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Bathophenanthroline

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Bathophenanthroline Basic information
Bathophenanthroline Chemical Properties
  • Melting point:218-220 °C(lit.)
  • Boiling point:459.52°C (rough estimate)
  • Density 1.2047 (rough estimate)
  • refractive index 1.7620 (estimate)
  • storage temp. Store at +15°C to +25°C.
  • solubility Soluble in organic solvents. Slightly soluble in acidic aqueous solutions. Insoluble in neutral or alkaline solutions.
  • pka4.83±0.10(Predicted)
  • form Crystalline Powder, Crystals or Crystalline Mass
  • color White to yellow to pinkish
  • BRN 261048
  • Stability:Stable. Incompatible with strong oxidizing agents.
  • InChIKeyDHDHJYNTEFLIHY-UHFFFAOYSA-N
  • CAS DataBase Reference1662-01-7(CAS DataBase Reference)
  • NIST Chemistry Reference1,10-Phenanthroline, 4,7-diphenyl-(1662-01-7)
  • EPA Substance Registry System1,10-Phenanthroline, 4,7-diphenyl- (1662-01-7)
Safety Information
MSDS
Bathophenanthroline Usage And Synthesis
  • ClassificationHole-blocking layer (HBL) materials , Electron injection layer (EIL) materials, OLEDS, Organic photovoltaics, Perovskite solar cells.
  • ApplicationsBPhen is widely used as a hole-blocking or exciton-blocking layer due to its wide energy gap and high ionisation potential.
    The phenanthroline unit is small, rigid, and planar, with extended π-electrons and short hopping lengths that facilitate electron mobility. The electron mobility of BPhen is about 5 × 10-4 cm2 V-1 s-1, which is about two orders of magnitude higher than that of Alq3.
    When doped with lithium, BPhen:Li is an excellent electron-transport material, and is often used as an electron-injection layer to enable ohmic contact to any electrode -- without the need to consider the work function alignments.
  • Reactions
    1. Bidentate ligand and reagent for determination of iron.
    2. Ligand used in the copper-catalyzed protodecarboxylation of aromatic carboxylic acids. 
  • Chemical Propertieswhite to faintly yellow crystalline powder
  • DefinitionChEBI: A member of the class of phenanthrolines that is 1,10-phenanthroline bearing two phenyl substituents at positions 4 and 7.
Bathophenanthroline Preparation Products And Raw materials
Bathophenanthroline(1662-01-7)Related Product Information
BathophenanthrolineSupplierMore
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