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1-Bromohexane

Basic information Chemical nature Synthesis and reactions Safety Related Supplier
1-Bromohexane Basic information
1-Bromohexane Chemical Properties
  • Melting point:−85 °C(lit.)
  • Boiling point:154-158 °C(lit.)
  • Density 1.176 g/mL at 25 °C(lit.)
  • vapor density 5.7 (vs air)
  • vapor pressure <10 mm Hg ( 20 °C)
  • refractive index n20/D 1.448(lit.)
  • Flash point:135 °F
  • storage temp. Store below +30°C.
  • solubility <1g/l
  • form Liquid
  • color Clear
  • Water Solubility Immiscible with water.
  • BRN 1731290
  • Stability:Stable. Incompatible with strong oxidizing agents, strong bases. Combustible.
  • InChIKeyMNDIARAMWBIKFW-UHFFFAOYSA-N
  • CAS DataBase Reference111-25-1(CAS DataBase Reference)
  • NIST Chemistry ReferenceHexane, 1-bromo-(111-25-1)
  • EPA Substance Registry SystemHexane, 1-bromo- (111-25-1)
Safety Information
  • Hazard Codes Xi
  • Risk Statements 36/37/38-10
  • Safety Statements 26-36-16
  • RIDADR UN 1993 3/PG 3
  • WGK Germany 2
  • RTECS MO0925000
  • TSCA Yes
  • HazardClass 3
  • PackingGroup III
  • HS Code 29033036
  • ToxicityLD50 orally in Rabbit: > 2000 mg/kg
MSDS
1-Bromohexane Usage And Synthesis
  • Chemical nature

    1-Bromohexane is organobromine compound with formula Br(CH2)5CH3. It is a colorless liquid.

  • Synthesis and reactions

    Most 1-bromoalkanes are prepared by free-radical addition of hydrogen bromide to the 1-alkene. These conditions lead to anti-Markovnikov addition, giving the 1-bromo derivative.
    1-Bromohexane undergoes reactions expected of simple alkyl bromides. It can form Grignard reagents. It reacts with potassium fluoride to give the corresponding fluorocarbons.

  • Chemical Propertiescolourless liquid
  • UsesIntermediate, for introduction of hexyl group.
  • Synthesis Reference(s)Chemistry Letters, 7, p. 833, 1978
    Synthetic Communications, 6, p. 21, 1976 DOI: 10.1080/00397917608062128
    Tetrahedron, 40, p. 641, 1984 DOI: 10.1016/S0040-4020(01)91092-0
  • Purification MethodsShake the bromide with H2SO4, wash with water, dry (K2CO3) and fractionally distil. [Beilstein 1 IV 352.]
1-Bromohexane Preparation Products And Raw materials
1-Bromohexane(111-25-1)Related Product Information
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