2,6-Dichlorophenol is a white crystalline solidhaving a strong odor similar to o-chlorophenol; Molecularweight=163.00; Boiling point=219.5℃; Freezing/Melting point=68-69℃. Hazard Identification (based onNFPA-704 M Rating System): Health 3, Flammability 0,Reactivity 0.
2,6-Dichlorophenol is a white crystalline solid having a strong odor similar to o-chlorophenol. Freely soluble in ethanol and ether, soluble in benzene and petroleum ether.
It is used primarily as a starting material for the manufacture of trichlorophenols, tetrachlorophenols, and pentachlorophenols. It also acts as a sex pheromone for the Lone Star tick.
ChEBI: 2,6-dichlorophenol is a dichlorophenol with the chloro substituents at positions 2 and 6. It is used as a chemical intermediate for 2,4,6-trichlorophenol and in the production of dehydro-l-ascorbic acid.
2,6-Dichlorophenol has been prepared by the chlorination of phenol with chlorine gas in the presence of nitrobenzene and fuming sulfuric acid, by the decomposition of the diazotate of 2,6-dichloro-4-aminophenol, and by the decarboxylation of 3,5-dichloro-4-hydroxybenzoic acid in quinoline or dimethylaniline.
Journal of the American Chemical Society, 73, p. 2723, 1951
DOI: 10.1021/ja01150a084Organic Syntheses, Coll. Vol. 3, p. 267, 1955
2,6-dichlorophenol is a white crystalline solid with a strong odor. Odor threshold concentration: 0.003 mg/L at 86°F; 200 micrograms/liter at 68-72°F. Taste threshold concentration: 0.0002 mg/L. (NTP, 1992)
2,6-Dichlorophenol is incompatible with acid chlorides, acid anhydrides and oxidizing agents .
Flash point data for 2,6-Dichlorophenol are not available; however, 2,6-Dichlorophenol is probably combustible.
Poison by
intraperitoneal route. Moderately toxic by
ingestion. A severe skin and eye irritant.
When heated to decomposition it emits
toxic fumes of Cl-. See also
CHLOROPHENOLS.
2,6-Dichlorophenol is produced as aby-product from the direct chlorination of phenol. It is usedprimarily as a starting material for the manufacture of trichlorophenols, tetrachlorophenols, and pentachlorophenols.It also acts as a sex pheromone for lone star tick.
If this chemical gets into the eyes, remove anycontact lenses at once and irrigate immediately for at least15 min, occasionally lifting upper and lower lids. Seek medical attention immediately. If this chemical contacts theskin, remove contaminated clothing and wash immediatelywith soap and water. Seek medical attention immediately. Ifthis chemical has been inhaled, remove from exposure,begin rescue breathing (using universal precautions, including resuscitation mask) if breathing has stopped and CPRif heart action has stopped. Transfer promptly to a medicalfacility. When this chemical has been swallowed, getmedical attention. Give large quantities of water andinduce vomiting. Do not make an unconscious personvomit.
Color Code—Blue: Health Hazard/Poison: Storein a secure poison location. Prior to working with 2,6-DCPyou should be trained on its proper handling and storage.Store in tightly closed containers in a refrigerator awayfrom oxidizers and other incompatible materials listedabove.
UN2020 Chlorophenols, solid, Hazard Class:
6.1; Labels: 6.1-Poisonous materials.
Incompatible with oxidizers (chlorates,
nitrates, peroxides, permanganates, perchlorates, chlorine,
bromine, fluorine, etc.); contact may cause fires or explosions. Keep away from alkaline materials, strong bases,
strong acids, oxoacids, epoxides, acid fumes, acid anhyrides
and acid chlorides
Dissolve in a combustible solvent and incinerate in a furnace equipped with afterburner
and scrubber. In accordance with 40CFR165, follow
recommendations for the disposal of pesticides and pesticide containers. Must be disposed properly by following
package label directions or by contacting your local or
federal environmental control agency, or by contacting
your regional EPA office. Consult with environmental
regulatory agencies for guidance on acceptable disposal
practices. Generators of waste containing this contaminant
(≥100 kg/mo) must conform with EPA regulations governing storage, transportation, treatment, and waste disposal
