801
Water Solubility  reacts
Sensitive  Air & Moisture Sensitive
BRN  3663489
InChI 1S/C2H6S.BH3/c1-3-2;/h1-2H3;1H3
InChIKey RMHDLBZYPISZOI-UHFFFAOYSA-N
SMILES B.CSC
CAS DataBase Reference 13292-87-0(CAS DataBase Reference)
NIST Chemistry Reference Borane-methyl sulfide complex(13292-87-0)
EPA Substance Registry System 13292-87-0(EPA Substance)

Safety Data

Symbol(GHS)  Flame (GHS02)Corrosion (GHS05)Skull and Crossbones (GHS06)Health Hazard (GHS08)
GHS02,GHS05,GHS06,GHS08
Signal word  Danger
Hazard statements  H225-H260-H301+H311-H318-H360FD-H412
Precautionary statements  P210-P231+P232-P273-P280-P301+P310-P305+P351+P338
Hazard Codes  F+,Xn,F,Xi
Risk Statements 
R12:Extremely Flammable.
R14/15:Reacts violently with water, liberating extremely flammable gases .
R19:May form explosive peroxides.
R20/22:Harmful by inhalation and if swallowed .
R37/38:Irritating to respiratory system and skin .
R41:Risk of serious damage to eyes.
R67:Vapors may cause drowsiness and dizziness.
R65:Harmful: May cause lung damage if swallowed.
R63:Possible risk of harm to the unborn child.
R48/20:Harmful: danger of serious damage to health by prolonged exposure through inhalation .
R38:Irritating to the skin.
R11:Highly Flammable.
R22:Harmful if swallowed.
R14:Reacts violently with water.
R40:Limited evidence of a carcinogenic effect.
R36:Irritating to the eyes.
R21:Harmful in contact with skin.
Safety Statements 
S36/37:Wear suitable protective clothing and gloves .
S62:If swallowed, do not induce vomiting: seek medical advice immediately and show this container or label .
S36/39:Wear suitable protective clothing and eye/face protection .
S33:Take precautionary measures against static discharges .
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S23:Do not breathe gas/fumes/vapor/spray (appropriate wording to be specified by the manufacturer) .
S16:Keep away from sources of ignition-No smoking .
S36:Wear suitable protective clothing .
S24/25:Avoid contact with skin and eyes .
S7/8:Keep container tightly closed and dry .
RIDADR  UN 3399 4.3/PG 1
WGK Germany  3
RTECS  PV5080000
F  10-13-23
TSCA  Yes
REACH Registrations Active
HazardClass  4.3
PackingGroup  II
HS Code  29309090
Storage Class 4.3 - Hazardous materials which set free flammable gases upon contact with water
Hazard Classifications Acute Tox. 4 Oral
Eye Dam. 1
Flam. Liq. 2
Repr. 1B
Skin Irrit. 2
Water-react 1

Hazard Information

Supplier