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112246-73-8

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Identification

Name
(+)-Diisopinocampheyl chloroborane
CAS
112246-73-8
Synonyms
(+)-B-CHLORODIISOPINOCAMPHENYLBORANE
(+)-B-CHLORODIISOPINOCAMPHEYLBORANE
(+)-B-DIISOPINOCAMPHEYL-CHLOROBORANE
(+)-BETA-CHLORODIISOPINOCAMPHEYLBORANE
(+)-Diisopinocampheylchloroborane
(+)-DIP CHLORIDE
(+)-DIP-CHLORIDE(TM)
(+)-IPC2BCL
(+)-beta-Chlorodiisopinocampheylborane (ca. 65% in n-hexane)
(+)-β-Chlorodiisopinocampheylborane
(+)-DIP-CHLORIDE, TYPICALLY 90-105%
(+)-DIP chloride[R]
(+)-Diisopinocampheylchloroborane, 1.8M solution in hexanes
(+)-DIP CHLORIDE 60-70% SOLUTION IN HEPTANE
(+)-B-Chlorodiisopinocampheylborane
(+)-Diisopinocampheyl chloroborane
(+)-DIP chloride
(+)-DIP-CHLORIDE IN HEPTANES, 2M SOLUTION
(+)-B-Chlorodiisopinocampheylborane (58% in Hexane, ca. 1.6mol/L)
Molecular Formula
C20H34BCl
MDL Number
MFCD00074808
Molecular Weight
320.75
MOL File
112246-73-8.mol

Chemical Properties

Appearance
White crystalline powder
Melting point 
53-55 °C(lit.)

mp 
53-55 °C(lit.)

Boiling point 
369.6±25.0 °C(Predicted)
density 
0.91
Fp 
>230 °F

storage temp. 
2-8°C

Usage
(+)-Diisopinocampheyl chloroborane(112246-73-8) are used for high enantiselective asymmetric reduction of prochiral ketones and for the preparation of β-amino alcohols.
InChIKey
PSEHHVRCDVOTID-YYNWCRCSSA-N
CAS DataBase Reference
112246-73-8(CAS DataBase Reference)

Safety Data

Hazard Codes 
C
Risk Statements 
R34:Causes burns.
R37:Irritating to the respiratory system.
Safety Statements 
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection .
S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) .
RIDADR 
UN 3261 8/PG 2

WGK Germany 
3


10-21
HazardClass 
8
PackingGroup 
III
HS Code 
29319090

Hazard Information

Chemical Properties
white to light yellow crystal powde
Uses
Both (+)- and (-)-DIP-chloride are used for asymmetric reduction of prochiral ketones and for the preparation of β-amino alcohols.

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