Bathophenanthroline CAS#: 1662-01-7

Bathophenanthroline

Bathophenanthroline Basic information

Bathophenanthroline Chemical Properties

Melting point:218-220 °C(lit.)
Boiling point:459.52°C (rough estimate)
Density 1.2047 (rough estimate)
refractive index 1.7620 (estimate)
storage temp. Store at +15°C to +25°C.
solubility Soluble in organic solvents. Slightly soluble in acidic aqueous solutions. Insoluble in neutral or alkaline solutions.
pka4.83±0.10(Predicted)
form Crystalline Powder, Crystals or Crystalline Mass
color White to yellow to pinkish
BRN 261048
Stability:Stable. Incompatible with strong oxidizing agents.
InChIKeyDHDHJYNTEFLIHY-UHFFFAOYSA-N
CAS DataBase Reference1662-01-7(CAS DataBase Reference)
NIST Chemistry Reference1,10-Phenanthroline, 4,7-diphenyl-(1662-01-7)
EPA Substance Registry System1,10-Phenanthroline, 4,7-diphenyl- (1662-01-7)

Safety Information

MSDS

Bathophenanthroline Usage And Synthesis

ClassificationHole-blocking layer (HBL) materials , Electron injection layer (EIL) materials, OLEDS, Organic photovoltaics, Perovskite solar cells.
ApplicationsBPhen is widely used as a hole-blocking or exciton-blocking layer due to its wide energy gap and high ionisation potential.
The phenanthroline unit is small, rigid, and planar, with extended π-electrons and short hopping lengths that facilitate electron mobility. The electron mobility of BPhen is about 5 × 10-4 cm2 V-1 s-1, which is about two orders of magnitude higher than that of Alq3.
When doped with lithium, BPhen:Li is an excellent electron-transport material, and is often used as an electron-injection layer to enable ohmic contact to any electrode -- without the need to consider the work function alignments.
Reactions
1. Bidentate ligand and reagent for determination of iron.
2. Ligand used in the copper-catalyzed protodecarboxylation of aromatic carboxylic acids.
Chemical Propertieswhite to faintly yellow crystalline powder
DefinitionChEBI: A member of the class of phenanthrolines that is 1,10-phenanthroline bearing two phenyl substituents at positions 4 and 7.

Bathophenanthroline Preparation Products And Raw materials

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