CAS: | 111-25-1 |
MF: | C6H13Br |
MW: | 165.07 |
EINECS: | 203-850-2 |
Product Categories: | Alkyl;Building Blocks;Intermediates;Chemical Synthesis;Halogenated Hydrocarbons;Organic Building Blocks;Industrial/Fine Chemicals;ALKYL BROMIDE;Bromine Compounds;Alkyl Bromides;Monofunctional & alpha,omega-Bifunctional Alkanes;Monofunctional Alkanes |
Mol File: | 111-25-1.mol |
![1-Bromohexane Structure](https://www.chemicalbook.com/CAS/GIF/111-25-1.gif) |
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1-Bromohexane Chemical Properties |
Melting point | −85 °C(lit.) |
Boiling point | 154-158 °C(lit.) |
density | 1.176 g/mL at 25 °C(lit.) |
vapor density | 5.7 (vs air) |
vapor pressure | <10 mm Hg ( 20 °C) |
refractive index | n20/D 1.448(lit.) |
Fp | 135 °F |
storage temp. | Store below +30°C. |
solubility | <1g/l |
form | Liquid |
color | Clear |
Water Solubility | Immiscible with water. |
BRN | 1731290 |
Stability: | Stable. Incompatible with strong oxidizing agents, strong bases. Combustible. |
InChIKey | MNDIARAMWBIKFW-UHFFFAOYSA-N |
CAS DataBase Reference | 111-25-1(CAS DataBase Reference) |
NIST Chemistry Reference | Hexane, 1-bromo-(111-25-1) |
EPA Substance Registry System | Hexane, 1-bromo- (111-25-1) |
1-Bromohexane Usage And Synthesis |
Chemical nature | 1-Bromohexane is organobromine compound with formula Br(CH2)5CH3. It is a colorless liquid.
![1-Bromohexane 1-Bromohexane](https://www.chemicalbook.com/NewsImg/2020-10-13/202010138595718612.png) |
Synthesis and reactions | Most 1-bromoalkanes are prepared by free-radical addition of hydrogen bromide to the 1-alkene. These conditions lead to anti-Markovnikov addition, giving the 1-bromo derivative. 1-Bromohexane undergoes reactions expected of simple alkyl bromides. It can form Grignard reagents. It reacts with potassium fluoride to give the corresponding fluorocarbons. |
Chemical Properties | 1-Bromohexane is a colourless liquid organohalide. It is a solvent that is frequently used in grignard reactions. It is also used as Intermediate, for introduction of hexyl group. |
Uses | 1-Bromohexane is utilized in the preparation of pharmaceuticals and organic chemicals. It is involved in Grignard reactions as an alkylating agent and in the synthesis of bromo-cyclic compounds. |
Application | 1-Bromohexane is a very useful synthetic intermediate,it can be used to react with Mg to prepare Grignard reagents which play an important role in formation of carbon-carbon bond. |
Synthesis Reference(s) | Chemistry Letters, 7, p. 833, 1978 Synthetic Communications, 6, p. 21, 1976 DOI: 10.1080/00397917608062128 Tetrahedron, 40, p. 641, 1984 DOI: 10.1016/S0040-4020(01)91092-0 |
Purification Methods | Shake the bromide with H2SO4, wash with water, dry (K2CO3) and fractionally distil. [Beilstein 1 IV 352.]
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Packing &shipping&Payment
Packing:25kg/drum
Shipping:by sea or by air
Payment:T/T,western union,moneygram
Packaging Details drum
Port:Tianjin
Lead Time :
Quantity(Kilograms) | 1 - 10000 | >10000 |
Est. Time(days) | 5 | To be negotiated |
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Company information
Hebei Mojin Biotechnology Co., Ltd, Our company is a professional in 4'-Methylacetophenone,Levamisole hydrochloride ,N-Methylformamide and other chemical reagents research and development production enterprises. Our business covers more than 30 countries, most of the big customers come from Europe, America and other countries in the world, we can guarantee the quality and price. In recent decades, with the efforts of all employees, we have established many cooperative companies in shandong, henan, guangdong and other places. Our corporate purpose is based on the market, enhance the strength, take the road of scientific and environmental sustainable development, relying on the country. Technology r & d center, increase the investment in r & d, based on the domestic market, expand the international market, manufacturing quality products, sincere service to the society, into a modern, ecological, scientific and technological enterprise world.
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