Physical properties
Gray amorphous powder or
crystals. Resistant to thermal
shock. Good oxidation
resistance up to 1500°C but
decomposes into nitrogen and
silicon above 1850°C. Excellent
corrosion resistance to molten
nonferrous metals such as Al,
Pb, Zn, Cd, Bi, Rb, and Sn, and
molten salts like NaCl-KCl, NaF,
and silicate glasses. However,
corroded by molten Mg, Ti, V,
Cr, Fe, and Co, cryolite, KOH,
and Na2 O.
Uses
Silicon nitride (Si3N4), resistant to oxidation, is an excellent coating for metals, as well as
an adhesive and abrasive, and it is used in high-temperature crucibles. It has proven useful as
heat-resistant substance for the nozzles on rocket engines.
General Description
Silicon nitride based ceramics possess high fracture toughness, hardness and wear resistance, resistance to corrosion, thermal stability. Two known polymorphs of silicon nitride exist, alpha and beta Si3N4, both have hexagonal structure. A study shows that a third state, cubic spinel structure, has also been synthesized.