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109-02-4

Name 4-Methylmorpholine
CAS 109-02-4
EINECS(EC#) 203-640-0
Molecular Formula C5H11NO
MDL Number MFCD00006175
Molecular Weight 101.15
MOL File 109-02-4.mol

Chemical Properties

Appearance clear liquid
Melting point  −66 °C(lit.)
Boiling point  115-116 °C750 mm Hg(lit.)
density  0.92 g/mL at 25 °C(lit.)
vapor density  >1 (vs air)
vapor pressure  18 mm Hg ( 20 °C)
refractive index  n20/D 1.435(lit.)
Fp  75 °F
storage temp.  Store at RT.
solubility  Chloroform (Soluble), Ethyl Acetate, Methanol (Slightly)
form  Liquid
pka 7.38(at 25℃)
color  Clear
Specific Gravity 0.920 (20/4℃)
PH 10.6 (50g/l, H2O, 20℃)
explosive limit 2.1%(V)
Water Solubility  >500 g/L (20 ºC)
Detection Methods GC,NMR
Merck  14,6277
BRN  102719
Stability: Volatile
InChIKey SJRJJKPEHAURKC-UHFFFAOYSA-N
LogP -0.32 at 25℃
Uses
Catalyst in polyurethane foams, extraction sol-vent, stabilizing agent for chlorinated hydrocar-bons, self-polishing waxes, oil emulsions, corrosioninhibitors, pharmaceuticals.
CAS DataBase Reference 109-02-4(CAS DataBase Reference)
NIST Chemistry Reference Morpholine, 4-methyl-(109-02-4)
EPA Substance Registry System 109-02-4(EPA Substance)

Safety Data

Hazard Codes  F,C
Risk Statements 
R11:Highly Flammable.
R20/21/22:Harmful by inhalation, in contact with skin and if swallowed .
R34:Causes burns.
R10:Flammable.
Safety Statements 
S16:Keep away from sources of ignition-No smoking .
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection .
S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) .
S25:Avoid contact with eyes .
RIDADR  UN 2535 3/PG 2
WGK Germany  1
RTECS  QE5775000
10-23
Autoignition Temperature 165 °C DIN 51794
TSCA  Yes
HazardClass  3
PackingGroup  II
HS Code  29349990
Safety Profile
Moderately toxic by ingestion and skin contact. Mildly toxic by inhalation. An irritant to skin, eyes, and mucous membranes. Flammable when exposed to heat or flame, can react vigorously with oxidizing materials. When heated to decomposition it emits toxic fumes of NOx.
Toxicity
LD50 orally in Rabbit: 1960 mg/kg LD50 dermal Rabbit 1240 mg/kg

Hazard Information

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