Chemical nature Synthesis and reactions
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1-Bromohexane

Chemical nature Synthesis and reactions
1-Bromohexane Structure
1-Bromohexane
  • CAS No.111-25-1
  • Chemical Name:1-Bromohexane
  • CBNumber:CB4447030
  • Molecular Formula:C6H13Br
  • Formula Weight:165.07
  • MOL File:111-25-1.mol
1-Bromohexane Property
  • Melting point: :−85 °C(lit.)
  • Boiling point: :154-158 °C(lit.)
  • Density  :1.176 g/mL at 25 °C(lit.)
  • vapor density  :5.7 (vs air)
  • vapor pressure  :<10 mm Hg ( 20 °C)
  • refractive index  :n20/D 1.448(lit.)
  • Flash point: :135 °F
  • storage temp.  :Store below +30°C.
  • solubility  :<1g/l
  • form  :Liquid
  • color  :Clear
  • Water Solubility  :Immiscible with water.
  • BRN  :1731290
  • Stability: :Stable. Incompatible with strong oxidizing agents, strong bases. Combustible.
  • InChIKey :MNDIARAMWBIKFW-UHFFFAOYSA-N
  • CAS DataBase Reference :111-25-1(CAS DataBase Reference)
  • FDA UNII :WVA0FAX7GA
  • NIST Chemistry Reference :Hexane, 1-bromo-(111-25-1)
  • EPA Substance Registry System :Hexane, 1-bromo- (111-25-1)
Safety
  • Hazard Codes  :Xi
  • Risk Statements  :36/37/38-10
  • Safety Statements  :26-36-16
  • RIDADR  :UN 1993 3/PG 3
  • WGK Germany  :2
  • RTECS  :MO0925000
  • TSCA  :Yes
  • HazardClass  :3
  • PackingGroup  :III
  • HS Code  :29033036
  • Toxicity :LD50 orally in Rabbit: > 2000 mg/kg
Hazard and Precautionary Statements (GHS)
  • Symbol(GHS)
  • Signal wordWarning
  • Hazard statements H303-H401-H411-H226-H315-H319-H335
  • Precautionary statements P261-P305+P351+P338-P280-P337+P313-P403+P235-P273-P280g-P210-P233-P240-P241+P242+P243-P264-P302+P352+P332+P313+P362+P364-P305+P351+P338+P337+P313-P501
1-Bromohexane Price More Price(13)
  • Brand: Sigma-Aldrich
  • Product number: B68240
  • Product name : 1-Bromohexane
  • Purity: 98%
  • Packaging: 100g
  • Price: $21.4
  • Updated: 2021/03/22
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  • Brand: Sigma-Aldrich
  • Product number: 8.01603
  • Product name : 1-Bromohexane
  • Purity: for synthesis
  • Packaging: 100 mL
  • Price: $29.51
  • Updated: 2021/03/22
  • Buy: Buy
  • Brand: Sigma-Aldrich
  • Product number: 8.01603
  • Product name : 1-Bromohexane
  • Purity: for synthesis
  • Packaging: 500 mL
  • Price: $49.58
  • Updated: 2021/03/22
  • Buy: Buy
  • Brand: Sigma-Aldrich
  • Product number: B68240
  • Product name : 1-Bromohexane
  • Purity: 98%
  • Packaging: 1kg
  • Price: $141
  • Updated: 2021/03/22
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  • Brand: TCI Chemical
  • Product number: B0600
  • Product name : 1-Bromohexane
  • Purity: >98.0%(GC)
  • Packaging: 25g
  • Price: $14
  • Updated: 2021/03/22
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1-Bromohexane Chemical Properties,Usage,Production

  • Chemical nature

    1-Bromohexane is organobromine compound with formula Br(CH2)5CH3. It is a colorless liquid.

  • Synthesis and reactions

    Most 1-bromoalkanes are prepared by free-radical addition of hydrogen bromide to the 1-alkene. These conditions lead to anti-Markovnikov addition, giving the 1-bromo derivative.
    1-Bromohexane undergoes reactions expected of simple alkyl bromides. It can form Grignard reagents. It reacts with potassium fluoride to give the corresponding fluorocarbons.

  • Chemical Properties colourless liquid
  • Uses Intermediate, for introduction of hexyl group.
  • Synthesis Reference(s) Chemistry Letters, 7, p. 833, 1978
    Synthetic Communications, 6, p. 21, 1976 DOI: 10.1080/00397917608062128
    Tetrahedron, 40, p. 641, 1984 DOI: 10.1016/S0040-4020(01)91092-0
  • Purification Methods Shake the bromide with H2SO4, wash with water, dry (K2CO3) and fractionally distil. [Beilstein 1 IV 352.]
1-Bromohexane Preparation Products And Raw materials
Raw materials
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  • HALOGEN
  • Monofunctional & 伪,蠅-Bifunctional Alkanes
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  • Halogenated Hydrocarbons
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  • Alkyl
  • Alkyl
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  • Chemical Synthesis
  • Halogenated Hydrocarbons
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  • ALKYL BROMIDE
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